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The effects of high boiling point fuel additives on deposits were investigated in a commercial turbocharged direct injection gasoline engine. It is known that high boiling point substances have a negative effect on deposits. The distillation end points of blended fuels containing these additives may be approximately 15°C higher than the base fuel (end point: 175°C). Three additives with boiling points between 190 and 196°C were examined: 4-tert-Butyltoluene (TBT), N-Methyl Aniline (NMA), and 2-Methyl-1,5-pentanediamine (MPD). Aromatics and anilines, which may be added to gasoline to increase its octane number, might have a negative effect on deposits. TBT has a benzene ring. NMA has a benzene ring and an amino group. MPD, which has no benzene ring and two amino groups, was selected for comparison with the former two additives.

In order to clarify the diesel fuel spray characteristics inside the cylinder, we developed two novel techniques, which are preparation of same level of temperature and pressure ambient as inside cylinder and quantitative measurement of vapor concentration. The first one utilizes combustion-type constant-volume chamber (inner volume 110cc), which allows 5 MPa and 873K by igniting the pre-mixture (n-pentane and air) with two spark plugs. In the second technique, TMPD vapor concentration is measured by using Laser Induced Exciplex Fluorescence method (LIEF). The concentration is compensated by investigation of the influence of ambient pressure (from 3 to 5 MPa) and temperature (from 550 to 900 K) on TMPD fluorescence intensity. By using two techniques, we investigated the influence of nozzle hole diameter, injection pressure and ambient condition on spray characteristics.