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In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.

ExxonMobil, Corning and Toyota have collaborated on an Onboard Separation System (OBS) to improve gasoline engine efficiency and performance. OBS is a membrane based process that separates gasoline into higher and lower octane fractions, allowing optimal use of fuel components based on engine requirements. The novel polymer-ceramic composite monolith membrane has been demonstrated to be stable to E10 gasoline, while typically providing 20% yield of ∼100 RON product when using RUL 92 RON gasoline. The OBS system makes use of wasted exhaust energy to effect the fuel separation and provides a simple and reliable means for managing the separated fuels that has been demonstrated using several generations of dual fuel test vehicles. Potential applications include downsizing to increase fuel economy by ∼10% while maintaining performance, and with turbocharging to improve knock resistance.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

Methanol steam reforming, which is an endothermic reaction, needs some heating. Both methanol conversion ratio and carbon monoxide (CO) concentration increase when temperature is elevated. As CO poisons a typical polymer electrolyte of a fuel cell, the relationship between methanol conversion ratio and CO concentration is a trade-off one. It was found from preliminary researches that the reforming reaction speed is controlled by heat transfer rate at large methanol flow rate, where methanol conversion ratio becomes lower and CO concentration becomes higher. Therefore it is necessary to develop a new methanol reforming concept that provides stable combustion for heating and enhanced heat transfer for improving the trade-off relationship and making a compact reformer. Reforming catalyst using metal honeycomb support and a new catalytic combustion were applied to a new concept plate type methanol steam reformer, which is used in a fuel cell of 3 kW-class electric generation.

The new generation engines currently being developed tend to require cold type spark plugs, which are prone to fouling. This paper describes the development of a new Coil on Plug ignition system that resolves this problem by using the high energy and the fast secondary voltage rise time of a capacitive ignition while maintaining inductive ignition characteristics for good ignitability. To evaluate the effectiveness of the system, spark plug insulation resistance was monitored and cold tests were conducted. The results demonstrated that the new ignition system is remarkably effective: insulation resistance remains high and startability and driveability are unaffected under conditions normally leading to excessive misfires and failure to start with a conventional inductive system. To satisfy environmental concerns, automobile manufactures are increasingly turning to high compression ratio engines in view of their improved performance.

This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.

The study of 10% ethanol blended gasoline (E10 gasoline) utilization has been conducted in the Japan Auto-Oil Program (JATOP). In order to clarify the impact of E10 gasoline on vehicle performances, exhaust emissions, evaporative emissions, driveability and material compatibility have been investigated by using domestic gasoline vehicles including mini motor vehicles which are particular to Japan. The test results reveal that E10 gasoline has no impact on exhaust emissions, engine startup time and acceleration period under the hot start condition, but a slight deterioration is observed in some test cases under the cold start condition using E10 gasolines with 50% distillation temperature (T50) level set to the upper limit of Japanese Industrial Standards (JIS) K 2202. Regarding evaporative emissions, the tested vehicles shows no remarkable increase in the hot soak loss (HSL), diurnal breathing loss (DBL) and running loss (RL) testing with E10 gasolines.

Quality control of gasoline constituents and its effect on the Intake Valve Deposits (IVD) has become a recent issue. In this paper, the effects of gasoline and oil quality on intake valve deposits were investigated using an Intake Valve Deposit Test Bench and a Sludge Simulator. The deposit formation from the gasoline maximized at an intake valve temperature of approximately 160 °C, and the deposits formed from the engine oil were maximum at approximately 250 °C. Therefore, the contribution of the gasoline or the engine oil appears to depend on the engine conditions. The gasoline which contains MTBE or ethanol with no detergent additive slightly increases the deposition amount. The gasoline with a superior detergent significantly decreases the deposition amount even when MTBE or ethanol is blended in the gasoline. Appropriate detergent fuel additive retards the oil deterioration.

The electrochemical and corrosion behavior of metals in aqueous environments has received substantial attention. However, relatively little work has been devoted to the electrochemistry and corrosion of metals in non-aqueous environments. Now, with greater pressures to increase fuel efficiencies and decrease exhaust emissions, alternatives and additives to gasoline (including methanol and ethanol) are receiving increased attention from government agencies and automobile manufacturers. Unfortunately, fundamental studies of the corrosion behavior of metals in these solutions are scarce. The objective of the present work is to investigate the electrochemical and corrosion behavior of iron in methanolic solutions containing Cl, H+, SO42-, and H2O. To accomplish this, a full factorial design test matrix was developed to systematically evaluate the effects of these impurities on the corrosion behavior of iron.

