Search Results

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from Initial Boiling Point (IBP) of gasoline to Final Boiling Point (FBP) of diesel. Polyoxymethylene Dimethyl Ethers (PODEn) have high oxygen content and cetane number, are promising green additive to diesel fuel. In this paper, WDF was prepared by blending diesel and gasoline at ratio of 1:1, by volume; the mass distribution of oligomers in the PODE3-4 product was 88.9% of PODE3 and 8.46% of PODE4. Diesel fuel (Diesel), WDF (G50D50) and WDF (80%)-PODE3-4 (20%) (G40D40P20) were tested in a light-duty single-cylinder diesel engine, combustion characteristic, fuel consumption and exhaust emissions were measured. The results showed that: at idling condition, G40D40P20 has better combustion stability, higher heat release rate, higher thermal efficiency compared with G50D50.

Knocking is the main obstacle of increasing compression ratio to improve the thermal efficiency of gasoline engines. In this paper, the concept of stratified stoichiometric mixture (SSM) was proposed to suppress knocking in gasoline engines. The rich mixture near the spark plug increases the speed of the flame propagation and the lean mixture in the end gas suppresses the auto ignition. The overall air/fuel ratio keeps stoichiometric to solve the emission problem using three way catalysts (TWC). Moreover, both the rich zone and lean zone lead to soot free combustion due to homogeneous mixture. The effect on the knocking of homogeneous and stratified mixture was studied in a direct injection spark ignition (DISI) engine using numerical simulation and experimental investigation respectively.

Polyoxymethylene dimethyl ethers (PODEn) are promising alternative fuel candidates for diesel engines because they present advantages in soot reduction. This study uses a PODEn mixture (contains PODE3-6) from mass production to provide oxygen component in blend fuels. The spray combustion of PODEn-diesel bend fuels in a constant volume vessel was studied using high speed imaging, PLII-LEM and OH* chemiluminescence. Fuels of several blend ratios are compared with pure diesel. Flame luminance data show a near linear decrease tendency with the blend ratio increasing. The OH* images reveal that the ignition positions of all the cases have small differences, which indicates that using a low PODEn blend ratio of no more than 30% does not need significant adjustment in engine combustion control strategies. It is found that 30% PODEn blended with diesel (P30) can effectively reduce the total soot by approximately 68% in comparison with pure diesel.

High boost and direct injection are effective ways for energy saving in gasoline engines. However, the occurrence of super-knock at high load has become a main obstacle for further improving power density and fuel economy. It has been known that super-knock can be induced by pre-ignition, and oil droplet auto-ignition is found to be one of the possible mechanisms. In this study, experiments were conducted in a single-cylinder thermal research engine (TRE), in which different types of oil and surrogates were directly injected into the cylinder and then led to pre-ignition and super-knock. The effect of oil injection timing, oil injection quantity, different gasoline and different oil were tested. All the oil in this work could induce pre-ignition, even though their combustion phasing was much later than that in the case of n-hexadecane.

Particle Number (PN) have already been a big issue for developing high efficiency internal combustion engines (ICEs). In this study, controlled spark-assisted stratified compression ignition (SSCI) with moderate end-gas auto-ignition was used for reducing PN in a high compression ratio gasoline direct injection (GDI) engine. Under wide open throttle (WOT) and Maximum Brake Torque timing (MBT) condition, high external cooled exhaust gas recirculation (EGR) was filled in the cylinder, while two-stage direct injection was used to form desired stoichiometric but stratified mixture. SSCI combustion mode exhibits two-stage heat release, where the first stage is associated with flame propagation induced by spark ignition and the second stage is the result of moderate end-gas auto-ignition without pressure oscillation at the middle or late stage of the combustion process.

Homogeneous Charge Induced Ignition (HCII) combustion is believed to be a promising approach to achieve clean and high efficiency combustion. HCII can be realized by using port-injection of the high-volatile fuel (gasoline) to prepare in-cylinder homogeneous charge and direct injection of the high-ignitable fuel (diesel) near the top dead center to control the start of combustion. In the current study, a numerical study was carried out to understand the mixing and auto-ignition process in HCII combustion. A multicomponent chemical kinetic mechanism for gasoline and diesel, consisting of n-heptane, iso-octane, ethanol, toluene, diisobutylene and n-decane, has been developed for predicting their ignition and oxidation. The final mechanism consists of 104 species and 398 reactions. This mechanism was validated with the experimental data of ignition delay times and laminar flame speeds for each component and real transportation fuels.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

A new combustion mode namely multiple premixed compression ignition (MPCI) for gasoline engines was proposed. The MPCI mode can be realized by two or more times gasoline injections into cylinder with a high pressure around the compression TDC and featured with a premixed combustion after each injection in the cylinder, which is different from the existed gasoline direct injection compression ignition (GDICI) modes such as homogeneous charge compression ignition (HCCI) mode with gasoline injection occurred in intake stroke, and partially premixed compression ignition (PPCI) mode with multiple gasoline injections in intake and compression strokes before the start of combustion (SOC). Therefore the spray and combustion of the MPCI mode are alternatively occurred as "spray-combustion-spray-combustion" near the TDC, rather than "spray-spray-combustion" sequence as traditional PPCI gasoline engines.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.

Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.