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Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.

The sustainability of Martian outposts development is strongly based on the capability of achieving a high level of autonomy both in terms of operations management and of resources availability. In situ production of consumables is a key point to allow humans to work and live on Mars avoiding or limiting the need for re-supplies of materials from Earth. Required consumables can be produced in situ exploiting the locally available resources, but also by means of green-houses and waste recycle systems. Dedicated robotic missions for in situ demonstration of this type of technologies are a fundamental step of the Martian In Situ Resources Utilization (ISRU) development roadmap. This paper is focused on the extraction of oxygen and fuels (e.g. methane) from the Martian atmosphere, and presents a feasibility study for a small technological demonstration plant.

Thrust vectoring is an interesting propulsion solution in aeronautic applications due to its fast response, improving aircraft's performance for take-off, landing and flight, and enabling Short/Vertical Take-Off and Landing (S/VTOL). In this context, an attempt to design a radically new concept of thrust vectoring nozzle is in current development. This novel nozzle, called ACHEON, bases the jet deviation control on the interaction of two primary jets of different velocities, where the one with higher velocity entrains the one with lower velocity. Two cylindrical walls are positioned after the two air jets mixing. If the inlet conditions are not symmetric, the Coanda effect on the walls forces the resulting air jet to divert from the symmetry axis. This paper shows the experimental pressure distribution along the Coanda wall for different inlet.

Emissions from aviation have become a focus of increasing interest in recent years. The growth of civil aviation is faster than nearly all other economic sectors. Increased demand has led to a higher growth rate in fossil fuels consumption by the aviation sector. Despite more fuel-efficient and less polluting turbofan and turboprop engines, the growth of air travel contributes to increase pollution attributable to aviation. Aircraft are currently the only human-made in situ generators of emissions in the upper troposphere and in the stratosphere. The depletion of the stratosphere's ozone layer by CFCs and related chemicals has underscored the importance of anticipating other potential insults to the ozone layer. Different possible solutions have been advanced to reduce the environmental impact of aviation, such as electrification of ground operations, optimization of airline timetables and airspace usage, limitation of cruise altitude and increased use of turboprop aircrafts.