Search Results

Photocatalysis is used to mineralize water pollutants, providing water treatment without a waste stream. This water treatment method allows for a compact reactor design (i.e., reduced Equivalent Systems Mass (ESM)) that is applicable in future NASA missions that will require water recovery. The reactor would provide a post-processing unit to remove any organic contaminants (e.g., VOCs) not removed in prior water subsystems. Several approaches to the reactor design are being explored. Titanium dioxide (TiO2) is the chosen photocatalyst based on its proven performance and non-toxicity. Because of their propensity to adsorb pollutants, silica and activated carbon are being investigated as supporting materials for the titania. Three types of particles are being tested for their ability to destroy organic contaminants: silica gel doped with titania, activated carbon coated with titania, and silica gel doped with both activated carbon and titania. Each material has certain advantages.

NASA will require a safe and efficient method for water recovery on long-term space missions. Photocatalysis represents a promising solution for part of a system designed for recovery of water from humidity condensate, urine, and shower waste. It eliminates the need for chemical oxidants that are dangerous and difficult to transport, and the considerable energy consumption of distillation. In terms of decreasing the equivalent system mass (ESM) with respect to these alternative technologies, considerations for the volume, mass, cooling and crew time are also important. This photocatalytic reactor generates the oxidant in the form of hydroxyl radicals and valence band holes by exposing silica-titania composite particles with a barium ferrite core to ultraviolet light. The magnetic core of the catalyst allows for separation, confinement, and agitation.

NASA has identified a number of water treatment options that have shown promise in space. The water recovery system on any particular mission will be a collection of individual treatment units, with each treatment unit focusing on a select group of contaminants. The project objective has been to develop a microgravity-compatible, compact post processor based on magnetic agitation that is safe and reliable and that provides product water that meets or exceeds NASA's potable water quality requirements. The micron-sized magnetic photocatalytic particles have been proven durable and capable of oxidizing synthetic organic chemicals. The reactor has been optimized with respect to agitation frequency (50 Hz), UV wavelength (312 nm), and geometry (circular coiled reactor cell).