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Journal Article

Laboratory Study of Soot, Propylene, and Diesel Fuel Impact on Zeolite-Based SCR Filter Catalysts

2009-04-20
2009-01-0903
Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.
Journal Article

Enhanced Durability of a Cu/Zeolite Based SCR Catalyst

2008-04-14
2008-01-1025
Passenger and light duty diesel vehicles will require up to 90% NOx conversion over the Federal Test Procedure (FTP) to meet future Tier 2 Bin 5 standards. This accomplishment is especially challenging for low exhaust temperature applications that mostly operate in the 200 - 350°C temperature regime. Selective catalytic reduction (SCR) catalysts formulated with Cu/zeolites have shown the potential to deliver this level of performance fresh, but their performance can easily deteriorate over time as a result of high temperature thermal deactivation. These high temperature SCR deactivation modes are unavoidable due to the requirements necessary to actively regenerate diesel particulate filters and purge SCRs from sulfur and hydrocarbon contamination. Careful vehicle temperature control of these events is necessary to prevent unintentional thermal damage but not always possible. As a result, there is a need to develop thermally robust SCR catalysts.
Journal Article

Technical Advantages of Vanadium SCR Systems for Diesel NOx Control in Emerging Markets

2008-04-14
2008-01-1029
Selective catalytic reduction (SCR) is a promising technology for diesel aftertreatment to meet NOx emissions targets in several countries. In established markets such as the US and Europe, zeolite SCR systems are expected to be used due to their ability to survive the exhaust gas temperatures seen in an active diesel particulate filter regeneration. In emerging markets where the fuel sulfur level may be as high as 2000 parts per million, zeolite SCR catalysts may have durability issues. In these markets, low sulfur fuel is needed overall to meet emissions standards and to avoid high sulfate emissions, but the aftertreatment system must be durable to high sulfur levels because there is a risk of exposure to high sulfur fuel. Also, emissions standards may be met without a DPF in some applications, so that the exhaust system would not see temperatures of 600°C or higher.
Journal Article

Detection, Origin and Effect of Ultra-Low Platinum Contamination on Diesel-SCR Catalysts

2008-10-06
2008-01-2488
This paper discusses the poisoning of a selective catalytic reduction (SCR) catalyst by trace levels of platinum originating from an upstream diesel oxidation catalyst (DOC). A diesel aftertreatment system consisting of a DOC, urea based SCR Catalyst and a DPF was aged and evaluated on a 6.4 liter diesel engine dynamometer. The SCR catalyst system consisted of an Fe-zeolite catalyst followed by a Cu-zeolite catalyst. After approximately 400 hours of engine operation at varied exhaust flow rates and temperatures, deactivation of the SCR catalyst was observed. A subsequent detailed investigation revealed that the Cu catalyst was not deactivated and the front half of the Fe-based catalyst showed severe deactivation. The deactivated portion of the catalyst showed high activity of NH3 conversion to NOx and N2O formation. The cause of the deactivation was identified to be the presence of trace Pt contamination.
Journal Article

Experimental Evaluation of Advanced Turbocharger Performance on a Light Duty Diesel Engine

2013-04-08
2013-01-0920
For diesel engines to meet current and future emissions levels, the amount of EGR required to reach these levels has increased dramatically. This increased EGR has posed big challenges for conventional turbocharger technology to meet the higher emissions requirements while maintaining or improving other vehicle attributes, to the extent that some OEMs resort to multiple turbocharger configurations. These configurations can include parallel, series sequential, or parallel - series turbocharger systems, which would inevitably run into other issues, such as cost, packaging, and thermal loss, etc. This study, as part of a U.S. Department of Energy (USDoE) sponsored research program, is focused on the experimental evaluation of the emission and performance of a modern diesel engine with an advanced single stage turbocharger.
Technical Paper

The Influence of Ammonia Slip Catalysts on Ammonia, N2O and NOX Emissions for Diesel Engines

