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Gasoline and gasoline-ethanol sprays from an outward-opening piezo-injector were studied in a constant volume/pressure chamber using high-speed imaging and phase doppler anemometry (PDA) under stratified cold start conditions corresponding to a vehicle ambient temperature of 243 K (−30°C/−22°F); in-cylinder air pressure of 5 bar, air temperature of 350 K (−30°C/−22°F) and fuel temperature of 243 K. The effects of varying in-cylinder pressure and temperature, fuel injection pressure and fuel temperature on the formation of gasoline, E75 and pure ethanol sprays were investigated. The results indicate that fuel composition affects spray behaviour, but less than expected. Furthermore, varying the temperature of the fuel or the air surrounding the spray also had minor effects. As expected, the fuel injection pressure was found to have the strongest influence on spray formation under stratified conditions.

Future pressures to reduce the fuel consumption of passenger cars may require the exploitation of alternative combustion strategies for gasoline engines to replace, or use in combination with the conventional stoichiometric spark ignition (SSI) strategy. Possible options include homogeneous lean charge spark ignition (HLCSI), stratified charge spark ignition (SCSI) and homogeneous charge compression ignition (HCCI), all of which are intended to reduce pumping and thermal losses. In the work presented here four different combustion strategies were evaluated using the same engine: SSI, HLCSI, SCSI and HCCI. HLCSI was achieved by early injection and operating the engine lean, close to its stability limits. SCSI was achieved using the spray-guided technique with a centrally placed multi-hole injector and spark-plug. HCCI was achieved using a negative valve overlap to trap hot residuals and thus generate auto-ignition temperatures at the end of the compression stroke.

The development of high efficiency powertrains is a key objective for car manufacturers. One approach for improving the efficiency of gasoline engines is based on homogeneous charge compression ignition, HCCI, which provides higher efficiency than conventional strategies. However, HCCI is only currently viable at relatively low loads, primarily because at high loads it involves rapid combustion that generates pressure oscillations in the cylinder (ringing), and partly because it gives rise to relatively high NOX emissions. This paper describes studies aimed at increasing the viability of HCCI combustion at higher loads by using fully flexible valve trains, direct injection with charge stratification (SCCI), and intake air boosting. These approaches were complemented by using EGR to control NOX emissions by stoichiometric operation, which enables the use of a three-way catalyst.

Eight different cylinder pressure trace based knock detection methods are compared using two reference cycles of different time-frequency content, reflecting single blast and developing blast, and a test population of 300 knocking cycles. It is shown that the choice of the pass window used for the pressure data has no significant effect on the results of the different methods, except for the KI20. In contrast to other authors, no sudden step in the knock characteristics is expected; first, because the data investigated contain only knocking cycles, and second, because a smooth transition between normal combustion and knock is expected, according to recent knock theory. It is not only the correlation coefficient, but also the Kendall coefficient of concordance, that is used to investigate the differences between the knock classification methods.

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.

This investigation includes a comparison of two Fischer Tropsch (FT) fuels derived from natural gas and a Rapeseed Methyl Ester (RME) fuel with Swedish low sulfur Diesel in terms of emissions levels, fuel consumption and combustion parameters. The engine used in the study was an AVL single cylinder heavy-duty engine, equipped with a cylinder head of a Volvo D12 engine. Two loads (25% and 100%) were investigated at a constant engine speed of 1200 rpm. The engine was calibrated to operate in different levels of EGR and with variable injections timings. A design of experiments was constructed to investigate the effects of these variables, and to identify optimal settings. The results showed that the soot emissions yielded by FT and RME fuels are up to 40 and 80 percent lower than those yielded by the Swedish Diesel. In addition the FT fuel gave slightly lower, and the RME significant higher NOx emissions than the Swedish Diesel.

Cycle-resolved end-gas temperatures were measured using dual-broadband rotational CARS in a single-cylinder spark-ignition engine. Simultaneous cylinder pressure measurements were used as an indicator for knock and as input data to numerical calculations. The chemical processes in the end-gas have been analysed with a detailed kinetic mechanism for mixtures of iso-octane and n-heptane at different Research Octane Numbers (RON'S). The end-gas is modelled as a homogeneous reactor that is compressed or expanded by the piston movement and the flame propagation in the cylinder. The calculated temperatures are in agreement with the temperatures evaluated from CARS measurements. It is found that calculations with different RON'S of the fuel lead to different levels of radical concentrations in the end-gas. The apperance of the first stage of the autoignition process is marginally influenced by the RON, while the ignition delay of the second stage is increased with increasing RON.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

Optical studies of combusting diesel sprays were done on three different alternative liquid fuels and compared to Swedish environmental class 1 diesel fuel (MK1). The alternative fuels were Rapeseed Oil Methyl Ester (RME), Palm Oil Methyl Ester (PME) and Fischer-Tropsch (FT) fuel. The studies were carried out in the Chalmers High Pressure High Temperature spray rig under conditions similar to those prevailing in a direct-injected diesel engine prior to injection. High speed shadowgraphs were acquired to measure the penetration of the continuous liquid phase, droplets and ligaments, and vapor penetration. Flame temperatures and relative soot concentrations were measured by emission based, line-of-sight, optical methods. A comparison between previous engine tests and spray rig experiments was conducted in order to provide a deeper explanation of the combustion phenomena in the engine tests.

