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Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.

California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.

Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.

Exhaust gas recirculation (EGR) is effective in reducing engine-out NOx emissions; however, the EGR system is subject to fouling and corrosion. Fouling is mainly due to particulate buildup on the EGR component (e.g., EGR valve and cooler) surfaces. Corrosion is primarily related to oxides of sulfur and nitrogen in the gas stream, especially problematic when condensation occurs [1]. Because cooled EGR is most effective in controlling NOx emissions, EGR cooler design and operation are important considerations in engine design in order to meet durability requirements. An approach has been developed to greatly reduce EGR system fouling. Four EGR coolers were tested simultaneously with various PM control devices installed upstream of the cooler. System configuration and on-engine test results are presented herein.

The diesel particulate filter (DPF) is a critical aftertreatment device for control of particulate matter (PM) emissions from a diesel engine. DPF survivability is challenged by several key factors such as: excessive thermal stress due to DPF runaway regenerations (or uncontrolled regeneration) may cause DPF substrate and washcoat failure. Catalyst poisoning elements from the diesel fuel and engine oil may cause performance degradation of the catalyzed DPF. Harsh vibration from the powertrain, as well as from the road surface, may lead to mechanical failure of the substrate and/or the matting material. Evaluations of these important validation parameters were performed.

A high-efficiency NOx aftertreatment system has been proposed for use in Diesel engines. This system includes a Lean NOx Trap (LNT) in series with a Selective Catalyst Reduction (SCR) catalyst [6], [7], [8], and is hereinafter referred to as the LNT-SCR system. The combined LNT-SCR system can potentially overcome many of the drawbacks of LNT-only and SCR-only operation and achieve very high NOx conversion efficiency without external addition of ammonia (or urea). A laboratory test procedure was developed to validate the LNT-SCR system concept, and a series of tests was conducted to test the NOx conversion of this system under various conditions. A Synthetic Gas Reactor (SGR) system was modified to accommodate LNT and SCR catalyst cores and synthetic gas mixtures were used to simulate rich-lean regeneration cycles from a diesel engine. A Fourier Transform Infrared (FTIR) system was used to measure gas compositions within the LNT-SCR system.

A novel urea evaporation and mixing device has been developed to improve the overall performance of a urea-SCR system. The device was tested with a MY2007 Cummins ISB 6.7L diesel engine equipped with an SCR aftertreatment system. Test results show that the device effectively improved the overall NO conversion efficiency of the SCR catalyst over both steady-state and transient engine operating conditions, while NH₃ slip from the catalyst decreased.

Particulate Matter (PM) emissions from gasoline direct injection (GDI) engines are becoming a concern and will be limited by future emissions regulations, such as the upcoming Euro 6 legislation. Therefore, PM control from a GDI engine will be required in addition to effective reduction of HC, CO and NOx emissions. Three different integrated aftertreatment systems were developed to simultaneously reduce PM, HC, CO and NOx emissions from a preproduction Ford 3.5L EcoBoost GTDI engine, with PM reduction as the major focus. PM reduction efficiencies were calculated based on the measurements of PM mass and solid particle number. Test results show that tradeoffs exist in the design of aftertreatment systems to significantly reduce PM emissions from a GDI engine.

Ideally, complete decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea decomposition reaction is a two-step process that includes the formation of ammonia and isocyanic acid as intermediate products via thermolysis. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid (CYN), biuret (BIU), melamine (MEL), ammeline (AML), ammelide (AMD), and dicyandimide (DICY). These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions can create oligomers that are difficult to remove from exhaust pipes. Deposits can affect efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow and negatively impact ammonia distribution on the SCR catalyst.

In this study, the criteria pollutant emissions from a light duty vehicle equipped with Dedicated EGR® technology were compared with emissions from an identical production GDI vehicle without externally cooled EGR. In addition to the comparison of criteria pollutant mass emissions, an analysis of the gaseous and particulate chemistry was conducted to understand how the change in combustion system affects the optimal aftertreatment control system. Hydrocarbon emissions from the vehicle were analyzed usin g a variety of methods to quantify over 200 compounds ranging in HC chain length from C1 to C12. The particulate emissions were also characterized to quantify particulate mass and number. Gaseous and particulate emissions were sampled and analyzed from both vehicles operating on the FTP-75, HWFET, US06, and WLTP drive cycles at the engine outlet location.

Ideally, complete thermal decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea thermal decomposition reaction includes the formation of isocyanic acid as an intermediate product. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid, biuret, melamine, ammeline, ammelide, and dicyandimide [1,2,3,4]. These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions, can create oligomers such as melam, melem, and melon [5, 6] that are difficult to remove from exhaust systems. Deposits can affect the efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow.