2007-04-16
2007-01-1572
The use of urea-based selective catalytic reduction (SCR) is a promising method for achieving U.S. Tier 2 diesel emission standards for NOx. To meet the Tier 2 standards for Particulate Matter (PM), a catalyzed diesel particulate filter (CDPF) will likely be present and any ammonia (NH3) that is not consumed over an SCR catalyst would pass over the CDPF to make nitrous oxide (N2O) emissions and/or oxides of nitrogen (NOx), or exit the exhaust system as NH3. N2O is undesirable due to its high greenhouse gas potential, while NOx production from the slipped NH3 would reduce overall system NOx conversion efficiency. This paper reviews certain conditions where NH3 slip past an SCR system may be a concern, looks at what would happen to this slipped NH3 over a CDPF, and evaluates the performance of various supplier NH3 slip catalysts under varied space velocities, temperatures and concentrations of NH3 and NOx.
Technical Paper

Development of Emission Transfer Functions for Predicting the Deterioration of a Cu-Zeolite SCR Catalyst

2009-04-20
2009-01-1282
Urea selective catalytic reduction (SCR) catalysts have the capability to deliver the high NOx conversion efficiencies required for future emission standards. However, the potential for the occasional over-temperature can lead to the irreversible deactivation of the SCR catalyst. On-board diagnostics (OBD) compliance requires monitoring of the SCR function to make sure it is operating properly. Initially, SCR catalyst performance metrics such as NOx conversion, NH3 oxidation, NH3 storage capacity, and BET surface area are within normal limits. However, these features degrade with high temperature aging. In this work, a laboratory flow reactor was utilized to determine the impact on these performance metrics as a function of aging condition. Upon the completion of a full time-at-temperature durability study, four performance criteria were established to help determine a likely SCR failure.
Technical Paper

Numerical Study of Ultra Low Solidity Airfoil Diffuser in an Automotive Turbocharger Compressor

2009-04-20
2009-01-1470
For the application of advanced clean combustion technologies, such as diesel HCCI/LTC, a compressor with high efficiency over a broad operation range is required to supply a high amount of EGR with minimum pumping loss. A compressor with high pitch of vaneless diffuser would substantially improve the flow range of the compressor, but it is at the cost of compressor efficiency, especially at low mass flow area where most of the city driving cycles resides. In present study, an ultra low solidity compressor vane diffuser was numerically investigated. It is well known that the flow leaving the impeller is highly distorted, unsteady and turbulent, especially at relative low mass flow rate and near the shroud side of the compressor. A conventional vaned diffuser with high stagger angle could help to improve the performance of the compressor at low end. However, adding diffuser vane to a compressor typically restricts the flow range at high end.
Technical Paper

Cu/Zeolite SCR on High Porosity Filters: Laboratory and Engine Performance Evaluations

2009-04-20
2009-01-0897
Selective catalytic reduction (SCR) is expected to be used extensively in the U.S. for diesel vehicle NOx control. Much progress has been made on improving performance and reducing complexity of SCR systems for vehicles in the past several years. SCR system complexity can be reduced further by implementation of SCR-coated diesel particulate filters (SCRFs). In this system, a high porosity (> 50%) filter substrate is coated with an SCR formulation, ideally in the pores of the filter walls, so that the DPF and SCR functions can be combined into a single catalyst. Two state-of-the-art Cu/zeolite SCR formulations and three types of high porosity filter substrates were included in this study. Laboratory and engine-dynamometer tests were performed to measure NOx conversion under a variety of conditions to assess the impact of ammonia oxidation, inlet NO2/NOx ratio, ammonia/NOx ratio, oxygen level, space velocity, soot loading, and ammonia loading level.
Technical Paper

Numerical Investigation of the Impact of Nozzle Endwall Clearance Distribution on Variable Nozzle Turbine Performance

