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Selective Catalytic Reduction (SCR), using urea injection, is being examined as a method for substantial reduction of oxides of nitrogen (NOx) for diesel engines, but the urea injection rates must be controlled to match the NOx production which may need to be predicted during open loop control. Unfortunately NOx is usually measured in the laboratory using a full-scale dilution tunnel and chemiluminescent analyzer, which cause delay and diffusion (in time) of the true manifold NOx concentration. Similarly, delay and diffusion of measurements of all emissions cause the task of creating instantaneous emissions models for vehicle simulations more difficult. Data were obtained to relate injections of carbon dioxide (CO2) into a tunnel with analyzer measurements. The analyzer response was found to match a gamma distribution of the input pulse, so that the analyzer output could be modeled from the tunnel CO2 input.

Relationships between diesel particulate matter (PM) mass and gaseous emissions mass produced by engines have been explored to determine whether any gaseous species may be used as surrogates to infer PM quantitatively. It was recognized that sulfur content of fuel might independently influence PM mass, since PM historically is composed of elemental carbon, organic carbon, sulfuric acid, ash and wear particles. Previous research has suggested that PM may be correlated with carbon monoxide (CO) for an engine that is exercised through a variety of speed and load cycles, but that the correlation does not extend to a group of engines. Large databases from the E-55/59 and Gasoline/Diesel PM Split programs were employed, along with the IBIS bus emissions database and several additional data sets for on- and off-road engines to examine possible relationships.