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In this work, a dynamic 0-D electro-thermal model of a lithium-polymer battery for automotive applications is presented. The model predicts the battery temperature during its charging/discharging phases under different environmental and operating conditions, by considering the requested power or current, the coolant flow rate and its temperature as model inputs. The model was first validated with experimental data carried out at the test bench where only the convective heat transfer between the battery and the ambient air was considered. The accuracy of the internal heat generation model was experimentally assessed for different current discharge rates. Then, a liquid cooling system was designed on purpose, assembled, and installed on the battery at the test bench for the improvement of the model predictions in liquid convection conditions.