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Journal Article

Development and Testing of a Sorbent-Based Atmosphere Revitalization System 2008/2009

2009-07-12
2009-01-2445
The design and evaluation of a Vacuum-Swing Adsorption (VSA) system to remove metabolic water and metabolic carbon dioxide from a spacecraft atmosphere is presented. The approach for Orion and Altair is a VSA system that removes not only 100 percent of the metabolic CO2 from the atmosphere, but also 100% of the metabolic water as well, a technology approach that has not been used in previous spacecraft life support systems. The design and development of an Orion Crew Exploration Vehicle Sorbent Based Atmosphere Revitalization system, including test articles, a facility test stand, and full-scale testing in late 2008 and early 2009 is discussed.
Journal Article

Engineered Structured Sorbents for the Adsorption of Carbon Dioxide and Water Vapor from Manned Spacecraft Atmospheres: Applications and Testing 2008/2009

2009-07-12
2009-01-2444
Developmental efforts are seeking to improve upon the efficiency and reliability of typical packed beds of sorbent pellets by using structured sorbents and alternative bed configurations. The benefits include increased structural stability gained by eliminating clay bound zeolite pellets that tend to fluidize and erode, and better thermal control during sorption leading to increased process efficiency. Test results that demonstrate such improvements are described and presented.
Technical Paper

Dimethyl Ether as an Ignition Enhancer for Methanol-Fueled Diesel Engines

1991-10-01
912420
Methanol-fueled diesels may be an attractive means of meeting future, more restrictive diesel particulate standards since methanol combustion forms very little soot. Unfortunately, methanol's autoignition temperature is high, and some means of improving its ignition is required. Therefore, we have investigated the use of dimethyl ether (DME), aspirated with the combustion air, to enhance the ignition of the injected methanol. A small, on-board catalytic reactor could be used to generate DME from the methanol fuel. This system requires minimal modifications to the engine design, and does not require use of an additive or fuel other than methanol. In this study, we measured maximum cylinder pressure and rate of pressure rise, ignition delay, emissions, and relative efficiencies for a single-cylinder, direct injection, high-speed diesel engine operated on both diesel fuel and methanol-DME.
Technical Paper

Weathering of Thermal Control Coatings

2007-07-09
2007-01-3020
Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.
Technical Paper

Development of a Rapid Cycling CO2 and H2O Removal Sorbent

2007-07-09
2007-01-3271
The National Aeronautics and Space Administration's (NASA) planned future missions set stringent demands on the design of the Portable Life Support System (PLSS), requiring dramatic reductions in weight, decreased reliance on supplies and greater flexibility for Extravehicular Activity (EVA) duration and objectives. Use of regenerable systems that reduce weight and volume of the space suit life support system is of critical importance to NASA, both for low orbit operations and for long duration manned missions. The carbon dioxide and humidity control unit in the existing PLSS design is relatively large, since it has to remove and store eight hours worth of carbon dioxide (CO2). If the sorbent regeneration can be carried out during the EVA with a relatively high regeneration frequency, the size of the sorbent canister and weight can be significantly reduced.
Technical Paper

Continuously Regenerable Freeze-Out CO2 Control Technology

2007-07-09
2007-01-3270
Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.
Technical Paper

Development and Testing of a Sorbent-Based Atmosphere Revitalization System for the Crew Exploration Vehicle 2006/2007

2007-07-09
2007-01-3254
The design of a vacuum-swing adsorption process to remove metabolic water, metabolic carbon dioxide, and metabolic and equipment generated trace contaminant gases from the Orion Crew Exploration Vehicle (CEV) atmosphere is presented. For Orion, the approach is taken that all metabolic water must be removed by the Sorbent-Based Atmosphere Revitalization System (SBAR), a technology approach that has not been used in previous spacecraft life support systems. Design and development of a prototype SBAR, a facility test stand, and subsequent testing of the SBAR in late 2006 and early 2007 is discussed.
Technical Paper

A New Method for Breath Capture Inside a Space Suit Helmet

2007-07-09
2007-01-3248
This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg (.0226-.046 atm). This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet.
Technical Paper

Development of a Test Facility for Air Revitalization Technology Evaluation

2007-07-09
2007-01-3161
Development of new air revitalization system (ARS) technology can initially be performed in a subscale laboratory environment, but in order to advance the maturity level, the technology must be tested in an end-to-end integrated environment. The Air Revitalization Technology Evaluation Facility (ARTEF) at the NASA Johnson Space Center (JSC) serves as a ground test bed for evaluating emerging ARS technologies in an environment representative of spacecraft atmospheres. At the center of the ARTEF is a hypobaric chamber which serves as a sealed atmospheric chamber for closed loop testing. A Human Metabolic Simulator (HMS) was custom-built to simulate the consumption of oxygen, and production of carbon dioxide, moisture and heat by up to eight persons. A variety of gas analyzers and dew point sensors are used to monitor the chamber atmosphere and the process flow upstream and downstream of a test article. A robust vacuum system is needed to simulate the vacuum of space.
Technical Paper

Improvement of Risk Assessment from Space Radiation Exposure for Future Space Exploration Missions

