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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

The new inline six cylinder Twin-Turbo gasoline engine forms the pinnacle of BMW's wide range of straight-six power units, developing maximum output of 300hp and a peak torque of 300 lb-ft with a displacement of 3.0 litre. Using two turbochargers in combination with the new BMW High Precision Fuel Injection leads to a responsive build-up of torque and to an impressive development of power over a wide engine speed range. This paper gives a detailed overview of the turbocharger-and the injection system and describes the effect of both systems on power and torque, as well as on fuel consumption and emission. The big advantage of using two small turbochargers is their low moment of inertia, even the slightest movement of the accelerator pedal by the driver's foot serving to immediately build up superior pressure and power. This puts an end to the turbo “gap” previously typical of a turbocharged power unit.

In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

In the environmentally conscious world we live in, auto manufacturers are under extreme pressure to reduce tailpipe emissions from cars and trucks. The manufacturers have responded by creating clean-burning engines and exhaust treatments that mainly produce CO2 and water vapor along with trace emissions of pollutants such as CO, THC, NOx, and CH4. The trace emissions are regulated by law, and testing must be performed to show that they are below a certain level for the vehicle to be classified as road legal. Modern engine and pollution control technology has moved so quickly toward zero pollutant emissions that the testing technology is no longer able to accurately measure the trace levels of pollutants. Negative emission values are often measured for some pollutants, as shown by results from eight laboratories independently testing the same SULEV automobile.

AJ alloy is used with a new Aluminum-Magnesium Composite Design, which is an innovative approach to lightweight crankcase technology. The component is manufactured using high pressure die cast process. A wide range of chemical compositions was used to develop a good understanding of the behavior of this alloy system (castability, thermophysical, mechanical, microstructure). The basic mechanical properties were determined from separately die cast samples and also from samples machined out from high pressure die cast components. Tensile, creep, bolt load retention/relaxation and high cycle fatigue properties were established and analyzed using multivariate analysis and statistical approach. This methodology was used to select the optimal chemical composition to match the requirements. The sensitivity of the alloy to heat exposure was investigated for both mechanical properties and microstructure.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

In the near future the effort on the development of exhaust gas treatment systems must be increased to meet the stringent emission requirements. If the relevant physical and chemical models are available, the numerical simulation is an important tool for the design of these systems. This work presents a CFD model that allows to cover the full range of applications in this area. After a detailed presentation of the theoretical background and the modeling strategies results for the simulation of a close-coupled catalyst are shown. The presented model is also applied to the oxidation of nitrogen oxides, to a diesel particle filter and a fuel-cell reformer catalyst.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

The spray-guided BMW DI combustion system eliminates the most important disadvantages of the wall-and air-guided 1st generation DI combustion systems. With its central injector position, the spray-guided system provides a stratified mixture at the spark plug and reduces wall wetting significantly. The low spray penetration and high spray stability of the outward-opening piezo injector allow an extension of the stratified engine map to higher engine load and speed. The piezo drive permits an extremely fast opening of the injector needle, thus enabling multiple injections with very short delay times and high flexibility for the calibration strategy to supply a very efficient combustion with low unburnt hydrocarbon and carbon monoxide emissions. Compared to a conventional throttled SI engine, the spray-guided system shows a fuel consumption potential of about 20% in the NEDC.

Automotive clear coats have a broad field of requirements to fulfill, e.g. weathering stability, stone chipping, chemical resistance, scratch resistance, and have to show a brilliant surface appearance. Beside this, the paint and repair process for high volume car manufacturing must be fulfilled with respect to costs and the environment. From the development point of view of a car manufacture interactions between these properties and the critical way of understanding and describing the value for the customer is shown. The conclusion of this scenario and a detailed benchmark study of different new clear coats guide to the development of the ‘Next generation’ of powder clear coats.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

The NO formation is essentially determined by the flame temperature. In an engine the latter depends on the composition of the fuel and the intake gas. In this study the efficiency of various NO reducing measures is analysed by means of a comparison of measurements and computations for the Most frequent operation point of a 1.9 1 DI Diesel engine. The O2 concentration, which is shown to be the dominant source of influence on the flame temperature and NO formation, is varied using synthetic gas mixtures or by EGR. The molar heat capacity of CO2 and H2O in the recirculated exhaust gas, the intake temperature and the H/C ratio in the fuel are less important for the formation of NO. Measures which reduce the NO formation increase the ignition delay and thereby the fraction of the premixed combustion. The impact of EGR on the combustion process is illustrated by high speed filming.

The formation of soot during the first phase and the oxidation of soot during the later phase of the combustion in a direct-injection diesel engine have been investigated in detail by an extinction method. The experiments were performed in a 1.9 l near-production high-speed four-cylinder in-line direct-injection diesel engine for passenger cars for different rates of exhaust gas recirculation (EGR) and for different fuels. The measurements result in crank angle resolved and cycle-averaged soot mass concentrations in the piston bowl and the combustion chamber. The results show that with increasing EGR-rates the amount of soot formed is increased only slightly but the amount of soot oxidized during combustion decreases significantly. This is assumed to be the main reason for the increase of soot in the exhaust gas with increasing EGR-rates.

Non-intrusive temperature measurements based on single-line laser-induced fluorescence of molecular oxygen in the transparent IDEA Diesel engine were investigated. Oxygen molecules were excited to fluorescence with a narrowband, tunable ArF excimer laser at 193 nm. The resulting fluorescence signals were recorded with an image-intensified CCD camera. The temperature increase during the compression phase of the four-cylinder direct injection Diesel engine could be evaluated from the LIF signals. In the crank angle range of the measurements, good agreement between measured and calculated temperatures (polytropic compression) was observed.

This paper describes an investigation of one operating point of the transient warmup curve of a gasoline engine. Coolant liquid and oil of this engine have been cooled down to a constant low level in order to perform detailed measurements and an analysis of this particular warmup point. The influence of low coolant temperature, different pressure drop in an air assisted fuel injection system and a variation of ignition angles on specific fuel consumption, exhaust emissions, energy conversion etc. will be shown. The results show that the suggested test procedure (keeping the coolant temperature at a constant low level) provides the possibility to simulate the behaviour of an engine with air assisted fuel injection during warmup. During this warmup period it is desired to run the engine with retarded ignition timing to realize a fast catalyst warmup.