The higher compression ratio engines, two-stroke engines and flexible fuel vehicles currently under development tend to face the problems of spark plug fouling owing to the necessity of using cold type spark plugs. This paper analyzes the sparking of fouled spark plugs and investigates the characteristics required of an ignition system in order to avoid fouling problems. The results clearly establish that to maintain a strong spark even when the plug is fouled, a high voltage should be instantaneously applied to the spark plug. A series-gap on the high-tension side was confirmed to be an effective means of achieving this and a new plug cap provided with a series-gap has resolved fouling problems such as failure to start. Lately, fuel economy and long-term energy conservation have become critically important. For automobiles, higher compression ratio engines, two-stroke engines and flexible fuel vehicles (FFVs) are being developed.

The wear mechanisms of the methanol engine were studied using dynamometer tests. Formic acid from methanol combustion mixes with the lubricant oil and attacks the metal surfaces. The iso tacho prorissis method was successfully applied to analyze the formic acid content of the used oil. A large amount of condensed water is also formed by methanol combustion and accelerates the wear. Wear can be effectively reduced by shortening lubricant oil change intervals, by using a special oil and by durable surface treatment of engine parts.

A methanol fueled, lean burn system has been developed to improve both specific fuel consumption and NOx emissions. A 1.6L four-cylinder engine with increased compression ratio has been used to develop this system. Three major components of the Toyota Lean Combustion System (T-LCS) have been applied: (1) A helical port with a swirl control valve (2) A lean mixture sensor (3) Timed, multi-point fuel injection. A 2250 lb. Inertia Weight test vehicle has been fitted with this engine, and fuel system materials have been modified. This methanol, lean burn system has improved the fuel economy by about 12% still satisfying the 1986 emission standards of the U.S.A. and Japan. Aldehyde emissions have also been evaluated.

The second generation methanol lean burn system has been developed. The power unit is a new, 4 valve 1.6L in-line four with compact combustion chambers. Lean misfire limit was extended by using a swirl control valve in the intake port which improves combustion under partial load. Lean mixture control is made by using a signal from lean mixture sensor provided in the exhaust manifold. An EGR system has been newly adopted to reduce NOx emissions and a under-floor type catalyst is also used to reduce formaldehyde emission in the cold transient mode in addition to the manifold type catalyst. Permissible excess air ratio range (PEXARR) was defined and used to indicate the potential for reducing vehicle NOx emissions in engine dynamometer tests to optimize compression ratio, valve timing and swirl ratio and to evaluate the effect of the EGR.

The effects of methanol/cosolvent/gasoline blends on hot weather driveability are surveyed. Results show that startability after engine-off soak drastically deteriorates in an EFI vehicle. By observing the behavior of the fuel in the delivery pipe during hot-start testing and the injected fuel spray shape at high fuel temperature, the authors confirmed that the main cause of this malfunction was the vapor lock in the injector nozzle. The relationship between hot weather driveability and fuel properties is discussed. The gasoline volatility expression commonly used to indicate deterioration in hot weather driveability was found to underestimate the increase in volatility of blended fuels at higher temperatures. A suggestion is made for a modification to the expression to include the effects of methanol blending on volatility characteristics at high temperatures so that EFI vehicle hot-startability may be predicted.

From the energy security and CO2 reduction point of view, much attention has been paid to the usage of bio-fuel. Recently, highly concentrated ethanol is used in some areas (“E85”; 85% ethanol and 15% gasoline in North America and Sweden, and “ethanol”; 93% ethanol and 7% water in Brazil). In these regions, Flexible Fuel Vehicles FFVs are being introduced that are capable of using fuels with a wide range of ethanol concentrations. Advantages of highly concentrated ethanol in internal combustion engine applications are higher thermal efficiency obtained due to higher octane number, and a reduction of nitrogen oxides due to lower combustion temperatures On the other hand, the latent heat of vaporization for ethanol is greater than gasoline, causing poor cold startability and high NMOG emissions. This paper examines the effect of highly concentrated ethanol on exhaust emissions at cold start in a SI- engine.

Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.