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Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

The emission regulations for diesel engines are continually becoming stricter to reduce pollution and conserve energy. To meet these increasingly stringent regulations, a new exhaust after-treatment device is needed. Recently, the authors proposed the simultaneous electrochemical reduction (ECR) system for diesel particulate matter (PM) and NOx. In this method, a gas-permeable electrochemical cell with a porous solid oxide electrolyte is used for PM filtering on the anode. Alkaline earth metal is coated on the cathode for NOx storage. Application of voltage to both electrodes enables the simultaneous reduction of PM and NOx by the forced flow of oxygen ions from the cathode to the anode (oxygen pumping). In this study, the basic characteristics of the ECR system were investigated, and a disk-shaped electrochemical cell was evaluated.

The effects of an increasing boost pressure, a high EGR rate and a high injection pressure on exhaust emissions from an HSDI (High Speed Direct Injection) diesel engine were examined. The mechanisms were then investigated with both in-cylinder observations and 3DCFD coupled with ϕT-map analysis. Under a high-load condition, increasing the charging efficiency combined with a high injection pressure and a high EGR rate is an effective way to reduce NOx and soot simultaneously, which realized an ultra low NOx of 16ppm at 1.7MPa of IMEP (Indicated Mean Effective Pressure). The flame temperature with low NOx and low soot emissions is decreased by 260K from that with conventional emissions. Also, the distribution of the fuel-air mixture plot on a ϕT-map is moved away from the NOx and soot formation peninsula, compared to the conventional emissions case.

In this study, we combined a diesel engine with the Toyota Hybrid System (THS). Utilizing the functions of the THS, reducing engine friction, lowering the compression ratio, and adopting a low pressure loop exhaust gas recirculation system (LPL-EGR) were examined to achieve both low fuel consumption and low nitrogen oxides (NOx) emissions over a wide operating range. After applying this system to a test vehicle it was verified that the fuel economy greatly surpassed that of a conventional diesel engine vehicle and that NOx emissions could be reduced below the value specified in the Euro 6 regulations without DeNOx catalysts.

A study of the effects of changes in gasoline composition is one area to explore in our effort to reduce tailpipe emissions from vehicles. However, affects on vehicle performances should also be considered from the perspective of practical useage. In this paper, the influence of gasoline composition (aromatics),volatility, and MTBE blending on engine outlet and tailpipe emissions are discussed,in particular,forcusing on distillation properties which have a close relationship to driveability. Under stable driving conditios and without a catalitic converter, the effects of gasoline volatility is small, while aromatics in gasoline affect exhaust HC and NOx emissions. MTBE has a leaning effect on the engine intake air/fuel mixture. During a transient driving cycle, a high gasoline 50% distillation temperature causes poor driveability, as a result, HC emissions increase.

An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.

In order to investigate the effect of sulfur and distillation properties on exhaust emissions, emission tests were carried out using a California Low Emission Vehicle (LEV) in accordance with the 1975 Federal Test Procedure ('75 FTP). To study the fuel effect on the exhaust emissions from different systems, these test results were compared with the results obtained from our previous studies using a 92MY vehicle for California Tier 1 standards and a 94MY vehicle for California TLEV standards. (1)(2) First, the sulfur effect on three regulated exhaust emissions (HC, CO and NOx) was studied. As fuel sulfur was changed from 30 to 300 ppm, the exhaust emissions from the LEV increased about 20% in NMHC, 17% in CO and 46% in NOx. To investigate the recovery of the sulfur effect, the test fuel was changed to 30 ppm sulfur after the 300 ppm sulfur tests. The emission level did not recover to that of the initial 30 ppm sulfur during three repeats of the FTP.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

With the advance in modularization of engine parts in recent years, there is increased use of plastic-made products in air intake systems. Plastic-made intake manifolds (Fig. 1) provide many advantages including reduced weight, reduced cost, and lower intake air temperatures. However, these manifolds have one disadvantage when compared with conventional aluminum-made intake manifolds, in that they transmit more noise because of their lower material density. For example, plastic intake manifolds of early development often generate flow noise when the throttle is opened quickly. With conventional aluminum intake manifolds, this flow noise had generated, but was not heard. This flow noise is presumed to be generated because of high-speed airflow generated when the throttle is opened quickly, but the mechanism of this noise generation has not been clarified.

