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The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and1H/13C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT™) apparatus.

This paper reports the development of new fuel ignition quality and combustion experiments performed using the Ignition Quality Tester (IQT). Prior SAE papers (961182, 971636, 1999-01-3591, and 2001-01-3527) documented the development of the IQT constant volume combustion chamber experimental apparatus to measure ignition qualities of diesel-type fuels. The ASTM International test method D6890 was developed around the IQT device to allow the rapid determination of derived cetane number (DCN). Interest in chemical kinetic models for the ignition of diesel and biodiesel model compounds is increasing to support the development of advanced engines and fuels. However, rigorous experimental validation of these kinetic models has been limited for a variety of reasons. Shock tubes and rapid compression machines are typically limited to premixed gas-phase studies, for example.

Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.

Battery second use-putting used plug-in electric vehicle (PEV) batteries into secondary service following their automotive tenure-has been proposed as a means to decrease the cost of PEVs while providing low cost energy storage to other fields (e.g., electric utility markets). To understand the value of used automotive batteries, however, we must first answer several key questions related to battery degradation, including: How long will PEV batteries last in automotive service? How healthy will PEV batteries be when they leave automotive service? How long will retired PEV batteries last in second-use service? How well can we best predict the second-use lifetime of a used automotive battery? Under the support of the U.S. Department of Energy's Vehicle Technologies Office, the National Renewable Energy Laboratory has developed a methodology and the requisite tools to answer these questions, including the Battery Lifetime Simulation Tool (BLAST).

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

With increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the automotive gasoline fuel spray has become essential. The acquisition of accurate and repeatable spray data is even more critical when a combustion strategy such as gasoline direct injection is to be utilized. Without industry-wide standardization of testing procedures, large variablilities have been experienced in attempts to verify the claimed spray performance values for the Sauter mean diameter, Dv90, tip penetration and cone angle of many types of fuel sprays. A new SAE Recommended Practice document, J2715, has been developed by the SAE Gasoline Fuel Injection Standards Committee (GFISC) and is now available for the measurement and characterization of the fuel sprays from both gasoline direct injection and port fuel injection injectors.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

Plug-in hybrid electric vehicle (PHEV) technology will provide substantial reduction in petroleum consumption as demonstrated in previous studies. Platform engineering steps including, reduced mass, improved engine efficiency, relaxed performance, improved aerodynamics and rolling resistance can impact both vehicle efficiency and design. Simulations have been completed to quantify the relative impacts of platform engineering on conventional, hybrid, and PHEV powertrain design, cost, and consumption. The application of platform engineering to PHEVs reduced energy storage system requirements by more than 12%, offering potential for more widespread use of PHEV technology in an energy battery supply-limited market. Results also suggest that platform engineering may be a more cost-effective way to reduce petroleum consumption than increasing the energy storage capacity of a PHEV.

The requirement of reduced emissions and improved fuel economy led the introduction of direct-injection (DI) spark-ignited (SI) engines. Dual-fuel injection system (direct-injection and port-fuel-injection (PFI)) was also used to improve engine performance at high load and speed. Ethanol is one of the several alternative transportation fuels considered for replacing fossil fuels such as gasoline and diesel. Ethanol offers high octane quality but with lower energy density than fossil fuels. This paper presents the combustion characteristics of a single cylinder dual-fuel injection SI engine with the following fueling cases: a) gasoline for PFI and DI, b) PFI gasoline and DI ethanol, and c) PFI ethanol and DI gasoline. For this study, the DI fueling portion varied from 0 to 100 percentage of the total fueling over different engine operational conditions while the engine air-to-fuel ratio remained at a constant level.

This paper focuses on the numerical investigation of the mixing and combustion of ethanol and gasoline in a single-cylinder 3-valve direct-injection spark-ignition engine. The numerical simulations are conducted with the KIVA code with global reaction models. However, an ignition delay model mitigates some of the deficiencies of the global one-step reaction model and is implemented via a two-dimensional look-up table, which was created using available detailed kinetics models. Simulations demonstrate the problems faced by ethanol operated engines and indicate that some of the strategies used for emission control and downsizing of gasoline engines can be employed for enhancing the combustion efficiency of ethanol operated engines.

Because combustion engine equipped vehicles must conform to stringent hydrocarbon (HC) emission requirements, many of them on the road today are equipped with an engine air intake system that utilizes a hydrocarbon adsorber. Also known as HC traps, these devices capture environmentally dangerous gasoline vapors before they can enter the atmosphere. A majority of these adsorbers use activated carbon as it is cost effective and has excellent adsorption characteristics. Many of the procedures for evaluating the adsorbtive performance of these emissions devices use mass gain as the measurand. It is well known that activated carbon also has an affinity for water vapor; therefore it is useful to understand how well humidity must be controlled in a laboratory environment. This paper outlines investigations that were conducted to study how relative humidity levels affect an activated carbon hydrocarbon adsorber.

