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A slip-controlled lock-up clutch system Is very efficient in improving the fuel economy of automatic transmission (AT) equipped vehicles. However, a special automatic transmission fluid (ATF) which combines an anti-shudder property with high torque capacity is required for this system. In this study, we established additive technology for ATF having a sufficient anti-shudder property and high torque capacity. Based on the technology, new ATF: ATF-T4 was developed. It was confirmed in actual AT tests that ATF-T4 has excellent anti-shudder durability and high torque capacity. Furthermore, ATF-T4 has good SAE No. 2 friction characteristics, oxidation stability, compatibility with materials (elastomers, nylons, etc.) and viscosity at low temperatures.

It is widely known that pellet-typed catalysts are deactivated by phosphorus (ZnDTP) that comes from engine oils. In this paper, the poisoning of monolithic three-way catalysts and oxygen sensors by engine oils is studied. First, catalysts and oxygen sensors were poisoned on the engine bench by test oils in which the quantity of phosphorus and ash was varied. Next, performance of the catalysts and sensors alone was examined and the vehicle exhaust emission at FTP mode was measured on a chassis dynamometer. The results indicate that phosphorus in engine oils poisons the monolithic catalyst and the oxygen sensor resulting in deterioration of the vehicle NOx exhaust emission. However, Ca sulfonate and Mg sulfonate detergents act by restraining phosphorus poisoning of the catalyst and the oxygen sensor. Through analysis of the catalyst and sensor surfaces, it is concluded that phosphorus poisons the catalyst and sensor forming a dense coating.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

The purposes of this paper are to develop a new laboratory oxidation stability testing method and to clarify factors relative to the viscosity increase of engine oil. Polymerized products, obtained from the oil after a JASO M333-93 engine test, were found to consist mainly of carboxyl, nitrate and nitro compounds and to increase the oil viscosity. A good similarity between the JASO M333-93 test and the laboratory simulation test was found for the polymerized products. The products were obtained not by heating oil only in air but by heating oil while supplying a synthetic blowby gas consisting of fuel pyrolysis products, NO, SO2 and air. The laboratory test has also revealed that the viscosity increase depends on oil quality, organic Fe content and hydrocarbon composition in the fuel. Moreover, it has been found that blowby gas and organic Fe accelerate ZnDTP consumption and that aromatics concentration in the fuel correlates with the viscosity increase of oil.

The relative oxidation stability of two fully formulated engine oils was compared in three testing methods by following the increase in kinematic viscosity of the oil. The purpose of the study was to determine the cause of the completely opposite ranking of the oxidation stability of the two oils that was observed in the ASTM Sequence IIIE engine test and the JASO M333 93 engine test and to determine the degree of correlation the two engine tests had with the field. The study consisted of laboratory oxidation testing, engine testing and taxi field testing to cover the range of conditions from controlled oxidation to actual driving conditions.

The anti-shudder effect of ATF additives and their mechanisms have been investigated. Anti-shudder durability was evaluated using an automatic transmission (AT) on an engine stand under continuously slip-controlled condition. The addition of over-based Ca-sulfonate and friction modifier (FM) remarkably improved the anti-shudder durability of ATF. The surface roughness of the contact area (contact area roughness) of the clutch plates was measured by an electron probe surface roughness analyzer. To evaluate the boundary frictional properties of the adsorbed film formed, the friction coefficient of the clutch plates in the absence of oil was examined after the anti-shudder durability test. It was found that shudder occurrence was strongly correlated with the contact area roughness and the boundary frictional property of the steel plate surface. Large contact area roughness and low boundary friction were preferred to prevent shudder.