2017-03-28
2017-01-1034
As the variable nozzle turbine(VNT) becomes an important element in engine fuel economy and engine performance, improvement of turbine efficiency over wide operation range is the main focus of research efforts for both academia and industry in the past decades. It is well known that in a VNT, the nozzle endwall clearance has a big impact on the turbine efficiency, especially at small nozzle open positions. However, the clearance at hub and shroud wall sides may contribute differently to the turbine efficiency penalty. When the total height of nozzle clearance is fixed, varying distribution of nozzle endwall clearance at the hub and shroud sides may possibly generate different patterns of clearance leakage flow at nozzle exit that has different interaction with and impact on the main flow when it enters the inducer.
Technical Paper

Study on the Interaction of Clearance Flow and Shock Wave in a Turbine Nozzle

2017-03-28
2017-01-1039
Radial flow Variable Nozzle Turbine (VNT) enables better matching between the turbocharger and engine. At partial loading or low-end engine operating points, the nozzle vane opening of the VNT is decreased to achieve higher turbine efficiency and transient response, which is a benefit for engine fuel consumption and emission. However, under certain small nozzle opening conditions (such as nozzle brake and low-end operating points), strong shock waves and strong nozzle clearance flow are generated. Consequently, strong rotor-stator interaction between turbine nozzle and impeller is the key factor of the impeller high cycle fatigue and failure. In present paper, flow visualization experiment is carried out on a linear turbine nozzle. The turbine nozzle is designed to have single-sided clearance, and the Schlieren visualization method is used to describe the formation and development process of clearance flow and shock wave under different clearance and expansion ratio configurations.
Technical Paper

Selective Catalytic Reduction Control with Multiple Injectors

2017-03-28
2017-01-0943
Over the past decade urea-based selective catalytic reduction (SCR) has become a leading aftertreatment solution to meet increasingly stringent Nitrogen oxide (NOx) emissions requirements in diesel powertrains. A common trend seen in modern SCR systems is the use of "split-brick" configurations where two SCR catalysts are placed in thermally distinct regions of the aftertreatment. One catalyst is close-coupled to the engine for fast light-off and another catalyst is positioned under-floor to improve performance at high space velocities. Typically, a single injector is located upstream of the first catalyst to provide the reductant necessary for efficient NOx reduction. This paper explores the potential benefit, in terms of improved NOx reduction, control of NH3 slip or reduced reductant consumption, of having independently actuated injectors in front of each catalyst.
Technical Paper

Limitations of Real-Time Engine-Out NOx Estimation in Diesel Engines

2017-03-28
2017-01-0963
Many excellent papers have been written about the subject of estimating engine-out NOx on diesel engines based on real-time available data. The claimed accuracy of these models is typically around 6-10% on validation data sets with known inputs. This reported accuracy typically ignores input uncertainties, thus arriving at an optimistic estimate of the model accuracy in a real-time application. In our paper we analyze the effect of input uncertainty on the accuracy of engine-out NOx estimates via a numerical Monte Carlo simulation and show that this effect can be significant. Even though our model is based on an in-cylinder pressure sensor, this sensor is limited in its capability to reduce the effect of other measured inputs on the model.
Technical Paper

Optimization of Gaussian Process Regression Model for Characterization of In-Vehicle Wet Clutch Behavior

2022-03-29
2022-01-0222
The advancement of Machine-learning (ML) methods enables data-driven creation of Reduced Order Models (ROMs) for automotive components and systems. For example, Gaussian Process Regression (GPR) has emerged as a powerful tool in recent years for building a static ROM as an alternative to a conventional parametric model or a multi-dimensional look-up table. GPR provides a mathematical framework for probabilistically representing complex non-linear behavior. Today, GPR is available in various programing tools and commercial CAE packages. However, the application of GPR is system dependent and often requires careful design considerations such as selection of input features and specification of kernel functions. Hence there is a need for GPR design optimization driven by application requirements. For example, a moving window size for training must be tuned to balance performance and computational efficiency for tracking changing system behavior.
Technical Paper

