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Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

The interaction of turbulent premixed methane combustion with the surrounding flow field can be studied using optically accessible test rigs such as a rapid compression expansion machine (RCEM). The high flexibility offered by such a test rig allows its operation at various thermochemical conditions at ignition. However, limitations inherent to such test rigs due to the absence of an intake stroke do not allow turbulence production as found in IC-engines. Hence, means to introduce turbulence need to be implemented and the relevant turbulence quantities have to be identified in order to enable comparability with engine relevant conditions. A dedicated high-pressure direct injection of air at the beginning of the compression phase is considered as a measure to generate adjustable turbulence intensities at spark timing and during the early flame propagation.

The sustainability of Martian outposts development is strongly based on the capability of achieving a high level of autonomy both in terms of operations management and of resources availability. In situ production of consumables is a key point to allow humans to work and live on Mars avoiding or limiting the need for re-supplies of materials from Earth. Required consumables can be produced in situ exploiting the locally available resources, but also by means of green-houses and waste recycle systems. Dedicated robotic missions for in situ demonstration of this type of technologies are a fundamental step of the Martian In Situ Resources Utilization (ISRU) development roadmap. This paper is focused on the extraction of oxygen and fuels (e.g. methane) from the Martian atmosphere, and presents a feasibility study for a small technological demonstration plant.

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.

Hyundai has developed a Santa Fe fuel cell vehicle (FCV) in which methanol fuel processor is installed and integrated with PEM fuel cell system. Pure hydrogen is produced from the mixture of methanol and water by steam reforming followed by metal membrane purification and is then fed to fuel cell system to generate electrical energy. This system has the advantage of simplifying the integration of fuel cell subsystem and fuel processor subsystem. The operation of brassboard system has been carried out for performance evaluation and the development of fuel cell controller. And then the methanol reforming fuel cell system has been incorporated into electric drive train in the vehicle. AC induction motor is powered by the hybrid system using fuel cell and a nickel metal hydride battery as energy sources to improve the system efficiency and the acceleration response of the vehicle.

The scope of the work presented in this paper was to apply the latest open source CFD achievements to design a state of the art, direct-injection (DI), heavy-duty, natural gas-fueled engine. Within this context, an initial steady-state analysis of the in-cylinder flow was performed by simulating three different intake ducts geometries, each one with seven different valve lift values, chosen according to an estabilished methodology proposed by AVL. The discharge coefficient (Cd) and the Tumble Ratio (TR) were calculated in each case, and an optimal intake ports geometry configuration was assessed in terms of a compromise between the desired intensity of tumble in the chamber and the satisfaction of an adequate value of Cd. Subsequently, full-cycle, cold-flow simulations were performed for three different engine operating points, in order to evaluate the in-cylinder development of TR and turbulent kinetic energy (TKE) under transient conditions.

A fuel cell system consists of a stack, a hydrogen fuel supply and an air supply system. This provides the required air flow and pressure which allows the stack to properly react on the cathode side to recombine Oxygen with the Hydrogen's protons and electrons resulting in water and heat. In addition the air flow and pressure are supporting directly or indirectly the water management. In this paper different air supply systems for automotive application developed by NuCellSys are compared: screw compressor and electrical turbo charger. Different technologies and control strategies allow the fuel cell system integrator to find the optimum between performances, weight, volume and cost. The authors describe the challenges and the new frontier of air supply systems for automotive fuel cell system application.

In the field of heavy-duty applications almost all engines apply the compression ignition principle, spark ignition is used only in the niche of CNG engines. The main reason for this is the high efficiency advantage of diesel engines over SI engines. Beside this drawback SI engines have some favorable properties like lower weight, simple exhaust gas aftertreatment in case of stoichiometric operation, high robustness, simple packaging and lower costs. The main objective of this fundamental research was to evaluate the limits of a SI engine for heavy-duty applications. Considering heavy-duty SI engines fuel consumption under full load conditions has a high impact on CO₂ emissions. Therefore, downsizing is not a promising approach to improve fuel consumption and consequently the focus of this work lies on the enhancement of thermal efficiency in the complete engine map, intensively considering knocking issues.