In recent years, gasoline direct injection (GDI) engines have been widely used by manufacturers in light-duty to meet stringent fuel economy and emissions standards. This study focuses on the relationship between various particle metrics such as number, size, surface area and mass of dilute exhaust particles from 12 different light-duty vehicles equipped with GDI engines. The campaign included the measurement of total particulate matter (PM) using Title 40 CFR Part 1066 compliant filter measurement, soot mass using photo-acoustics based analyzer, organic carbon (OC) & elemental carbon (EC) mass using thermo-optical analysis of quartz filter samples, solid particle number using European Union Regulation No. 49 compliant number system and solid particle size/number using an electrical mobility based size spectrometer.

Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.

With the rapid expansion of the automotive market in China, air quality in the major cities has become a severe concern. Great efforts have been made in introducing new emission regulations; however, fuel and lubricant qualities, emissions aftertreatment system durability and in-use compliance to the emissions regulations still require significant improvement. China follows the European Union (EU) emission regulations in general, but different levels of standards exist. This paper gives a comprehensive overview of the current and near-future heavy-duty diesel emission regulations, as well as fuel and lubricant specifications.

Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH₃ storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH₃ storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH₃ slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.

Diesel particulate filters (DPF) have been shown to effectively reduce particulate emissions from diesel engines. However, uncontrolled DPF regeneration can easily damage the DPF. In this paper, three different types of uncontrolled DPF regeneration are defined. They are: Type A: Uncontrolled high initial exotherm at the start of DPF regeneration, Type B: “Runaway” or uncontrolled regeneration, which takes place when the engine goes to idle during normal DPF regeneration, and Type C: Uneven soot distribution causing excess thermal stress during normal DPF regeneration. In this paper, different control strategies are developed for each of the three types of uncontrolled DPF regenerations. These control strategies include SOF control, exhaust flow pattern improvement, as well as EGR control through intake throttling and A/F ratio control.

As agencies continue to focus on emissions compliance, low NOX discussions have started to propagate beyond the on-highway market. Nonroad applications, which contribute to 29% of the PM emissions and 11% of the NOX emissions in California, are being reviewed to understand the technological challenges and requirements for improved emissions performance. To help facilitate a nonroad low NOX technology demonstration, information from current engine and aftertreatment technologies required a detailed assessment. The following work will discuss the emissions characterization results from two non-road engine platforms. The intention of this study was to compare the emissions species from different approaches designed to meet Tier 4 emissions regulations. The platforms reflect available technology for DPF and non-DPF aftertreatment architectures.

In recent years, Diesel Particulate Filter (DPF) systems have become the state-of-the-art technology to realize low particulate emission for light, medium or heavy-duty diesel vehicles. In addition to good filtration efficiency and thermo-mechanical robustness, the engine backpressure resulted from the DPF installation is an important parameter which directly impacts the fuel economy of the engine. The goal of this experimental test series was to determine the dependence of fuel consumption on engine backpressure resulted from a DPF installed on a heavy-duty application. The testing was executed on a MY2003 Volvo D12 heavy-duty diesel engine in an engine test cell at Southwest Research Institute (SwRI). Empty DPF cans were used with an exhaust valve to mimic the post turbo pressure levels for two different types of DPF materials at nine selected engine operating points of the European Stationary Cycle (ESC).

Recent legislation enacted for the European Union (EU) and the United States calls for a substantial reduction in particulate mass (and number in the EU) emissions from gasoline spark-ignited vehicles. The most prominent technology being evaluated to reduce particulate emissions from a gasoline vehicle is a wall flow filter known as a gasoline particulate filter (GPF). Similar in nature to a diesel particulate filter (DPF), the GPF will trap and store particulate emissions from the engine, and oxidize said particulate with frequent regeneration events. The GPF will also collect ash particles in the wall flow substrate, which are metallic components that cannot be oxidized into gaseous components. Due to high temperature operation and frequent regeneration of the GPF, the impact of ash on the GPF has the potential to be substantially different from the impact of ash on the DPF.

Formation of urea-derived deposits in selective catalytic reduction (SCR) aftertreatment systems continues to be problematic at temperatures at and below 215 °C. Several consequences of deposit formation include: NOx and NH3 slip, exhaust flow maldistribution, increased engine backpressure, and corrosion of aftertreatment components. Numerous methods have been developed to reduce deposit formation, but to date, there has been no solution for continuous low-temperature dosing of Urea-Water Solution (UWS). This manuscript presents a novel methodology for reducing low-temperature deposit formation in SCR aftertreatment systems. The methodology described herein involves incorporation and dissolution of an HNCO hydrolysis catalyst directly into the UWS. HNCO is a transient species formed by the thermolysis of urea upon injection of UWS into the aftertreatment system.