2007-07-09
2007-01-3116
Protecting astronauts from space radiation exposure is an important challenge for mission design and operations for future exploration-class and long-duration missions. Crew members are exposed to sporadic solar particle events (SPEs) as well as to the continuous galactic cosmic radiation (GCR). If sufficient protection is not provided the radiation risk to crew members from SPEs could be significant. To improve exposure risk estimates and radiation protection from SPEs, detailed evaluations of radiation shielding properties are required. A model using a modern CAD tool ProE™, which is the leading engineering design platform at NASA, has been developed for this purpose. For the calculation of radiation exposure at a specific site, the cosine distribution was implemented to replicate the omnidirectional characteristic of the 4π particle flux on a surface.
Technical Paper

ISRU Production of Life Support Consumables for a Lunar Base

2007-07-09
2007-01-3106
Similar to finding a home on Earth, location is important when selecting where to set up an exploration outpost. Essential considerations for comparing potential lunar outpost locations include: (1) areas nearby that would be useful for In-Situ Resource Utilization (ISRU) oxygen extraction from regolith for crew breathing oxygen as well as other potential uses; (2) proximity to a suitable landing site; (3) availability of sunlight; (4) capability for line-of-sight communications with Earth; (5) proximity to permanently-shadowed areas for potential in-situ water ice; and (6) scientific interest. The Mons Malapert1 (Malapert Mountain) area (85.5°S, 0°E) has been compared to these criteria, and appears to be a suitable location for a lunar outpost.
Technical Paper

Development of a Pilot Scale Apparatus for Control of Solid Waste Using Low Temperature Oxidation

2007-07-09
2007-01-3135
In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.
Technical Paper

Demonstration of Oxygen Production on the Moon and Mars

1997-07-01
972498
Scientists and engineers at NASA are currently developing flight instruments which will demonstrate oxygen production on the Moon and Mars. REGA will extract oxygen from the lunar regolith, measure implanted solar wind and indigenous gases, and monitor the lunar atmosphere. MIP will demonstrate oxygen production on Mars, along with key supporting technologies including filtration, atmospheric acquisition and compression, thermal management, solar cell performance, and dust removal.
Technical Paper

Development and Testing of a Non-Expendable Contaminant Control System

1997-07-01
972433
The control of trace contaminants on the International Space Station (ISS) is carried out by a combination of activated carbon absorption and catalytic oxidation. The carbon bed absorbs most hydrocarbons, chloro and chlorofluorocarbons (CHCs and CFCs) while the catalytic oxidizer removes compounds such as methane, ethylene, ethane, and carbon monoxide that cannot be absorbed by the charcoal bed. Unfortunately, the Space Station catalyst of 0.5% palladium on alumina does not effectively oxidize CHCs and CFCs, and in fact is powerfully poisoned by them (Wright et al. 1996). Thus, even though the charcoal bed has little affinity for CFCs and CHCs, it must be sized to completely remove these compounds in order to protect the crew and prevent poisoning of the catalytic oxidizer. TDA Research Inc. (TDA), under contract to NASA-JSC, has designed, built, and tested an all-catalytic trace contaminant control system (TCCS) to be used in Phase III of the Early Human Testing Program.
Technical Paper

Utilizing Exploration Life Support Technology on ISS - a Bold New Approach

1998-07-13
981808
A new life support approach is proposed for use on the International Space Station (ISS). This involves advanced technologies for water recovery and air revitalization, tested at the Johnson Space Center (JSC), including bioprocessing, reverse-osmosis and distillation, low power carbon dioxide removal, non-expendable trace contaminant control, and carbon dioxide reduction.
Technical Paper

Development and Testing of a Sorbent-Based Atmosphere Revitalization System for the Crew Exploration Vehicle 2007/2008

2008-06-29
2008-01-2082
The design of a Vacuum-Swing Adsorption (VSA) system to remove metabolic water and metabolic carbon dioxide from the Orion Crew Exploration Vehicle (CEV) atmosphere is presented. The approach for Orion is a VSA system that removes not only 100 percent of the metabolic CO2 from the atmosphere, but also 100% of the metabolic water as well, a technology approach that has not been used in previous spacecraft life support systems. The design and development of the Sorbent Based Atmosphere Regeneration (SBAR) system, including test articles, a facility test stand, and full-scale testing in late 2007 and early 2008 is discussed.
Technical Paper

The Smoke Eater, A Sorbent/Catalyst for Recovery from Fires

2008-06-29
2008-01-2098
The possibility and consequences of a fire on board a spacecraft and the subsequent effects of the resultant toxic gases and smoke on the crew, equipment and mission is an ever-present hazard for the National Aeronautics and Space Administration (NASA). The necessity to remove these contaminants in the presence of high levels of humidity and carbon dioxide has prompted the development of a new prototype atmospheric filter (smoke eater) that can scrub acid gases, basic gases, and carbon monoxide from a spacecraft atmosphere in a post-fire event to a concentration below one half the Spacecraft Maximum Allowable Concentration (SMAC) levels. TDA Research, Inc. (TDA) is developing an advanced smoke eater to remove combustion byproducts. The material makeup of the smoke eater will also be applicable to spacecraft evacuation masks and the shipboard atmospheric revitalization system.
Technical Paper

Evaluation of Commercial Off-the-Shelf Ammonia Sorbents and Carbon Monoxide Oxidation Catalysts

2008-06-29
2008-01-2097
Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.
Technical Paper

Further Testing of an Amine-Based Pressure-Swing System for Carbon Dioxide and Humidity Control

2008-06-29
2008-01-2101
In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft, but additional data was needed on the operational characteristics of the package in a simulated spacecraft environment. One unit was tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the latter part of 2006. Those test results were reported in a 2007 ICES paper.
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