In this paper experimental results of a medium duty single cylinder research engine with spark ignition are presented. The engine was operated with stoichiometric natural gas combustion and additional charge dilution by means of external and cooled exhaust gas recirculation (EGR). The first part of this work considers the benefits of cooled EGR on thermo-mechanical stress of the engine including exhaust gas temperature, cylinder head temperature, and knock behaviour. This is followed by the analysis of the influence of cooled EGR on the heat release rate. In this context the impact of fuel gas composition is also under investigation. The influence of increasing EGR on fuel efficiency, which is caused by a changed combustion process due to higher fractions of inert gases, is shown in this section. By application of different pistons a relationship between the piston bowl geometry and the flame propagation has been demonstrated.

Recently, flexible fuel vehicle (FFV) has been drawn great attention because of its response for immediate use as alternative fueled one. Hyundai FFV can be operated on arbitrary fuel mixtures between gasoline and M85 with the specially programmed electronic control unit (ECU) which can determine optimized fueling quantity and ignition timing as the methanol content by the signal from electrostatic type fuel sensor. In this paper, the results of various tests including engine performance, cold startability, durability and exhaust emission reduction have been described. Full load, cold mode durability tests and field trials have been carried out with some material changes and surface treatments in the lubricating parts and fuel system. But, more work on its durability improvement is still required.

This paper describes Hyundai's research and development work on a flexible fuel vehicle (FFV). The work on FFV has been conducted to evaluate its potential as an alternative to the conventional gasoline vehicle. Hyundai FFV described here can operate on M85, gasoline, or any of their combinations, in which the methanol concentration is measured by an electrostatic type fuel sensor. For that operation, a special FFV ECU has been developed and incorporated in the FFV. The characteristics affecting FFV operation, such as FFV ECU control strategy and injector flow rate, have been investigated and optimized by experiment. Various development tests have been performed in view of engine performance, durability, cold startability, and exhaust emissions reduction. The exhaust gas aftertreatment system being consisted of manifold type catalytic converter(MCC) and secondary air injection system has shown good emission reduction performance including formaldehyde emission.

In HMC, the fundamental research on the hydrogen fueled engine and vehicle has been carried out. For this engine, solenoid driven injector is used to supply gaseous hydrogen into the cylinder and various operating parameters have been changed to study the combustion characteristics of hydrogen. After these experiments on engine, hydrogen fueled vehicle has been constructed and it is controlled by ECU. The amount of emission from the hydrogen vehicle with stoichiometric operation is less than 1/3 of the ULEV legislation.

Since the last decade, alternative powertrains are playing an important role in the strategy of car manufacturers. One important goal is the introduction of zero emission powertrains. These powertrain systems raise increasing political and public interest with the hydrogen fuel cell engine being the most competitive powertrain technology. During the development of this new technology, all the functional aspects including the automotive vehicle safety need to be considered. Hydrogen sensors are installed in the system to optimize the performance of a hydrogen fuel cell system and to enhance the safety concept. New results of sensor optimization and innovative test and development methods based on real vehicle data are described in this paper.

Modification of gasoline blendstock composition in preparing ethanol-gasoline blends has a significant impact on vehicle exhaust emissions. In “splash” blending the blendstock is fixed, ethanol-gasoline blend compositions are clearly defined, and effects on emissions are relatively straightforward to interpret. In “match” blending the blendstock composition is modified for each ethanol-gasoline blend to match one or more fuel properties. The effects on emissions depend on which fuel properties are matched and what modifications are made, making trends difficult to interpret. The purpose of this paper is to illustrate that exclusive use of a match blending approach has fundamental flaws. For typical gasolines without ethanol, the distillation profile is a smooth, roughly linear relationship of temperature vs. percent fuel distilled.