In the study reported here the combustion and emission characteristics of a heavy duty six-cylinder diesel engine fuelled with dimethyl ether (DME) of chemical grade and DME with small and varying amounts of methanol and/or water were experimentally investigated. In addition, the size distribution of emitted particles and selected unregulated emissions were sampled. Methanol and water additions had a very limited effect on emissions, but affected the combustion processes in a way that accentuated the premixed combustion and thus caused more energy to be released early in the cycle. At high load, however, the effect was reversed, due to the lack of distinct premixed combustion. The results confirm that DME combustion does not generate any accumulation mode particles. The particles that are detected are smaller than the soot size range and do not occur in greater numbers than those from a diesel engine in the corresponding size range.

Combustion information from three combustion chamber geometries was analyzed: Pancake and horseshoe geometry on a single-cylinder research engine, and pentroof geometry in a turbocharged four-cylinder production engine. Four different fuels were used. In the horseshoe configuration, the cylinder pressure traces from the burnt gas and from the end-gas pocket were evaluated. It is shown that the characteristics of knock are to a large degree a function of the combustion chamber geometry and that they are influenced strongly by the transducer position. It is shown for pentroof geometry that the number of cycles required to properly describe the knock population is a function of the knock intensity. A large error potential is shown for samples smaller than about 100 - 200 consecutive cycles. Good agreement between knock description based on accelerometer data and based on pressure data was found.

DME was tested in a heavy duty diesel engine and in an optically accessible high-temperature and pressure spray chamber in order to investigate and understand the effect of nozzle parameters on emissions, combustion and fuel spray concentration. The engine study clearly showed that smaller nozzle orifices were advantageous from combustion, efficiency and emissions considerations. Heat release analysis and fuel concentration images indicate that smaller orifices result in higher mixing rate between fuel and air due to reductions in the turbulence length scale, which reduce both the magnitude of fuel-rich regions and the steepness of fuel gradients in the spray, which enable more fuel to burn and thereby shorten the combustion duration.

A novel concept of combined hydrogen production and power generation system based on the combustion of aluminum in water is explored. The energy conversion system proposed is potentially able to provide four different energy sources, such us pressurized hydrogen, high temperature steam, heat, and work at the crankshaft on demand, as well as to fully comply with the environment sustainability requirements. Once aluminum oxide layer is removed, the pure aluminum can react with water producing alumina and hydrogen while releasing a significant amount of energy. Thus, the hydrogen can be stored for further use and the steam can be employed for energy generation or work production in a supplementary power system. The process is proved to be self-sustained and to provide a remarkable amount of energy available as work or hydrogen.

It has been previously shown that engine-out soot emissions can be reduced by using Fischer-Tropsch (FT) fuels, due to their lack of aromatics, compared to conventional Diesel fuels. In this investigation the engine-out emissions and fuel consumption parameters of an FT fuel derived from natural gas were compared to those of Swedish low sulfur diesel (MK1) when used in Low Temperature Combustion mode in a single cylinder heavy-duty diesel engine. The effects of varying Needle Opening Pressure (NOP), Charge Air Pressure (CAP) and Exhaust Gas Recirculation (EGR) according to an experimental design on the measured variables were also assessed. CAP and EGR were found to be the most significant factors for the combustion and emission parameters of both fuels. Increases in CAP resulted in lower soot emissions due to enhanced charge mixing, however NOx emissions rose as CAP increased.

The purpose of the investigation presented here was to compare the effects of fuel composition on combustion parameters, emissions and fuel consumption in engine tests and simulations with five fuels: a Diesel-water emulsion, a Diesel-ethanol blend, a Diesel-ethanol blend with EHN (cetane number improver), a Fischer-Tropsch Diesel and an ultra-low sulfur content Diesel. The engine used in the experiments was a light duty, single cylinder, direct injection, common rail Diesel engine equipped with a cylinder head and piston from a Volvo NED5 engine. In tests with each fuel the engine was operated at two load points (3 bar IMEP and 10 bar IMEP), and a pilot-main fuel injection strategy was applied under both load conditions. Data were also obtained from 3-D CFD simulations, using the KIVA code, to compare to the experimental results and to further analyze the effects of water and ethanol on combustion.

A semi-detailed chemical mechanism for combustion of gasoline-ethanol blends, which is based on sub-mechanisms of gasoline surrogate and for ethanol is developed and validated aiming at CFD engine modeling. The gasoline surrogate is composed of iso-octane, toluene, and n-heptane in volumetric proportions of 55%:35%:10%, respectively. In this way, the hydrogen-carbon atomic ratio H/C, which is around 1.87 for real gasoline, is accurately reproduced as well as a mixture equivalence ratio that is important for Gasoline Direct Injection engine applications. The integrated mechanism for gasoline-ethanol blends includes 120 species participating in 677 reactions. The mechanism is tested against experimental data on ignition delay times and laminar flame speeds, obtained for various n-heptane/iso-octane/toluene/ethanol-air mixtures under various equivalence ratios, initial temperatures, and pressures. Chemical, thermodynamic and transport properties used in the calculations are discussed.

To elucidate the processes controlling the auto-ignition timing and overall combustion duration in homogeneous charge compression ignition (HCCI) engines, the distribution of the auto-ignition sites, in both space and time, was studied. The auto-ignition locations were investigated using optical diagnosis of HCCI combustion, based on laser induced fluorescence (LIF) measurements of formaldehyde in an optical engine with fully variable valve actuation. This engine was operated in two different modes of HCCI. In the first, auto-ignition temperatures were reached by heating the inlet air, while in the second, residual mass from the previous combustion cycle was trapped using a negative valve overlap. The fuel was introduced directly into the combustion chamber in both approaches. To complement these experiments, 3-D numerical modeling of the gas exchange and compression stroke events was done for both HCCI-generating approaches.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).