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A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.

Conventional CFD-based shape optimization technology that uses parametric shape modification and optimal solutions searching algorithms has the two problems: (1) outcome of optimized shapes depend on the selection of design parameters made by the designer, and (2) high computational costs. To resolve those problems, two innovative inverse analysis technologies based on the Adjoint Method were developed in previous study: surface geometry deformation sensitivity analysis to identify the locations to be modified, and topology optimization to generate an optimal shape for maximizing the cost function in the constrained design space. However, these technologies are only applicable to steady flows. Since most flows in a vehicle (such as engine in-cylinder flow) are transient, a practical technology for surface geometry sensitivity analysis has been developed based on the Transient Adjoint Method.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.

This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.

The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.

Abnormal combustion referred to as Low Speed Pre-Ignition (LSPI) may restrict low speed torque improvements in turbocharged Direct Injection (DI) - Spark Ignition (SI) Engines. Recent investigations have reported that the auto-ignition of an engine oil droplet from the piston crevice in the combustion chamber may cause unexpected and random LSPI. This study shows that engine oil formulations have significant effects on LSPI. We found that the spontaneous ignition temperature of engine oil, as determined using High-Pressure Differential Scanning Calorimetry (HP-DSC) correlates with LSPI frequency in a prototype turbocharged DI-SI engine. Based on these findings, we believe that the oxidation reaction of the oil is very important factor to the LSPI. Our test data, using a prototype engine, shows both preventative and contributory effects of base oil and metal-based engine oil additives.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

The purpose of this study is to analyze the piston skirt friction reduction effect of a diamond-like carbon (DLC)-coated wrist pin. The floating liner method and elasto-hydrodynamic lubrication (EHL) simulation were used to analyze piston skirt friction. The experimental results showed that a DLC-coated wrist pin reduced cylinder liner friction, and that this reduction was particularly large at low engine speeds and large pin offset conditions. Friction was particularly reduced at around the top and bottom dead center positions (TDC and BDC). EHL simulation confirmed that a DLC-coated wrist pin affects the piston motion and reduces the contact pressure between the piston skirt and cylinder liner.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

A technique for induction-hardening local portions of vehicle body reinforcements press-formed of thin sheet steel has been developed, with the aim of ensuring occupant safety in a side collision. This technique for increasing the tensile strength of sheet steel was practically applied to the front floor cross member and center pillar reinforcement. Owing to this method, the weight of body reinforcements can be decreased. New induction-hardening systems have also been developed for the present technique. One is an apparatus which allows induction-hardening a part with a three-dimensionally curved surface. Another is a straightening quench technique used to retain the same dimensional accuracy as the original press-formed part.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

With the support of Horiba and Horiba STEC, Toyota Motor Corporation has developed an exhaust emissions simulator to verify the accuracy of extremely low emissions measurement systems. It can reliably verify the accuracy (correlation) of each SULEV emission measurement system to within 5% under actual conditions. The simulator's method of simulating SULEV gasoline engine cold-start emissions is to inject bottled gases with known concentrations of each emission constituent to the base gas, which is clean exhaust gas from a SULEV vehicle with new fully warmed catalysts. First, the frequencies and dynamic ranges of the SULEV cold-start emissions were analyzed and the method of 2 injecting the bottled gases was considered based on the results of that analysis. A high level of repeatability and accuracy was attained for all injection flow ranges in the SULEV cold-start emission simulation by switching between high-response digital Mass Flow Controllers (MFCs) of different full scales.

1 The principal characteristics required of sealing materials used in the body shop have focused on their adhesion to oily steel sheets and quick curing performance. Means for attaining these characteristics have been narrowed down to a basic resin system and a curing system. Various techniques have been studied to ensure proper anti-corrosion performance at the sealer application boundaries and thin application areas. They include the addition of anti-corrosion fillers, the provision of conductivity (through electro-deposition), and the application of a micro foam film over the application boundaries. Thus, prospects for attaining the same level of anti-corrosion performance as existing materials have been achieved.

A new HC adsorber system was developed to achieve California SULEV emission standards for a V8 5.0-liter engine application (i.e. LS600hL). A HC adsorber system was first released on 2001 PZEV Prius (1.5-liter engine) in U.S.A. For the 5.0L application the substrate volume of both catalyst and adsorber had to be enlarged for a large volume displacement. Prius-type adsorber system could not be adopted for LS600hL because of the problems of installation. So, a new constructional adsorber was proposed. However the increase of gas flow into the adsorber substrate was a problem for desorption. The gas flow into the adsorber substrate was found to be controllable by the specification adjustment of the “throat” and “retainer” parts of adsorber system. Thus the rapid desorption was successfully reduced, and the HC adsorber system achieved a 50% reduction of HC emission.

This paper demonstrates the development of a full multi-body vehicle model and its use in virtual design and troubleshooting of a vehicle response to throttle input. The multibody model is divided into three main subsystems: the chassis, the driveline and the powertrain subsystems. The chassis system includes a complete representation of both the front and the rear suspensions, both the front and rear subframes, and the vehicle body. The driveline system includes the output shafts from the transmission unit to the tires. The powertrain system includes complete representation of the cranktrain for a V6 combustion engine. Also included in the powertrain is a nonlinear representation of the gearbox where bearing clearances and gear lashes are considered. The cranktrain torque output is linked to the transmission using a torque converter model. The vehicle components are virtually assembled together through different joint types, force elements, and kinematic constraints.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

NO2 sources of roadside atmosphere at Matsubarabashi monitoring station in Tokyo were investigated analytically. The result showed that contribution of urban background is dominant from November to February and NO oxidation with O3 has large contribution from April to September. NO2 air quality standard will be achieved by reducing vehicle NOx emission to post-new long-term regulation level. The analytical method was verified by using our developed simulation system, which consists of micro traffic flow analyzer and CFD-based, unsteady-state diffusion with chemical reaction solver.

Due to regulations for even lower levels of pollutants in exhaust gas, development of advanced combustion techniques and increasingly efficient catalysts has become more crucial than ever. One of the essential technologies to achieve this goal is an advanced measurement method, which can detect the characteristics of exhaust gas, such as temperature and chemical compositions, in real-time to clarify their reaction mechanisms. A direct and fast response (1ms) measurement technique was developed based on diode laser absorption spectroscopy and applied to practical engine exhaust measurement to prove the validity of this technology for various applications such as clarification of engine start phenomena and improvement of EGR controls.