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Battery models are often applied to describe the dynamic characteristics of batteries and can be used to predict the state of the battery. Due to the process of charging and discharging, the battery heat generation will cause the inhomogeneity between inner battery temperature and surface temperature. In this paper, a novel battery impedance model, which takes the impact of the battery internal temperature gradient on battery impedance into account, is proposed to improve the battery model performance. Several experiments are designed and conducted for pouch typed battery to investigate the electrochemical impedance spectroscopy (EIS) characteristics with the artificial temperature gradient (using a heating plate). Experimental results indicate that the battery internal temperature gradient will influence battery EIS regularly.

Lithium-ion battery charging strategy affects charging time of electric vehicles, energy efficiency of entire vehicle, service life and safety. This paper focuses on the lithium iron phosphate (LiFePO4) battery, based on the battery internal mechanism and the working conditions, taking charging time, effective full-charge capacity and charge energy efficiency as the evaluation indexes. Firstly, through a series of comparative experiments of the constant-current constant-voltage and the constant current charging strategy, the evaluation indexes variations in different temperatures and charging currents have been studied in the paper. By analyzing the respective characteristics of constant current charging phase and constant voltage charging phase in the whole charging process and their own contributions, we have found out the superiority of the constant current charging strategy.

The application of Li(Ni0.8Co0.1Mn0.1)O2 (NCM811) cathode-based lithium-ion batteries (LIBs) has alleviated electric vehicle range anxiety. However, the subsequent thermal safety issues limit their market acceptance. A detailed analysis of the failure evolution process for large-format LIBs is necessary to address the thermal safety issue. In this study, prismatic cells with nominal capacities of 144Ah and 125Ah are used to investigate the thermal runaway (TR) characteristics triggered by lateral overheating. Additionally, TR characteristics under two states of charge (SoCs) (100% and 5%) are discussed. Two cells with 100% SoC exhibit similar characteristics, including high failure temperature, high inhomogeneity of temperature distribution, multi-points jet fire, and significant mass loss. Two cells with 5% SoC demonstrate only a slight rupture of the safety valve and the emission of white smoke.