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Abstract Addition of hydrogen to hydrocarbons in premixed turbulent combustion is of technological interest due to their increased reactivity, flame stability and extended lean extinction limits. However, such flames are a challenge to reaction modelling, especially as the strong preferential diffusion effects modify the physical processes, which are of importance even for highly turbulent high-pressure conditions. In the present work, Reynolds-averaged Navier-Stokes (RANS) modelling is carried out to investigate pressure and hydrogen content on methane/hydrogen/air flames.

Abstract This work presents a numerical study of the performance and nitrogen oxides (NOx) emissions of a conventional ethanol engine converted to work as a flex-fuel nonconventional architecture: the Split-Cycle Engine (SCE). For this study, the conventional engine fueled with hydrous ethanol was modeled and validated with data from experimental tests. Then the model was converted to operate as an SCE with two compressors and two expanders and simulated with a progressive downsizing of the compressors of the SCE. When the swept volume of the compressors was reduced to 87% of that of the expanders, the thermal conversion efficiency increased by 3.3%. Because of this, the downsized SCE was submitted to simulation runs using two different fuels: hydrous ethanol (H100) and an indolene-ethanol blend (H85). The results of the simulations were compared to the experimental results of the conventional engine.

Abstract The rapid utilization of fossil fuels has triggered the finding of alternative renewable fuel that replaces or reduces the consumption by alternative fuels for fueling compression ignition (CI) engines. One such renewable fuel is ethanol which can be manufactured from biomass. The present study details the utilization of an optimum amount of ethanol in CI engine by modifying the operating parameters. It was already published in the previous paper that 45% ethanol can be utilized along with diesel using 10% butanol as cosolvent. This fuel is also meeting the minimum requirement with respect to properties as per ASTM standards. This experimental study was performed to investigate the influence of modifying the engine operating parameters on the performance, combustion, and emission parameters fueled with the blend containing 45% ethanol under various load conditions.

Abstract To overcome the limitations such as lower combustion efficiency (CE) and higher cyclic variability in methanol/diesel (M/D) reactivity controlled compression ignition (RCCI) combustion, a fuel having higher reactivity than diesel (i.e., polyoxymethylene dimethyl ethers, PODE) was used in our previous study. Methanol/PODE RCCI combustion resulted in improved CE and reduction in soot and unburned emissions compared to M/D RCCI combustion. However, it was noticed that the use of neat PODE as high-reactivity fuel had damaged the fuel line materials frequently due to its higher oxygen content and lower viscosity. In addition, Methanol/PODE RCCI has also resulted in higher NO emissions compared to M/D RCCI combustion.

Abstract The aim of this article is to analyze the energy recovery of synthesis gases in an internal combustion engine, in terms of both their general behavior and recommendations for their future composition in production. This article presents an experimental analysis of power and economical parameters of internal combustion engine as a source of propulsion for a cogeneration unit. The power parameters were measured using 13 various low-energy synthesis gases as fuels. Most of them are methane-free synthesis gases. The main components of these synthesis gases were hydrogen, carbon monoxide, methane, carbon dioxide, and nitrogen. The composition of the synthesis gases responded to various waste gasification technologies. The mass lower heating value of the selected synthesis gases ranged from 4 to 8 MJ/kg.

Abstract In current production natural gas/gasoline bi-fuel vehicles, fuels are supplied via port fuel injection (PFI). Injecting a gaseous fuel in the intake port significantly reduces the volumetric efficiency and consequently torque as compared to gasoline. In addition to eliminating the volumetric efficiency challenge, direct injection (DI) of natural gas (NG) can enhance the in-cylinder flow, mixing, and combustion process resulting in improved efficiency and performance. A computational fluid dynamics (CFD) approach to model high-pressure gaseous injection was developed and validated against X-ray data from Argonne’s Advanced Photon Source. NG side and central DI of various designs and injection strategies were assessed experimentally along with CFD correlation. Significant effects on combustion metrics were quantified and explained via improved understanding of the in-cylinder flow effects due to NG injection.

Abstract Internal combustion (IC) engines are widely used in automotive, marine, agricultural and industrial machineries because of their superior performance, high efficiency, power density, durability and versatility in size and power outputs. In response to the demand for improved engine efficiency and lower CO2 emissions, advanced combustion process control techniques and more renewable fuels should be adopted for IC engines. Lean-burn combustion is one of the technologies with the potential to improve thermal efficiencies due to reduced heat loss and higher ratio of the specific heats. In order to operate the IC engines with very lean air/fuel mixtures, multiple turbulent jet pre-chamber ignition has been researched and developed to extend the lean-burn limit. Turbulent Jet Ignition (TJI) offers very fast burn rates compared to spark plug ignition by producing multiple ignition sites that consume the main charge rapidly.