Electrifying transportation can reduce or eliminate dependence on foreign fuels, emission of green house gases, and emission of pollutants. One challenge is finding a pathway for vehicles that gains wide market acceptance to achieve a meaningful benefit. This paper evaluates several approaches aimed at making plug-in electric vehicles (EV) and plug-in hybrid electric vehicles (PHEVs) cost-effective including opportunity charging, replacing the battery over the vehicle life, improving battery life, reducing battery cost, and providing electric power directly to the vehicle during a portion of its travel. Many combinations of PHEV electric range and battery power are included. For each case, the model accounts for battery cycle life and the national distribution of driving distances to size the battery optimally. Using the current estimates of battery life and cost, only the dynamically plugged-in pathway was cost-effective to the consumer.

The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

Delphi and the National Renewable Energy Laboratory (NREL) collaborated to develop a simulation code to model the mechanical and electrical architectures of a series hybrid vehicle simultaneously. This co-simulation code is part of the larger ADVISOR® product created by NREL and diverse partners. Simulation of the macro power flow in a series hybrid vehicle requires both the mechanical drivetrain and the entire electrical architecture. It is desirable to solve the electrical network equations in an environment designed to comprehend such a network and solve the equations in terms of current and voltage. The electrical architecture for the series hybrid vehicle has been modeled in Saber™ to achieve these goals. This electrical architecture includes not only the high-voltage battery, generator, and traction motor, but also the normal low-voltage bus (14V) with loads common to all vehicles.

Internal combustion engines are designed to maximize power subject to meeting exhaust emission requirements and minimizing fuel consumption. Maximizing engine power and fuel economy is limited by engine knock for a given air-to-fuel charge. Therefore, the ability to detect engine knock and run the engine at its knock limit is a key for the best power and fuel economy. This paper shows inaudible knock detection ability using in-cylinder ionization signals over the entire engine speed and load map. This is especially important at high engine speed and high EGR rates. The knock detection ability is compared between three sensors: production knock (accelerometer) sensor, in-cylinder pressure and ionization sensors. The test data shows that the ionization signals can be used to detect inaudible engine knock while the conventional knock sensor cannot under some engine operational conditions.

MBT timing for an internal combustion engine is also called minimum spark timing for best torque or the spark timing for maximum brake torque. Unless engine spark timing is limited by engine knock or emission requirements at a certain operational condition, there exists an MBT timing that yields the maximum work for a given air-to-fuel mixture. Traditionally, MBT timing for a particular engine is determined by conducting a spark sweep process that requires a substantial amount of time to obtain an MBT calibration. Recently, on-line MBT timing detection schemes have been proposed based upon cylinder pressure or ionization signals using peak cylinder pressure location, 50 percent fuel mass fraction burn location, pressure ratio, and so on. Because these criteria are solely based upon data correlation and observation, both of them may change at different engine operational conditions. Therefore, calibration is still required for each MBT detection scheme.

An ADVISOR model of a large sport utility vehicle with a fuel cell / battery hybrid electric drivetrain is developed using validated component models. The vehicle mass, electric traction drive, and total net power available from fuel cells plus batteries are held fixed. Results are presented for a range of fuel cell size from zero (pure battery EV) up to a pure fuel cell vehicle (no battery storage). The fuel economy results show that some degree of hybridization is beneficial, and that there is a complex interaction between the drive cycle dynamics, component efficiencies, and the control strategy.

The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.

Environmental concerns and changes in regulations around the world are turning mass-production electric vehicles (EVs) a reality. While the average driver is very familiar with the instruments available for the current internal combustion engine vehicles (ICEVs), the same does not hold for EVs. They require unique gages and tell-tales (also known as warning lights), tailored to their architecture, operating modes and intended use. This paper makes a comparison of the instruments used in ICEVs and EVs, suggesting a minimum set and standardization of the associated symbols.

The National Renewable Energy Laboratory (NREL) has conducted a series of chassis dynamometer and road tests on the 2000 model-year Honda Insight. This paper will focus on results from the testing, how the results have been applied to NREL's Advanced Vehicle Simulator (ADVISOR), and how test results compare to the model predictions and published data. The chassis dynamometer testing included the FTP-75 emissions certification test procedure, highway fuel economy test, US06 aggressive driving cycle conducted at 0°C, 20°C, and 40°C, and the SC03 test performed at 35°C with the air conditioning on and with the air conditioning off. Data collection included bag and continuously sampled emissions (for the chassis tests), engine and vehicle operating parameters, battery cell temperatures and voltages, motor and auxiliary currents, and cabin temperatures.