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We assessed the engine-out emissions of an ultra-low sulfur diesel (ULSD) and a neat hydrogenated vegetable oil (HVO) from a light-duty diesel truck equipped with common rail direct injection. The vehicle was tested at least twice on each fuel using the LA-92 drive cycle and at steady-state conditions at 30 mph and 50 mph at different loads. Results showed reductions in the engine-out total hydrocarbon (THC), carbon monoxide (CO), nitrogen oxide (NOx), and particulate emissions with HVO. The reductions in soot mass, solid particle number, and particulate matter (PM) mass emissions with HVO were due to the absence of aromatic and polyaromatic hydrocarbon compounds, as well as sulfur species, which are known precursors of soot formation. Volumetric fuel economy, calculated based on the carbon balance method, did not show statistically significant differences between the fuels.

Biofuels, such as ethanol and butanol, have been the subject of significant political and scientific attention, owing to concerns about climate change, global energy security, and the decline of world oil resources that is aggravated by the continuous increase in the demand for fossil fuels. This study evaluated the potential emissions impacts of different alcohol blends on a fleet of modern gasoline vehicles. Testing was conducted on a fleet of nine vehicles with different combinations of ten fuel blends over the Federal Test Procedure and Unified Cycle. The vehicles ranged in model year from 2007-2014 and included four vehicles with port fuel injection (PFI) fueling and five vehicles with direct injection (DI) fueling. The ten fuel blends included ethanol blends at concentrations of 10%, 15%, 20%, 51%, and 83% by volume and iso-butanol blends at concentrations of 16%, 24%, 32%, and 55% by volume, and an alcohol mixture giving 10% ethanol and 8% iso-butanol in the final blend.

Gasoline direct injection (GDI) engines have improved thermodynamic efficiency (and thus lower fuel consumption) and power output compared with port fuel injection (PFI) and their penetration is expected to rapidly grow in the near future in the U.S. market. In addition, the use of alternative fuels is expanding, with a potential increase in ethanol content beyond the current 10%. Increased emphasis has been placed on butanol due to its more favorable fuel properties, as well as new developments in production processes. This study explores the influence of mid-level ethanol and iso-butanol blends on criteria emissions, gaseous air toxics, and particulate emissions from two wall-guided gasoline direct injection passenger cars fitted with three-way catalysts. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer.

The electrooxidation of carbon black, which contains Pt electrocatalyst particles, was investigated in concentrated phosphoric acid at 0.6 to 1.0V. At the high potentials, anodic dissolution of Pt is rapid, and consequently no metal is present to catalyze the corrosion of carbon at 160 °C in 98% H3PO4. On the other hand, at 0.6V anodic dissolution of Pt is negligible, and hence it is present to catalyze the corrosion of carbon. In fact, the measurements indicate that the corrosion rate is noticeable higher than that of carbon black without Pt. These results suggest the Pt particles with surface Pt-0 may serve as an intermediary which facilitates the corrosion of carbon.

The relationship between ethanol and iso-butanol fuel concentrations and vehicle particulate matter emissions was investigated. This study utilized a gasoline direct injection (GDI) flexible fuel vehicle (FFV) with wall-guided fueling system tested with four fuels, including E10, E51, E83, and an iso-butanol blend at a proportion of 55% by volume. Emission measurements were conducted over the Federal Test Procedure (FTP) driving cycle on a chassis dynamometer with an emphasis on the physical and chemical characterization of particulate matter (PM) emissions. The results indicated that the addition of higher ethanol blends and the iso-butanol blend resulted in large reductions in PM mass, soot, and total and solid particle number emissions. PM emissions for the baseline E10 fuel were characterized by a higher fraction of elemental carbon (EC), whereas the PM emissions for the higher ethanol blends were more organic carbon (OC) in nature.

The primary objective of this study was to evaluate the impact of three different biodiesel feedstocks on emissions compared to a baseline CARB ULSD with two heavy-duty trucks equipped with and without aftertreatment technologies. The biodiesels included a soybean oil methyl ester (SME), a waste cooking oil methyl ester (WCO), and a methyl ester obtained from animal fat (AFME), blended at a 50% level by volume with the CARB diesel. The vehicles were equipped with a 2010 Cummins ISX-15 engine with a selective catalytic reduction (SCR), diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF) and with a 2002 Cummins ISX-450 engine. Both vehicles were tested over the Urban Dynamometer Driving Schedule (UDDS) on a heavy-duty chassis dynamometer. For this study, nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2), total hydrocarbons (THC), methane (CH4), non-methane hydrocarbons (NMHC), and particulate matter (PM) were measured.

This study provides one of the first evaluations of the integrated particle size distribution (IPSD) method in comparison with the current gravimetric method for measuring particulate matter (PM) emissions from light-duty vehicles. The IPSD method combines particle size distributions with size dependent particle effective density to determine mass concentrations of suspended particles. The method allows for simultaneous determination of particle mass, particle surface area, and particle number concentrations. It will provide a greater understanding of PM mass emissions at low levels, and therefore has the potential to complement the current gravimetric method at low PM emission levels. Six vehicles, including three gasoline direct injected (GDI) vehicles, two port fuel injected (PFI) vehicles, and one diesel vehicle, were tested over the Federal Test Procedure (FTP) driving cycle on a light-duty chassis dynamometer.

A novel ambient dilution tunnel has been designed, tested and employed to measure the emissions from active parked regenerations of Diesel Particulate Filters (DPFs) for 2007 and 2010 certified heavy duty diesel trucks (HDDTs). The 2007 certified engine had greater regulated emissions than the 2010 certified engine. For a fully loaded 2007 DPF there was an initial period of very large mass emissions, which was then followed by very large number of small particle emissions. The Particle Size Distribution, PSD, was distributed over a large range from 10 nm to 10 μm. The parked regenerations of the 2010 DPF had a much lower initial emission pattern, but the second phase of large numbers of small particles was very similar to the 2007 DPF. The emission results during regeneration have been compared to total emissions from recent engine dynamometer testing of 2007 and 2010 DPFs, and they are much larger.

Introducing water in a diesel engine has been known to decrease peak combustion temperatures and decrease NOx emissions. This however, has been limited to stationary and marine applications due to the requirement of a separate water supply tank in addition to the fuel tank, thereby a two-tank system. Combustion of hydrocarbon fuels produce between 1.35 (Diesel) and 2.55 times (Natural Gas) their mass in water. Techniques for extracting this water from the exhaust flow of an engine have been pursued by the United States department of defense (DOD) for quite some time, as they can potentially reduce the burden of supply of drinking water to front line troops in theater. Such a technology could also be of value to engine manufacturers as it could enable water injection for performance, efficiency and emissions benefits without the drawbacks of a two-tank system.