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Technical Paper

Cloud Point Depressants and their Effect on Diesel Fuel Properties

1998-10-19
982575
Many marketers of branded diesel fuels are introducing a “premium” diesel fuel grade. The National Conference on Weights and Measures is recommending that one of the criteria for marketing a fuel as “premium” is that it have a lower cloud point or alternatively a reduced low temperature flow test (LTFT) failure point [1]. However, waxy crudes and process limitations make it difficult for refiners to economically make very low cloud point diesel fuel. Fortunately, cloud point depressants (CPDs) can overcome these limitations. However, refiners are concerned about the effect cloud point additives have on other diesel fuel properties. We found that cloud point depressants allow refiners to meet low temperature specifications while being neutral or beneficial to other diesel fuel properties.
Technical Paper

Study of Diesel and Ethanol Blends Stability

2003-10-27
2003-01-3191
Characteristics of E diesel, a fuel blend of diesel fuel and ethanol, are considered in a matrix of tests. One characteristic of particular concern and a subject of this investigation is that of stability. Methods to evaluate stability are looked at and compared in light of the potential for distillate and ethanol to separate under certain conditions. The quality of the fuel blend is enhanced by the use of enabling additives to ensure stability which necessitates development of a standard for assessment of the quality of stability. The properties of various base diesel fuels and their influence on stability are also studied. Other key characteristics are evaluated including viscosity, pour point, and oxidative stability.
Technical Paper

Review of Exhaust Emissions of Compression Ignition Engines Operating on E Diesel Fuel Blends

2003-10-27
2003-01-3283
Recently, research and testing of oxygenated diesel fuels has increased, particularly in the area of exhaust emissions. Included among the oxygenated diesel fuels are blends of diesel fuel with ethanol, or E diesel fuels. Exhaust emissions testing of E diesel fuel has been conducted by a variety of test laboratories under various conditions of engine type and operating conditions. This work reviews the existing public data from previous exhaust emissions testing on E diesel fuel and includes new testing performed in engines of varied design. Emissions data compares E diesel fuel with normal diesel fuel under conditions of different engine speeds, different engine loads and different engine designs. Variations in performance under these various conditions are observed and discussed with some potential explanations suggested.
Technical Paper

Developing Next Generation Axle Fluids, Part III: Laboratory CAFE Simulation Test as a Key Fluid Development Tool

2003-10-27
2003-01-3235
The regulatory drive for emission reductions, increased fuel costs, and likely increases in Corporate Average Fuel Economy (CAFE) requirements have made fuel efficiency a key issue for North American vehicle manufacturers and marketers. At the same time the popularity of sport utility vehicles and light trucks has made it more difficult to achieve CAFE objectives. In order to accommodate both public vehicle preference and government mandated CAFE requirements automobile manufacturers are seeking all available means to increase fuel economy through advanced system design, engineered materials, and improved lubricant technology. Axle lubricants can have a significant impact on fuel economy; moreover, axle lubricants can be tailored to deliver maximum operating efficiency over either specific or wide ranges of operating conditions.
Technical Paper

Combustion Modeling of Soot Reduction in Diesel and Alternate Fuels using CHEMKIN®

2001-03-05
2001-01-1239
A new gas phase kinetic model using Westbrook's gas phase n-heptane model and Frenklach's soot model was constructed. This model was then used to predict the impact on PAH formation as an indices of soot formation on ethanol/diesel fuel blends. The results were then compared to soot levels measured by various researchers. The ignition delay characteristics of ethanol were validated against experimental results in the literature. In this paper the results of the model and the comparison with experimental results will be discussed along with implications on the method of incorporation of additives and alternative fuels.
Technical Paper

Using Cloud Point Depressants Opportunistically To Reduce No.2 Diesel Fuel Cloud Point Giveaway

2001-05-07
2001-01-1927
Diesel fuel is a blend of various middle distillate components separated at the refinery. The composition and characteristics of the diesel fuel blend changes daily if not hourly because of normal process variation, changing refinery processing conditions, changing crude oil diet or changing diesel fuel and kerosene market conditions. Regardless of the situation going on at the refinery or the market, the resultant diesel fuel must consistently meet established cloud point specifications. To consistently meet the cloud point specifications, refiners are forced to blend their diesel fuels in such a way that the resultant blend is always on the low side of the cloud point specification even when the refining process adversely changes the fuel characteristics. This practice has the effect of producing several degrees of cloud point “giveaway” when the refinery is not experiencing adverse swings in product quality.
Technical Paper

Developing Next Generation Axle Fluids: Part I - Test Methodology to Measure Durability and Temperature Reduction Properties of Axle Gear Oils

