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Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.

Low temperature heat release (LTHR) has been of interest to researchers for its potential to mitigate knock in spark ignition (SI) engines and control auto-ignition in advanced compression ignition (ACI) engines. Previous studies have identified and investigated LTHR in both ACI and SI engines before the main high temperature heat release (HTHR) event by appropriately curating the in-cylinder thermal state during compression, or in the case of SI engines, timing the spark discharge late to reveal LTHR (sometimes referred to as pre-spark heat release). In this work, LTHR is demonstrated in isolation from HTHR events. Tests were run on motored single-cylinder engines and inlet air temperatures and pressures were adjusted to realise LTHR from n-heptane and iso-octane (2,2,4-trimethylpentane) without entering the HTHR regime. LTHR was observed for a lean n-heptane-air mixture at inlet temperatures ranging from 60°C to 100°C and inlet pressures of 0.9 bar (absolute).