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A direct calibration has been performed on laser-induced fluorescence measurements of the oil film in a single cylinder air-cooled research engine by simultaneously measuring the minimum oil film thickness by the capacitance technique. At the minimum oil film thickness the capacitance technique provides an accurate measure of the ring-wall distance, and this value is used as a reference for the photomultiplier voltage, giving a calibration coefficient. This calibration coefficient directly accounts for the effect of temperature on the fluorescent properties of the constituents of the oil which are photoactive. The inability to accurately know the temperature of the oil has limited the utility of off-engine calibration techniques. Data are presented for the engine under motoring conditions at speeds from 800 - 2400 rpm and under varying throttle positions.

The role of mixture stratification on combustion rate has been investigated in a constant volume combustion vessel in which mixtures of different equivalence ratios can be added in a spatially and temporally controlled fashion. The experiments were performed in a regime of low fluid motion to avoid the complicating effects of turbulence generated by the injection of different masses of fluid. Different mixture combinations were investigated while maintaining a constant overall equivalence ratio and initial pressure. The results indicate that the highest combustion rate for an overall lean mixture is obtained when all of the fuel is contained in a stoichiometric mixture in the vicinity of the ignition source. This is the result of the high burning velocity of these mixtures, and the complete oxidation which releases the full chemical energy.

Vapor concentration measurements were performed for two unit injectors typically found in small- and medium-bore applications under evaporating conditions similar to those experienced in Diesel engines. Ambient gas temperatures of 800 and 1000 K and an ambient density of 15 kg/m3 were investigated using a constant volume combustion-type spray chamber. The exciplex laserinduced fluorescence technique with TMPD/naphthalene doped into the fuel was used to quantitatively determine the vapor-phase concentration and liquid-phase extent. The vapor-phase concentration was quantified using a previously developed method that includes corrections for the temperature dependence of the TMPD fluorescence, laser sheet absorption, and the laser sheet intensity profile. The effect of increasing ambient temperature (1000 vs. 800 K) was significant on intact liquid length, and on the spray-spreading angle in the early portion of the injection period.

The noise characteristics of four camera systems representative of those typically used for laser-imaging experiments (a back-illuminated slow-scan camera, a frame-straddling slow-scan camera, an intensified slow-scan camera and an intensified video-rate camera) were investigated, and the results are presented as a function of the signal level and illumination level. These results provide the maximum possible signal-to-noise ratio for laser-imaging experiments, and represent the limit of quantitative signal interpretation. A calibration strategy for engine data that limits the uncertainties associated with thermodynamic and optical correction was presented and applied to engine data acquired with two of the camera systems. When a rigorous analysis of the signal is performed it is seen that shot noise limits the quantitative interpretation of the data for most typical laser-imaging experiments, and obviates the use of single-pixel data.

Combustion under stratified operating conditions in a direct-injection spark-ignition engine was investigated using simultaneous planar laser-induced fluorescence imaging of the fuel distribution (via 3-pentanone doped into the fuel) and the combustion products (via OH, which occurs naturally). The simultaneous images allow direct determination of the flame front location under highly stratified conditions where the flame, or product, location is not uniquely identified by the absence of fuel. The 3-pentanone images were quantified, and an edge detection algorithm was developed and applied to the OH data to identify the flame front position. The result was the compilation of local flame-front equivalence ratio probability density functions (PDFs) for engine operating conditions at 600 and 1200 rpm and engine loads varying from equivalence ratios of 0.89 to 0.32 with an unthrottled intake. Homogeneous conditions were used to verify the integrity of the method.

Planar instantaneous fuel concentration measurements were made by laser-induced fluorescence of 3-pentanone in the spark gap just prior to ignition in a direct-injection spark-ignition engine operating at a light load, highly stratified condition. The distribution of the average equivalence ratio in a circle of 1.9 mm diameter centered on the spark plug showed that a large fraction of the cycles had an equivalence ratio below the lean limit, yet acceptable combustion was achieved in those cycles. Further, weak correlation was found between the local average equivalence ratio near the spark plug and the time required to achieved a 100 kPa pressure rise above the motoring pressure, as well as other parameters which characterize the early stages of combustion. The cause for this behavior is assessed to be mixture motion during the spark discharge which continually convects fresh mixture through the spark gap during breakdown.