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With the continuous upgrading of emission regulations, NOx emission limit is becoming more and more strict, especially in the cold start phase. Passive NOx absorber (PNA) can adsorb NOx at a relatively low exhaust temperature, electrically heated catalyst (EHC) has great potential to improve exhaust gas temperature and reduce pollutant emissions of diesel engines at cold start conditions, while experimental research on the combined use of these two kinds of catalysts and the coupling mode of the electrically heated catalyst and the aftertreatment system under the cold start condition are lacking. In this paper, under a certain cold start and medium-high temperature phase, the exhaust gas temperature and emission characteristics of PNA, EHC and aftertreatment system under different coupling modes were studied.