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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The present paper describes some results of a cooperative research project between GM Powertrain Europe and Istituto Motori of CNR aimed at studying the impact of FAME and GTL fuel blends on the performance, emissions and fuel consumption of the latest-generation automotive diesel engines. The investigation was carried out on the newly released GM 2.0L 4-cylinder “torque-controlled” Euro 5 diesel engine for PC application and followed previous tests on its Euro 4 version, in order to track the interaction between the alternative fuels and the diesel engine, as the technology evolves. Various blends of first generation biodiesels (RME, SME) and GTL with a reference diesel fuel were tested, notably B20, B50 and B100. The tests were done in a wide range of engine operation points for the complete characterization of the biodiesels performance in the NEDC cycle, as well as in full load conditions.

The present paper describes some results of a research project aimed at studying the impact of alternative fuels blends on the emissions and fuel consumption of an Euro 5 automotive diesel engine. Two alternative fuels were chosen for the experiments: RME and GTL. The tests were done in the three most important operating conditions for the engine emission calibration. Moreover, the NOx-PM trade-off by means of EGR sweep was performed in the same operating conditions, in order to evaluate the engine EGR tolerability when burning low sooting fuels as the RME. The investigations put in evidence that the impact of the alternative fuels on modern diesel engines remains significant. This also depends on the interaction between the alternative fuel characteristics and the engine-management strategies, as described in detail in the paper.

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

Modern VVA systems offer new potentialities in improving the fuel consumption for spark-ignition engines at low and medium load, meanwhile they grant a higher volumetric efficiency and performance at high load. Recently introduced systems enhance this concept through the possibility of concurrently modifying the intake valve opening, closing and lift leading to the development of almost "throttle-less" engines. However, at very low loads, the control of the air-flow motion and the turbulence intensity inside the cylinder may require to select a proper combination of the butterfly throttling and the intake valve control, to get the highest BSFC (Brake Specific Fuel Consumption) reduction. Moreover, a low throttling, while improving the fuel consumption, may also produce an increased gas-dynamic noise at the intake mouth. In highly "downsized" engines, the intake valve control is also linked to the turbocharger operating point, which may be changed by acting on the waste-gate valve.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

High pressure diesel sprays were visualized under vaporizing and combusting conditions in a constant-volume combustion vessel. Near-simultaneous visualization of vapor and liquid phase fuel distribution were acquired using a hybrid shadowgraph/Mie-scattering imaging setup. This imaging technique used two pulsed LED's operating in an alternative manner to provide proper light sources for both shadowgraph and Mie scattering. In addition, combustion cases under the same ambient conditions were visualized through high-speed combustion luminosity measurement. Two single-hole diesel injectors with same nozzle diameters (100μm) but different k-factors (k0 and k1.5) were tested in this study. Detailed analysis based on spray penetration rate curves, rate of injection measurements, combustion indicators and 1D model comparison have been performed.

Detailed experimental information on the early stages of spark ignition process represent a substantial part for guiding the development of engines with higher efficiencies and reduced pollutant emissions. Flame kernel formation influences strongly combustion development inside the cylinder, especially for a direct injection spark ignition engine. This study presents the analysis of the evolution of spark-ignited flame kernels with detailed view upon cycle-to-cycle variations. Experiments are performed in a SI optical engine equipped with the cylinder head and injection system of a commercial turbocharged engine. Blend of commercial gasoline and butanol (40% by volume) is tested at stoichiometric and lean mixture conditions. Experiments are carried out at 2000 rpm through conventional tests (based on in-cylinder pressure measurements and exhaust emission analysis) and through optical diagnostics. In particular, UV-visible digital imaging and natural emission spectroscopy are applied.

An innovative quasi-dimensional multizone combustion model for the spray formation, combustion and emission formation analysis in DI diesel engines was assessed and applied to an optical single cylinder engine. The model, which has been recently presented by the authors, integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model. The 1D spray model is capable of predicting the equivalence ratio of the fuel during the mixing process, as well as the spray penetration. The multizone approach is based on the application of the mass and energy conservation laws to several homogeneous zones identified in the combustion chamber. A specific submodel is also implemented to simulate the dilution of the burned gases. Soot formation is modeled by an expression which derives from Kitamura et al.'s results, in which an explicit dependence on the local equivalence ratio is considered.

In this study, experiments were carried out in an optical single-cylinder Direct Injection Spark Ignition engine fuelled with n-butanol and gasoline, alternatively. The engine is equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio). The head has four valves and a centrally located spark device with surface charge ignition. A conventional elongated hollow Bowditch piston is used and an optical crown, accommodating fused-silica window, is screwed onto it. The injector is side mounted and features 6 holes oriented to guide the jets towards the piston crown. During the experimental activity, the injection pressure was maintained at 100 bar for all conditions; the injection timing and the number of injections were adjusted to investigate their influence on combustion and emissions.