Abstract This study focused on using adsorbents to suppress engine oil deterioration as a result of the influence of biodiesel. Engine oil performance is affected by the use of biodiesel that results in short period of oil drain interval. Neat base oil, 80% blended with biodiesel, was 20% thermo oxidatively aged. Magnesium aluminum hydroxycarbonate and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-buty-4-hydroxybenzyl)benzene were applied, and the formation of oligomers in the base oil-RME mixture was monitored. The adsorbents intercept the precursors of the aging procedure and, therefore, interfere with the aging process. The analysis with FTIR showed less to no formation of oligomers. About 90% reduction in the total acid number was observed, with about 90% reduction in viscosity increment. The adsorbents, therefore, have an enhanced influence on the oxidative stability of biodiesel and its blends.

Abstract In the last few years, reactivity-controlled compression ignition (RCCI) mode combustion has gained researchers’ attention due to its superior performance, combustion, and emission characteristics compared to other low-temperature combustion (LTC) strategies. In this study, RCCI mode combustion investigations were carried out to explore the effects of exhaust gas recirculation (EGR) and intake charge temperature (ICT) on combustion, performance, and emission characteristics of a mineral diesel/methanol-fueled engine. In this study, constant engine speed (1500 rpm) and load (3 bar brake mean effective pressure [BMEP]) were used to perform engine experiments. The premixed ratio (rp) of methanol was varied from rp = 0 to rp = 0.75, where rp = 0 represents the baseline compression ignition (CI) mode combustion. At all rp, EGR rate and ICT were varied from 0 to 30% and 40° to 80°C, respectively.

Abstract Combustion engines and liquid fuels are likely to continue playing a central role in freight transportation with renewable fuels reducing carbon emissions. Ethanol and methanol are future renewable fuels with a knock resistance that make them suitable for heavy-duty (HD) spark ignition (SI) engines. This simulation work focuses on the potential for improving the efficiency of an ethanol- and methanol-fueled HD SI engine using early intake valve closing Miller valve timing. With Miller valve timing, the expansion ratio and thermodynamic efficiency can be increased while maintaining the same effective compression ratio. However, Miller timing requires increased boost pressure to retain the same trapped air mass and also suffers from reduced in-cylinder turbulence.

Abstract In this experimental study, a novel combustion technique, “reactivity-controlled compression ignition” (RCCI), has been investigated using alcohols acting as low-reactivity fuel (LRF) and mineral diesel acting as high-reactivity fuel (HRF). Combustion experiments were performed in a single-cylinder research engine at a constant engine speed of 1500 rpm and a low engine load of 3 bar brake mean effective pressure (BMEP). RCCI combustion is a practical low-temperature combustion (LTC) concept, which was achieved using three primary alcohols: Methanol, Ethanol, and Butanol in different premixed ratios (rp = 0.25, 0.50, and 0.75) with mineral diesel. Results showed a relatively superior performance and emissions characteristics of RCCI combustion compared to conventional compression ignition (CI) combustion. The influence of LRF was visible in RCCI combustion, which exhibited a more stable combustion compared to the baseline CI combustion.

Corrigendum - The word "Differ" in the title should be corrected to "Different". The correct title is: Rapid Methodology to Simultaneous Quantification of Different Antioxidants in Biodiesel Using Infrared Spectrometry and Multivariate Calibration.

Abstract Particulate formation was studied under homogeneous-intent stoichiometric operating conditions when ethanol-blended (E10) or methanol-blended (M20) gasoline fuel was injected during intake stroke of a 4-stroke direct-injected engine. The engine was tested at wide open throttle under naturally aspirated conditions for a speed-load of 1500 rev/min and 9.8 bar indicated mean effective pressure. In-cylinder soot observations and exhaust soot measurements were completed for different fuel rail pressures, injection timings, coolant and piston temperatures of the optical engine. Fuel delivery settings were tested with both single and split injections during intake stroke. The target piston temperature of the optical engine was attained using pre-determined number of methane port fuel injection firing cycles. Overall, the in-cylinder soot observations correlated well with the engine-out soot measurements. A warmer cylinder head favored soot reduction for both fuels.

