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EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

The effect of multiple injections in a heavy-duty diesel engine was investigated by focusing on single-pilot injection and double-pilot injection strategies with a wide injection timing range, various injection quantity ratios, and various dwell times. Combustion characteristics were studied through flame visualization and heat release analyses as well as emissions tests. Single-pilot injection resulted in a dramatic reduction in nitrogen oxide and smoke emissions when the injection timing was advanced over 40° CA before the start of injection (BSOI) due to combustion with partially premixed charge compression ignition. A brown-colored flame area, which indicates a very fuel-rich mixture region, was rarely detected when more fuel was injected during single-pilot injection. However, hydrocarbon emission increased up to intolerable levels because fuel wetting on the cylinder wall increased.

This paper describes the results of a DOE (design of experiment) applied to an exhaust heat exchanger to lower the exhaust gas temperature mainly under high load conditions. The heat exchanger was installed between the exhaust manifold and the inlet of the close-coupled catalytic converter (CCC) to avoid thermal aging. The DOE evaluates the influence of the selected eight design parameters of the heat exchanger geometry on the performance of the exhaust gas cooling system, and the interaction between these parameters. To maximize the heat transfer between exhaust gas and coolant, fins were implemented at the inner surface of the heat exchanger. The design parameters consist of the fin geometry (length, thickness, arrangement, number of fin), coolant direction, exchanger wall thickness, and the length of the heat exchanger. The acceptable range of each design parameter is discussed by analyzing the DOE results.

The Homogeneous Charge Compression Ignition (HCCI) combustion concept is currently under widespread investigation due to its potential to increase thermal efficiency while greatly decreasing harmful exhaust pollutants. Simulation tools have been developed to explore the implications of initial mixture thermodynamic state on engine performance and emissions. In most cases these modeling efforts have coupled a detailed fuel chemistry mechanism with empirical descriptions of the in-cylinder heat transfer processes. The primary objective of this paper is to present a fundamentally based boundary layer heat transfer model. The two-zone combustion model couples an adiabatic core zone with a boundary layer heat transfer model. The model predicts film coefficient, with approximately the same universal shape and magnitudes as an existing global model.

In order to reduce hydrocarbon emission in gasoline engine, especially during warming-up period, it is necessary to estimate the fuel and fuel product flow rate in the emission gas. The intake airflow rate should also be estimated. A strategy was proposed to estimate air fuel ratio in a spark ignition engine. The mass of air in the cylinder was determined by filling-emptying method, and the fuel in the intake manifold and cylinder was estimated by the “wall-wetting” effect calculation. The use of graphical dynamic system control software is becoming more popular as automotive engineers strive to reduce the time to develop new control systems. The rapid prototype engine controller has been developed by using MATLAB, SIMULINK, REAL TIME WORKSHOP, xPC Target, and WATCOM C++. The sensor data from the engine will be transferred to computer, and the fuel delivery will be calculated.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

When automobile hydrocarbons are exhausted into the atmosphere in the presence of NOx and sunlight, ground-level ozone is formed. While researchers have used Maximum Incremental Reactivity (MIR) factors to estimate ozone production, this procedure often overestimates Local Ozone Production (LOP) because it does not consider local atmospheric conditions. In this paper, an enhanced MIR methodology for estimating actual LOP attributable to a vehicle in a particular ozone problem area is presented. In addition to using tabulated MIR factors, the procedure also uses local hydrocarbon reaction terms and a relative mechanistic reactivity term that account for local atmospheric conditions. Through this approach, the effects of hydrocarbon reaction rates, hydrocarbon residence times, and prevailing HC/NOx ratio are accounted for. The procedure is intended to enable automotive engineers to more realistically estimate actual local ozone production resulting from hydrocarbon emissions.

Mode transition between low temperature combustion and conventional combustion was investigated in a direct injection diesel engine. Low temperature diesel combustion was realized by means of high exhaust gas recirculation rate (69~73%) and early injection timing (-28~ -16 crank angle degree after top dead center) compared with those (20% exhaust gas recirculation rate and -8 crank angle degree after top dead center) of conventional combustion. Tests were carried out at different engine speeds and injection pressures. Exhaust gas recirculation rate was changed transiently by controlling each throttle angle for fresh air and exhaust gas recirculation to implement mode transition. Various durations for throttle transition were applied to investigate the effect of speed change of exhaust gas recirculation rate on the characteristics of mode transition.

