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Journal Article

Applicable Diesel Oxidation Catalyst for Multi-Diesel Exhaust System

2014-04-01
2014-01-1511
The diesel oxidation catalysts (DOC) having high purification performance to the exhaust gas at low temperatures were investigated. In this paper two main technological improvements from conventional DOC are shown. First is forming Pt/Pd composite particles in order to suppress sintering of precious metal under high thermal aging condition. This generating Pt/Pd composite and the effect were exemplified by TEM-EDS and XRD analysis. Second is adjusting electric charge of Pt/Pd surface to reduce interaction between Pt/Pd and carbon monoxide (CO) by modifying the support material components. Adjusting electric charge of Pt/Pd surface by applying new support material could cancel CO poisoning at Pt/Pd surface. Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) studies suggested that improved support material is more suitable for CO oxidation at a low temperature based on the concept.
Technical Paper

Impact of Aging and NOX/Soot Ratio on the Performance of a Catalyzed Particulate Filter for Heavy Duty Diesel Applications

2005-04-11
2005-01-0663
Particulate filters are currently the method of choice for reducing soot levels in diesel exhaust to the extremely low levels required for meeting future emission standards. For cost effective, reliable and manageable soot regeneration, the Catalytic Diesel Particulate Filter (CDPF) has proven to be one of the most promising solutions for maintaining filter performance. The activity of the CDPF can help lower soot ignition temperature thereby promoting active, oxygen-based filter regeneration. It can also facilitate passive regeneration of a filter at temperatures below 400 °C through formation of NO2 by catalyzing the oxidation of NO. There are two important factors which affect the passive regeneration of a CDPF. One is the influence of NOX/soot ratio. The other is the deterioration of the catalytic function upon aging. Together they determine the quantity of NO2 available for soot oxidation.
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