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Theoretically, homogeneous charge compression engines (HCCI) are able to grant a high thermal efficiency, as well as a low NOx and particulate emissions. This ability is mainly due to the combustion process, which, contrary to both Diesel and Gasoline engine, is homogeneous in time and space within the combustion chamber. But despite these advantages, the engine operating condition is limited by the narrow boundaries of misfire at low load and knocking at high load. For that matter, one of the numerous ways of overcoming knocking is to deliberately create fuel inhomogeneities within the combustion chamber, since it has proved to lengthen combustion duration and to drastically reduce maximum pressure rise rate (PRR). Nevertheless, though the global effects of fuel inhomogeneities on PRR have been studied, we lack information that explains this phenomenon.

In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.