2002-05-06
2002-01-1691
Light trucks and sport utility vehicles (SUVs) have become extremely popular in the United States in recent years, but this shift to larger passenger vehicles has placed new demands upon the gear lubricant. The key challenge facing vehicle manufacturers in North America is meeting government-mandated fuel economy requirements while maintaining durability. Gear oils must provide long-term durability and operating temperature control in order to increase equipment life under severe conditions while maintaining fuel efficiency. This paper describes the development of a full-scale light duty axle test that simulates a variety of different driving conditions that can be used to measure temperature reduction properties of gear oil formulations. The work presented here outlines a test methodology that allows gear oil formulations to be compared with each other while accounting for axle changes due to wear and conditioning during testing.
Technical Paper

Developing Next Generation Axle Fluids – Part II - Systematic Formulating Approach

2002-05-06
2002-01-1692
Light trucks and sport utility vehicles (SUVs) have become extremely popular in the United States in recent years, but this shift to larger passenger vehicles has placed new demands upon the gear lubricant. The key challenge facing vehicle manufacturers in North America is meeting government-mandated fuel economy requirements while maintaining the durability required for severe service. In light truck/SUV applications, gear oils must provide operating temperature control under extreme conditions such as trailer-towing. Higher operating temperatures for prolonged periods can adversely affect metallurgical properties and reduce fluid film thickness, both of which can lead to premature equipment failures. In our view, operating temperature is an important indicator of durability. Unfortunately, lubricants optimized for temperature control do not always provide the best fuel economy.
Technical Paper

Lubricity and Injector Pump Wear Issues with E diesel Fuel Blends

2002-10-21
2002-01-2849
The search for alternative energy sources, particularly renewable sources, has led to increased activity in the area of ethanol blended diesel fuel, or E diesel. E diesel offers potential benefits in reducing greenhouse gases, reducing dependence on crude oil and reducing engine out emissions of particulate matter. However, there are some concerns about the use of E diesel in the existing vehicle fleet. One of the chief concerns of the use of E diesel is the affect of the ethanol on the lubricating properties of the fuel and the potential for fuel system wear. Additive packages that are used to formulate E diesel fuels can improve fuel lubricity and prevent abnormal fuel system wear. This work studies the lubricity properties of several E diesel blends and the diesel fuels that are used to form them. In addition to a variety of bench scale lubricity tests, injector pump tests were performed as an indicator of long term durability in the field.
Technical Paper

Effects of PuriNOx™ Water-Diesel Fuel Emulsions on Emissions and Fuel Economy in a Heavy-Duty Diesel Engine

2002-10-21
2002-01-2891
The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.
Technical Paper

Effects of Water-Fuel Emulsions on Spray and Combustion Processes in a Heavy-Duty DI Diesel Engine

2002-10-21
2002-01-2892
Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.
Technical Paper

Counteracting detrimental EGR effects with diesel fuel additive

2003-05-19
2003-01-1915
A new generation of fluid technology using novel diesel fuel detergent/dispersant chemistry provides a multitude of beneficial effects to the diesel engine, especially the latest model designs. In addition to improved injector, valve and combustion chamber deposit removal, the additive restores power, fuel economy, performance and emission levels1. Positive observations have also been documented along with improved performance concerning crankcase lube viscosity, soot loading and TBN retention. An even greater added benefit is the inherent capability of the fuel additive to deal with several EGR issues now prominent with the introduction of new engines. Recent research, reported herein, has uncovered the extensive efficacy of this chemistry for piston durability and neutralization of ring corrosion phenomena. All of the beneficial additive attributes are further enhanced with increased oxidative and thermal fuel stability and no loss of filterability.
Technical Paper

Next Generation Torque Control Fluid Technology, Part II: Split-Mu Screening Test Development

2006-10-16
2006-01-3271
The popularity of SUVs and light trucks in North America, combined with the return to rear-wheel-drive cars globally, is significantly increasing the installation of torque control devices that improve vehicle stability and drivability. As with other driveline hardware, it is important to optimize the friction material-lubricant-hardware system to ensure that a torque control device provides consistent performance over the life of the vehicle. While there are many publications on friction tests relevant to automatic transmission fluids, the literature relating to torque control testing is not as well developed. In this paper, we will describe a split-mu vehicle test and the development of a split-mu screening test. The screening test uses the SAE#2 friction test rig and shows how results from this test align with those from actual vehicle testing.
Technical Paper

A Study of Axle Fluid Viscosity and Friction Impact on Axle Efficiency

2016-04-05
2016-01-0899
The growing need for improved fuel economy is a global challenge due to continuously tightening environmental regulations targeting lower CO2 emission levels via reduced fuel consumption in vehicles. In order to reach these fuel efficiency targets, it necessitates improvements in vehicle transmission hardware components by applying advanced technologies in design, materials and surface treatments etc., as well as matching lubricant formulations with appropriate additive chemistry. Axle lubricants have a considerable impact on fuel economy. More importantly, they can be tailored to deliver maximum operational efficiency over specific or wide ranges of operating conditions. The proper lubricant technology with well-balanced chemistries can simultaneously realize both fuel economy and hardware protection, which are perceived to have a trade-off relationship.
Technical Paper

