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Journal Article

GC-MS Speciation and Quantification of 1,3 Butadiene and Other C1-C6 Hydrocarbons in SI / HCCI V6 Engine Exhaust

2008-04-14
2008-01-0012
It is known that the levels of hydrocarbon (HC) emissions from Homogeneous Charge Compression Ignition (HCCI) engines are relatively higher than that of Spark-Ignition (SI) engines because of the lower combustion temperature. In order to improve understanding of the mechanisms and products of HCCI combustion in comparison with SI combustion, a quantitative analysis of individual hydrocarbons in the C1 - C6 range emitted in the exhaust gases of gasoline direct injection V6 engine operating in SI and HCCI modes with cam profile switching has been carried out using gas chromatography - mass spectrometry (GCMS) apparatus attached on-line to engine exhaust. In this study, with a GC run time of 20 minutes all aliphatic and olefinic hydrocarbon species in the range C1 to C6 are resolved.
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