An Assessment of the Impact of Exhaust Turbine Redesign, for Narrow VGT Operating Range, on the Performance of Diesel Engines with Assisted Turbocharger

2019-04-02
2019-01-0326
Electrically assisted turbochargers are a promising technology for improving boost response of turbocharged engines. These systems include a turbocharger shaft mounted electric motor/generator. In the assist mode, electrical energy is applied to the turbocharger shaft via the motor function, while in the regenerative mode energy can be extracted from the shaft via the generator function, hence these systems are also referred to as regenerative electrically assisted turbochargers (REAT). REAT allows simultaneous improvement of boost response and fuel economy of boosted engines. This is achieved by optimally scheduling the electrical assist and regeneration actions. REAT also allows the exhaust turbine to operate within a narrow range of optimal vane positions relative to the unassisted variable geometry turbocharger (VGT). The ability to operate within a narrow range of VGT vane positions allows an opportunity for a more optimal turbine design for a REAT system.
Journal Article

Impact and Prevention of Ultra-Low Contamination of Platinum Group Metals on SCR Catalysts Due to DOC Design

2009-04-20
2009-01-0627
Diesel aftertreatment systems configured with a diesel oxidation catalyst (DOC) upstream of an urea selective catalytic reduction (SCR) catalyst run the risk of precious metal contamination. During active diesel particulate filter (DPF) regeneration events, the DOC bed temperature can reach up to 850°C. Under these conditions, precious metal (especially Pt) can be volatized and then deposited on a downstream SCR catalyst. In this paper, the impact of ultra-low contamination of platinum group metals (PGM) on the SCR catalyst was studied. A method based on precious metal volatilization of a Pt-rich DOC at 850°C and under lean gas conditions was employed to contaminate downstream FeSCR and CuSCR formulations. The contamination resulted in poor NOx conversion (via NOx remake) and excessive N2O formation. The precious metal volatilization method was employed to screen various Pt/Pd based DOCs to avoid contamination of the downstream FeSCR.
Journal Article

Smart DPF Regenerations - A Case Study of a Connected Powertrain Function

2019-04-02
2019-01-0316
The availability of connectivity and autonomy enabled resources, within the automotive sector, has primarily been considered for driver assist technologies and for extending the levels of vehicle autonomy. It is not a stretch to imagine that the additional information, available from connectivity and autonomy, may also be useful in further improving powertrain functions. Critical powertrain subsystems that must operate with limited or uncertain knowledge of their environment stand to benefit from such new information sources. Unfortunately, the adoption of this new information resource has been slow within the powertrain community and has typically been limited to the obvious problem choices such as battery charge management for electric vehicles and efforts related to fuel economy benefits from adaptive/coordinated cruise control. In this paper we discuss the application of connectivity resources in the management of an aftertreatment sub-system, the Diesel Particulate Filter (DPF).
Journal Article

Machine Learning Approach for Constructing Wet Clutch Torque Transfer Function

2021-04-06
2021-01-0712
A wet clutch is an established component in a conventional powertrain. It also finds a new role in electrified systems. For example, a wet clutch is utilized to couple or decouple an internal combustion engine from an electrically-driven drivetrain on demand in hybrid electric vehicles. In some electrical vehicle designs, it provides a means for motor speed reduction. Wet clutch control for those new applications may differ significantly from conventional strategy. For example, actuator pressure may be heavily modulated, causing the clutch to exhibit pronounced hysteresis. The clutch may be required to operate at a very high slip speed for unforeseen behaviors. A linear transfer function is commonly utilized for clutch control in automating shifting applications, assuming that clutch torque is proportional to actuator pressure. However, the linear model becomes inadequate for enabling robust control when the clutch behavior becomes highly nonlinear with hysteresis.
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