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To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.

In this paper we report on a new state of the art diesel LNT (Lean NOx Trap) formulation that is designed to comply with North American emission legislation for diesel passenger cars. Improved performance and durability is demonstrated in an aging study using hydrothermal furnace aging and a prolonged procedure behind the engine consisting of repeated cycles containing sulfur exposure, desulfation and simulated regeneration of a diesel particulate filter. The improved barium based technology shows an increased thermal stability in terms of upper not-to-exceed temperature of at least 50°C. Our data show that potassium based technologies can represent a viable solution for certain applications that require extremely high NOx-conversions at temperatures above 500°C. Potassium based technologies with improved anchoring of the alkali metal show significant reduction in potassium loss to the exhaust gas.