In the recent years, the interest in heavy-duty engines fueled with Compressed Natural Gas (CNG) is increasing due to the necessity to comply with the stringent CO2 limitation imposed by national and international regulations. Indeed, the reduced number of carbon atoms of the NG molecule allows to reduce the CO2 emissions compared to a conventional fuel. The possibility to produce synthetic methane from renewable energy sources, or bio-methane from agricultural biomass and/or animal waste, contributes to support the switch from conventional liquid fuels to CNG. To drive the engine development and reduce the time-to-market, the employment of numerical analysis is mandatory. This requires a continuous improvement of the simulation models toward real predictive analyses able to reduce the experimental R&D efforts. In this framework, 1D numerical codes are fundamental tools for system design, energy management optimization, and so on.

Dimethyl ether (DME) represents a promising fuel for heavy-duty engines thanks to its high cetane number, volatility, absence of aromatics, reduced tank-to-wheel CO2 emissions compared to Diesel fuel and the possibility to be produced from renewable energy sources. However, optimization of compression-ignition engines fueled with DME requires suitable computational tools to design dedicated injection and combustion systems: reduced injection pressures and increased nozzle diameters are expected compared to conventional Diesel engines, which influences both the air-fuel mixing and the combustion process. This work intends to evaluate the validity of two different combustion models for the prediction of performance and pollutant emissions in compression-ignition engines operating with DME. The first one is the Representative Interactive Flamelet while the second is the Approximated Diffusive Flamelet.

Active prechamber combustion systems for SI engines represent a feasible and effective solution in reducing fuel consumption and pollutant emissions for both marine and ground heavy-duty engines. However, reliable and low-cost numerical approaches need to be developed to support and speed-up their industrial design considering their geometry complexity and the involved multiple flow length scales. This work presents a CFD methodology based on the RANS approach for the simulation of active prechamber spark-ignition engines. To reduce the computational time, the gas exchange process is computed only in the prechamber region to correctly describe the flow and mixture distributions, while the whole cylinder geometry is considered only for the power-cycle (compression, combustion and expansion). Outside the prechamber the in-cylinder flow field at IVC is estimated from the measured swirl ratio.

This work has the objective to present the extension of a novel quasi-dimensional model, developed to simulate the combustion process in diesel Compression Ignition (CI) engines, to describe this process when Dimethyl ether (DME) is used as fuel. DME is a promising fuel in heavy-duty CI engines application thanks to its high Cetane Number (CN), volatility, high reactivity, almost smokeless combustion, lower CO2 emission and the possibility to be produced with renewable energy sources. In this paper, a brief description of the thermodynamic model will be presented, with particular attention to the implementation of the Tabulated Kinetic Ignition (TKI) model, and how the various models interact to simulate the combustion process. The model has been validated against experimental data derived from constant-volume DME combustion, in this case the most important parameters analyzed and compared were the Ignition Delay (ID) and Flame Lift Off Length (FLOL).

After the second worldwide oil crisis, Brazil put in place by 1975 a strategic plan to stimulate the usage of ethanol (from sugar cane), to be mixed to the gasoline or to be sold as 100% ethanol fuel (known as E100). To enable an engine to operate with both gasoline and ethanol (and their mixtures), by 2003 the “Flex Fuel” technology was implemented. By 2012 calendar year, from a total of about 3.8 million vehicles sold in the Brazilian market, 91% offered the “Flex Fuel” technology, and great majority used a gasoline sub-tank to assist on cold starts (typically below 15°C, where more than 85% of ethanol is present in fuel tank). The gasoline sub-tank system suffers from issues such as gasoline deterioration, crash-worthiness and user inconvenience such as bad drivability during engine warm up phase. This paper presents fuel injector technologies capable of rapidly electrically heating the ethanol fuel for the Brazilian transportation market.