Next Generation Torque Control Fluid Technology, Part I: Break-Away Friction Screening Test Development

2006-10-16
2006-01-3270
The popularity of SUVs and light trucks in North America, combined with the return to rear-wheel-drive cars globally, is significantly increasing the installation rates of torque control devices that improve vehicle stability and drivability. As with other driveline hardware, it is important to optimize the friction material-lubricant-hardware system in order to ensure that a torque control device provides consistent performance over the life of the vehicle. While there are many publications on friction tests relevant to automatic transmission fluids, the literature relating to torque control testing is not as well developed. In this paper we will describe the development of a break-away friction screening test using a Full-Scale Low-Velocity Friction Apparatus (FS-LVFA). Additionally, we will illustrate how this screening test can be used to investigate the fundamental friction material-lubricant interactions that occur in continuously engaged limited slip differentials.
Technical Paper

Cloud Point Depressant Response Effects in Ultra-Low-Sulfur Diesel Fuel

2005-10-24
2005-01-3898
Cloud point depressants (CPD) have been successfully used for many years in low-sulfur diesel fuels. For over ten years, custom-designed, specialty polymer chemistry has enabled refiners to meet cloud point (CP) guidelines with substantially less kerosene. This translates into greater refined yields through cut-point adjustment upgrades and the potential for diverting kerosene to more lucrative market opportunities, such as jet fuel. The practice of cut-point downgrades to gas oil can be costly because diesel fuel generally has greater value. Kerosene dilutions have historically been as high as 30%-40% by volume with low-sulfur diesel fuels [1, 2]. While kerosene addition enables fuels to reach CP guidelines, it may negatively impact the fuel's energy content, cetane number, lubricity, flash point and density. Properly designed CP additives are able to substantially reduce or even eliminate the need for kerosene, thus substantially reducing refinery costs.
Technical Paper

Breaking the Viscosity Paradigm: Formulating Approaches for Optimizing Efficiency and Vehicle Life

2005-10-24
2005-01-3860
The popularity of light trucks and sport utility vehicles (SUVs), coupled with growing consumer demand for vehicles with more size, weight and horsepower, has challenged the original equipment manufacturers' (OEM) ability to meet the Corporate Average Fuel Economy (CAFE) specifications due to the increased contribution of these vehicle classes on fleet averages. The need for improved fuel economy is also a global issue due to the relationship of reduced fuel consumption to reduced CO2 emissions. Vehicle manufacturers are challenged to match the proper fluid with the application to provide the required durability protection while maximizing fuel efficiency. Recent new viscosity classifications outlined under SAE J306 aid in more tightly defining options for lubricant choice for a given application. Changes to the SAE J306 viscosity classification define new intermediate viscosity grades, SAE 110 and SAE 190.
Technical Paper

The Impact of Lubricant and Fuel Derived Sulfur Species on Efficiency and Durability of Diesel NOx Adsorbers

2004-10-25
2004-01-3011
Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.
Technical Paper

Systematic Formulation of Efficient and Durable Axle Lubricants for Light Trucks and Sport Utility Vehicles

2004-10-25
2004-01-3030
Consumer demand for size, weight and horsepower has dictated a prominent role for sport utility vehicles and light trucks in the product lines of major North American automobile manufacturers. Inherently less efficient than passenger cars, these vehicles will be facing more stringent light duty CAFE (Corporate Average Fuel Economy) standards beginning in 2005 when mileage targets will be elevated to 21 mpg; this figure will be further increased to 22.2 mpg by 2007. In order to accommodate both public demand and CAFE requirements, vehicle manufacturers are seeking ways to improve fuel economy through design and material modifications as well as through improvements in lubrication. The axle lubricant may have an important impact on fuel economy, and axle lubricants can be tailored to deliver higher levels of operating efficiency over a wide range of conditions.
Technical Paper

Energy Conservation Through The Use of Multigraded Gear Oils In Trucks

1977-02-01
770833
Studies of selected automotive gear lubricants in heavy truck tandem axles and transmissions have revealed improvements in fuel economy associated with the viscosity of lubricants tested (grades 75W, 75W-90, and 80W-140). The testing included a heavy truck on-highway fleet test and test track operation. Standard laboratory gear tests on light viscosity monograde (SAE 75W) oils indicate that oils of this type may be deficient in EP protection. Combined observations show that there may be a critical balance between axle lubricant fuel economy benefits and axle durability in field service.
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