This paper reports 1D and 3D CFD analyses aiming to improve the gas-dynamic noise emission of a downsized turbocharged VVA engine through the re-design of the intake air-box device, consisting in the introduction of external or internal resonators. Nowadays, modern spark-ignition (SI) engines show more and more complex architectures that, while improving the brake specific fuel consumption (BSFC), may be responsible for the increased noise radiation at the engine intake mouth. In particular VVA systems allow for the actuation of advanced valve strategies that provide a reduction in the BSFC at part load operations thanks to the intake line de-throttling. In these conditions, due to a less effective attenuation of the pressure waves that travel along the intake system, VVA engines produce higher gas-dynamic noise levels.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

In the recent years, the interest in heavy-duty engines fueled with Compressed Natural Gas (CNG) is increasing due to the necessity to comply with the stringent CO2 limitation imposed by national and international regulations. Indeed, the reduced number of carbon atoms of the NG molecule allows to reduce the CO2 emissions compared to a conventional fuel. The possibility to produce synthetic methane from renewable energy sources, or bio-methane from agricultural biomass and/or animal waste, contributes to support the switch from conventional fuel to CNG. To drive the engine development and reduce the time-to-market, the employment of numerical analysis is mandatory. This requires a continuous improvement of the simulation models toward real predictive analyses able to reduce the experimental R&D efforts. In this framework, 1D numerical codes are fundamental tools for system design, energy management optimization, and so on.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

Cycle-To-Cycle Variability (CCV) must be properly considered when modeling the ignition process in SI engines operating with ultra-lean mixtures. In this work, a strategy to model the impact of the ignition type on the CCV was developed using the RANS approach for turbulence modelling, performing multi-cycle simulations for the power-cycle only. The spark-discharge was modelled through a set of Lagrangian particles, introduced along the sparkgap and interacting with the surrounding Eulerian gas flow. Then, at each discharge event, the velocity of each particle was modified with a zero-divergence perturbation of the velocity field with respect to average conditions. Finally, the particles velocity was evolved according to the Simplified Langevin Model (SLM), which keeps memory of the initial perturbation and applies a Wiener process to simulate the stochastic interaction of each channel particle with the surrounding gas flow.

The common realization of the necessity to reduce the use of mineral sources is promoting the use of alternative fuels. Big efforts are being made to replace petroleum derivatives in the internal combustion engines (ICEs). For this purpose it is mandatory to evaluate the behavior of non-conventional fuels in the ICEs. The optical diagnostics have proven to be a powerful tool to analyze the processes that take place inside the engine. In particular, 2d imaging in the infrared range can reveal new details about the effect of the fuel properties since this technique is still not very common. In this work, a comparison between commercial diesel fuel and two non-conventional fuels has been made in an optically accessible diesel engine. The non-conventional fuels are: the first generation biofuel Rapeseed Methyl Ester (RME) and an experimental blend of diesel and a fuel with high glycerol content (HG).

The paper reports the results of an experimental investigation carried out in a prototype optically accessible compression ignition engine fuelled with different blends of commercial diesel and n-butanol. Thermodynamic analysis and exhaust gas measurements were supported by optical investigations performed through a wide optical access to the combustion chamber. UV-visible digital imaging and 2D chemiluminescence were applied to characterize the combustion process in terms of spatial and temporal occurrence of auto-ignition, flame propagation, soot and OH evolution. The paper illustrates the results of the spray combustion for diesel and n-butanol-diesel blends at 20% and 40% volume fraction, exploring a single and double injection strategy (pilot+main) from a common rail multi-jet injection system. Tests were performed setting a pilot+main strategy with a fixed dwell time and different starts of injection.

The paper reports an experimental study on the effect of compression ratio variation on the performance and pollutant emissions of a single-cylinder light-duty research diesel engine operating in DF mode. The architecture of the combustion system as well as the injection system represents the state-of-the-art of the automotive diesel technology. Two pistons with different bowl volume were selected for the experimental campaign, corresponding to two CR values: 16.5 and 14.5. The designs of the piston bowls were carefully performed with the 3D simulation in order to maintain the same air flow structure at the piston top dead center, thus keeping the same in-cylinder flow characteristics versus CR. The engine tests choice was performed to be representative of actual working conditions of an automotive light-duty diesel engine.

An investigation has been carried out on the spray penetration and soot formation processes in a research diesel engine by means of a quasi-dimensional multizone combustion model. The model integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model, and is capable of predicting the spray formation, combustion and soot formation processes in the combustion chamber. The multizone model was used to analyze three operating conditions, i.e., a zero load point (BMEP = 0 bar at 1000 rpm), a medium load point (BMEP = 5 bar at 2000 rpm) and a medium-high load point (BMEP = 10 bar at 2000 rpm). These conditions were experimentally tested in an optical single cylinder engine with the combustion system configuration of a 2.0L Euro4 GM diesel engine for passenger car applications.