Two effects of rich-spike duration on NOx-storing have been analyzed. The first one, that NOx-storing speed decreases as rich-spike duration increases, is explained as the influence of NOx diffusion in wash-coat layer, which is quantified by a simple mathematical expression for NOx-storing rate. The second one, a peculiar behavior of NOx-storing in appearance of the outlet NOx concentration, is clarified: Heat produced directly or indirectly (via oxygen storage in ceria) by rich-spike warms up the downstream part, which releases excess NOx at the raised temperature. Contributions of the oxygen storage and the carbonate of NOx-storage material are also discussed.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

Ignition and combustion control of HCCI (Homogeneous Charge Compression Ignition) in DI (Direct Injection) Diesel Engine were examined. In this study, double injection technique was used by Common Rail injection system. The first injection was used as an early injection for fuel diffusion and to advance the changing of fuel to lower hydrocarbons (i.e. low temperature reaction). The second injection was used as an ignition trigger for all the fuel. It was found that the ignition of the premixed gas could be controlled by the second injection when the early injection was maintaining low temperature reaction. It was found that as the boost pressure increased, ignition timing advanced slightly and the rate of pressure increase markedly decreased. The rate of pressure increase is one of the factors concerning operation limit in this combustion. Therefore, the VNT (Variable Nozzle Turbo-charger) was applied to the production engine to allow boost pressure control.

The effects of the phosphorus and sulfated ash contents of engine oils on the deactivation of monolithic three-way catalysts and oxygen sensors were studied. The effect of temperature was evaluated as well. The catalysts and oxygen sensors were poisoned in a 100-hour engine bench test. As a result, it was learned that engine oils with higher phosphorus contents showed a higher concentration of phosphorus on the catalyst surfaces, and the ability of the catalysts to convert carbon monoxide and oxides of nitrogen decreased. However, the phosphorus content was not observed to have any effect on hydrocarbons. The sulfated ash reduced the phosphorus concentration on the catalyst surface, but it also had a negative effect on the catalytic activity. The deactivation of the catalysts was much more noticeable at 800°C than at 720°C. In the tests at 720°C and 800°C, no deactivation of the oxygen sensors was observed, regardless of the composition of the engine oil.

A description is made of new control methods to improve response of wheel slip regulation. These methods enabled a new Traction Control (TRC) system based on throttle control rather than brake pressure to be developed. Major points are as follows: (1) Use of fuel injection cut-off to minimize delay (2) Additional adaptive throttle control logic By these means, a response nearly equal to that with brake pressure control is achieved at lower cost and with a considerable weight saving. Furthermore, the system, by suppressing noise and vibration, enhances the driver's control ability.

This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.

Model based control design is an important method for optimizing engine operating conditions so as to simultaneously improve engines' thermal efficiency and emission profiles. Modeling of intake system that includes an intake throttle valve, an EGR valve and a variable geometry turbocharger was constructed based on conservation laws combined with maps. Calculated results were examined the predictive accuracy of fresh charge mass flow, EGR rate and boost pressure.

This paper describes the development of a High Speed Calculation Diesel Combustion Model that predicts combustion-related behaviors of diesel engines from passenger cars. Its output is dependent on the engine's operating parameters and on input from on-board pressure and temperature sensors. The model was found to be capable of predicting the engine's in-cylinder pressure, rate of heat release, and NOx emissions with a high degree of accuracy under a wide range of operating conditions at a reasonable computational cost. The construction of this model represents an important preliminary step towards the development of an integrated Model Based Control system for controlling combustion in diesel engines used in passenger cars.

The efficiency of the NOx Storage and Reduction (NSR) catalysts used in the aftertreatment of diesel engine exhaust gases can potentially be increased by using reactive reductants such as CO and H₂ that are formed during in-cylinder combustion. In this study, a multi-dimensional computational fluid dynamics (CFD) code coupled with complex chemical analysis was used to study combustion with various fuel after-injection patterns. The results obtained will be useful in designing fuel injection strategies for the efficient formation of CO.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.