The effect of pilot injection and exhaust gas recirculation (EGR) on premixed charge compression ignition (PCCI) combustion was investigated in a single-cylinder direct-injection diesel engine with low engine speed and low load. The injection timing of PCCI combustion was fixed at 25 ~ 30 crank angle degree before top dead center (°CA BTDC) based on the ignition delay and power output. The level of oxides of nitrogen (NOx) emissions of PCCI combustion was 68% lower than that of conventional diesel combustion owing to the reduction of near-stoichiometric region which is well known as the main source of NOx formation. However, the indicated mean effective pressure (IMEP), hydrocarbon (HC), particulate matter (PM) and carbon monoxide (CO) emissions deteriorated compared with conventional diesel combustion because of early injection, advanced combustion phase and lowered combustion temperature. EGR has been applied to PCCI combustion.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

The characteristics of soot particles in an exhaust gas for low temperature diesel combustion (LTC) compared with conventional combustion in a compression ignition engine were experimentally investigated by the elemental and thermogravimetric analysis (TGA). Morphology of soot particles was also studied by the transmission electron microscopy (TEM). From the result of the TGA, the water can be evaporated until about 150°C for both combustion regimes. The soot particles for LTC contained more volatile hydrocarbons, which can be easily evaporated from 200°C to 420°C compared with conventional diesel combustion. The soot oxidation for conventional combustion occurs up to 600°C, on the other hand the particles for LTC is oxidized below 520°C. Elemental analysis showed higher oxygen weight fraction resulted from the oxygenated hydrocarbon for the soot particles in LTC. TEM has shown primary particles to be in a diameter range of 20 to 50 nm for conventional diesel combustion.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.

Engine performance under transients is greatly affected by the fuel behavior in the induction systems. To better understand the fuel behavior, a computer model has been developed to study the one-dimensional coupled heat and mass transfer processes occurring during the transient evaporation of liquid fuel from a heated surface into stagnant air. The energy and mass diffusion equations are solved simultaneously to yield the transient temperatures and species concentrations using a modified finite difference technique. The numerical technique is capable of solving the coupled equations while simultaneously tracking the movement of the evaporation interface. Evaporation results are presented for various initial film thicknesses representing typical puddle thicknesses for multi-point fuel injection systems using heptane, octane, and nonane pure hydrocarbon fuels.

In this study, single and double post injections were applied to diesel premixed charge compression ignition (PCCI) combustion to overcome the drawbacks those are high level of hydrocarbons (HC) and carbon monoxide (CO) emissions in a single-cylinder direct-injection diesel engine. The operating conditions including engine speed and total injection quantity were 1200 rpm and 12 mg/cycle, which are the representative of low engine speed and low load. The main injection timing of diesel PCCI combustion was set to 28 crank angle degree before top dead center (CAD BTDC). This main injection timing showed 32% lower level of nitric oxides (NOx) level and 8 CAD longer ignition delay than those of conventional diesel combustion. However, the levels of HC and CO were 2.7 and 3 times higher than those of conventional diesel combustion due to over-lean mixture and wall wetting of fuel.

Combustion in engines can be controlled by the amount of residual gas, which has high temperature and heat capacity compared with fresh charge. Residual gas also acts like a dilution gas during combustion period. Accordingly, combustion duration increases, while the peak combustion temperature and nitrogen oxides (NOx) decreases. Amount of residual gas is affected by pressure difference between exhaust and intake, valve timing and engine speed. The main objective of this work is to identify the effects of exhaust throttle, valve timing and load conditions on residual gas fraction and engine performance. The intake valve open timing was varied freely under fixed exhaust valve close (EVC) timing. Additionally, exhaust throttle has been installed in the exhaust manifold to build up the exhaust back-pressure allowing extra amount of exhaust gases to be admitted into the cylinder during the valve overlap duration.

Despite remarkable progress made over the past 30 years, automobiles continue to be a major source of hydrocarbon emissions. The objective of this study is to evaluate whether variable exhaust valve opening (EVO) and exhaust valve closing (EVC) can be used to reduce hydrocarbon emissions. An automotive gasoline engine was tested with different EVO and EVC timings under steady-state and start-up conditions. The first strategy that was evaluated uses early EVO with standard EVC. Although exhaust gas temperature is increased and catalyst light-off time is reduced, the rapid drop in cylinder temperature increases cylinder-out hydrocarbons to such a degree that a net increase in hydrocarbon emissions results. The second strategy that was evaluated uses early EVO with early EVC. Early EVO reduces catalyst light-off time by increasing exhaust gas temperature and early EVC keeps the hydrocarbon-rich exhaust gas from the piston crevice from leaving the cylinder.