Abstract In the development of hydrocarbon (HC) traps for E85 fuel vehicle emission control, the addition of palladium (Pd) to BEA zeolite was studied for trapping and decreasing cold-start ethanol emissions. BEA zeolite after a laboratory aging at 750°C for 25 hours released nearly all of the trapped ethanol as unconverted ethanol at low temperature, and some ethene was released at a higher temperature by a dehydration reaction. The addition of Pd to BEA zeolite showed a decrease in the release of unconverted ethanol emissions even after the lab aging. The release of methane (CH4), acetaldehyde (CH3CHO), carbon monoxide (CO), and CO2 from Pd-BEA zeolite during desorption (temperature programmed desorption (TPD)) demonstrated that multiple ethanol reaction mechanisms were involved including dehydrogenation and decomposition reactions.

Abstract The aim of this work is to quantify three different antioxidants in biodiesel - Santoflex, baynox, and tocopherol-using Middle Infrared (MIR) spectroscopy and chemometrics. For the construction of the models, 28 samples containing an antioxidant in the range of 0.1 to 500 mg/kg in biodiesel were used. We developed three models based on PLS 1 multivariate calibration method to quantify each of the three antioxidants separately and a model based on PLS 2 method to quantify simultaneously all the antioxidants. All models were compared to the values of root mean square error of calibration (RMSEC) and validation (RMSEP). For the baynox, santoflex, and tocopherol antioxidants quantification using PLS 1, the values of RMSEC and RMSEP were 37.2, 18.8, 9.0 mg/kg, and 26.7, 21.1, 68.6 mg/kg, respectively.

Abstract In this article, a comparative study of hydrogenated vegetable oil (HVO) and Diesel was performed in two constant volume combustion rigs and an optical accessible compression-ignited chamber (OACIC). Ignition, combustion, and nitric oxide (NO) emissions were studied under constant ambient gas density of 16.4 kg/m3, 21% vol oxygen concentration, and two different injection pressures of 800 and 1000 bar. Emission of NO was measured only in the OACIC, while a line-of-sight soot temperature distribution by applying two-color pyrometry was investigated in both setups. In general, the HVO as alternative fuel showed shorter ignition delay and less NO emission than Diesel for both injection pressures. Due to difference in the molecular structure, soot temperature of biofuel flames had narrower temperature spectrum than conventional fuel. Moreover, this study reveals the significance of wall-jet interaction for utilization of the biofuel.

Abstract Environmental protection and the depletion of nonrenewable energy sources necessitate the search for the replacement of, among others, diesel fuel (Df) in diesel engines with renewable fuel without major structural changes. For this reason, vegetable oils are of interest as a possible fuel for this type of engine. Unfortunately, the physicochemical properties of vegetable oils differ significantly from Df. In addition to the boiling and freezing points, these properties include viscosity, density, and surface tension as well as wetting properties. For this reason, an attempt was made to modify these properties by adding n-hexane (Hex) and ethanol (Et) to canola oil (Co). The viscosity, density, surface tension, and wetting properties of Hex and Et are significantly different from those for Co.

Abstract Higher gasoline heat of vaporization (HOV) can enable higher compression-ratio, direct-injection, spark-ignition engines by providing evaporative cooling that effectively increases fuel knock resistance. Methods to directly measure this fuel property in complex gasoline samples are not well developed. This study aimed to further improve a differential scanning calorimetry/thermogravimetric analysis (DSC/TGA) method to measure the total and partial HOV of gasoline. Ten market gasoline samples were chosen to have a wide range of properties to assess the method’s capability across the entire volatility range, with an emphasis on understanding how well the method captures the initial 10% of sample evaporation and how much sample is left unevaporated at the end of the experiment.

Erratum

Abstract Biogas, natural gas, and their usage in the diesel engine will be important in the future. For this purpose, the effects of biogas on engine performance, emissions, and engine vibrations of the diesel engines with dual fuel system are investigated in comparison with natural gas. It has also been included in evaluating the deformation of the engine oil due to hydrogen sulfide combustion reactions. In this study, a constant speed, naturally aspirated, and direct injection of the diesel engine with volume of 2.5 liter has been converted into a dual fuel system that can be included in gas fuels. In order to determine engine performance, exhaust emissions, engine vibration, and noise, the tests were carried out at load stages of 5, 10, 15, 20, and 25 kW and at a constant speed of 1500 rpm. The experiments were first performed in a mono operation condition of the conventional diesel fuel.