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As the United States makes plans to return astronauts to the moon and eventually send them on to Mars, designing the most effective, efficient, and robust spacesuit life support system that will operate successfully in dusty environments is vital. Some knowledge has been acquired regarding the contaminants and level of infiltration that can be expected from lunar and Mars dust, however, risk mitigation strategies and filtration designs that will prevent contamination within a spacesuit life support system are yet undefined. A trade study was therefore initiated to identify and address these concerns, and to develop new requirements for the Constellation spacesuit element Portable Life Support System. This trade study investigated historical methods of controlling particulate contamination in spacesuits and space vehicles, and evaluated the possibility of using commercial technologies for this application. The trade study also examined potential filtration designs.

Patent-pending Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is currently being investigated for removal and rejection of carbon dioxide (CO2) and heat from a Portable Life Support System (PLSS) to a Martian environment. The metabolically-produced CO2 present in the ventilation loop gas is collected using a CO2 selective adsorbent that has been cooled via a heat exchanger to near CO2 sublimation temperatures (∼195 K) with liquid CO2 (LCO2) obtained from Martian resources. Once the adsorbent is fully loaded, used, warm (∼300 K), moist ventilation loop gas is used to heat the adsorbent via another heat exchanger to reject the collected CO2 to the Martian ambient. Two beds are used to achieve continuous CO2 removal by cycling between the cold and warm conditions for adsorbent loading and regeneration, respectively.

Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed to address carbon dioxide (CO2) and heat removal/rejection in a Mars Portable Life Support System (PLSS). The technology utilizes an adsorbent that when cooled with liquid CO2 to near sublimation temperatures (∼195 K) removes metabolically-produced CO2 in the ventilation loop. Once fully loaded, the adsorbent is then warmed (∼300 K) externally by the ventilation loop, rejecting the captured CO2 to Mars ambient. Two beds are used to provide a continuous cycle of CO2 removal/rejection as well as facilitate heat exchange out of the ventilation loop. To investigate the feasibility of the technology, a series of model calibration experiments were conducted which lead to the selection and partial characterization of an appropriate adsorbent.

The National Aeronautics and Space Administration's (NASA) planned future missions set stringent demands on the design of the Portable Life Support System (PLSS), requiring dramatic reductions in weight, decreased reliance on supplies and greater flexibility for Extravehicular Activity (EVA) duration and objectives. Use of regenerable systems that reduce weight and volume of the space suit life support system is of critical importance to NASA, both for low orbit operations and for long duration manned missions. The carbon dioxide and humidity control unit in the existing PLSS design is relatively large, since it has to remove and store eight hours worth of carbon dioxide (CO2). If the sorbent regeneration can be carried out during the EVA with a relatively high regeneration frequency, the size of the sorbent canister and weight can be significantly reduced.

Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.

This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg (.0226-.046 atm). This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet.

The partial electrochemical reduction of carbon dioxide (CO2) using ceramic oxygen generators (COGs) is well known and widely studied. Conventional COGs use yttria-stabilized zirconia (YSZ) electrolytes and operate at temperatures greater than 700 °C. Operating at a lower temperature has the advantage of reducing the mass of the ancillary components such as insulation and heat exchangers (to reduce the COG oxygen output temperature for comfortable inhalation). Moreover, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight if the oxygen can be recovered. Recently, the University of Florida developed novel ceramic oxygen generators employing a bilayer electrolyte of gadolinia-doped ceria and erbia-stabilized bismuth oxide (ESB) for NASA's future exploration of Mars.

As part of NASA's initiative to develop an advanced portable life support system (PLSS), a baseline schematic has been chosen that includes gaseous oxygen in a closed circuit ventilation configuration. Supply oxygen enters the suit at the back of the helmet, passes over the astronaut's body, and is extracted at the astronaut's wrists and ankles through the liquid cooling and ventilation garment (LCVG). The extracted gases are then treated using a rapid cycling amine (RCA) system for carbon dioxide and water removal and activated carbon for trace gas removal before being mixed with makeup oxygen and reintroduced into the helmet. Thermal control is provided by a suit water membrane evaporator (SWME). As an extension of the original schematic development, NASA evaluated several Helmet Exhalation Capture System (HECS) configurations as alternatives to the baseline.

Metabolic heat regenerated temperature swing adsorption (MTSA) technology is being developed for removal and rejection of carbon dioxide (CO2) and heat from a portable life support system (PLSS) to the Martian environment. Previously, hardware was built and tested to demonstrate using heat from simulated, dry ventilation loop gas to affect the temperature swing required to regenerate an adsorbent used for CO2 removal. New testing has been performed using a moist, simulated ventilation loop gas to demonstrate the effects of water condensing and freezing in the heat exchanger during adsorbent regeneration. Also, the impact of MTSA on PLSS design was evaluated by performing thermal balances assuming a specific PLSS architecture. Results using NASA's Extravehicular Activity System Sizing Analysis Tool (EVAS_SAT), a PLSS system evaluation tool, are presented.

Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed for thermal and carbon dioxide (CO2) control for a Portable Life Support System (PLSS), as well as water recycling. CO2 removal and rejection is accomplished by driving a sorbent through a temperature swing starting at below freezing temperatures. The swing is completed by warming the sorbent with a separate condensing ice heat exchanger (CIHX) using metabolic heat from moist ventilation gas. The condensed humidity in the ventilation gas is recycled at the habitat. Designing a heat exchanger to efficiently transfer this energy to the sorbent bed and allow the collection of the water is a challenge since the CIHX will operate in a temperature range from 210 K to 280 K. The ventilation gas moisture will first freeze and then thaw, sometimes existing in three phases simultaneously.

Metabolic heat regenerated temperature swing adsorption (MTSA) that is incorporated into a Portable Life Support System (PLSS) is being explored as a viable means of removing and rejecting carbon dioxide (CO2) from an astronaut's ventilation loop. Sorbent pellets, which were used in previous work, are inherently difficult to heat and cool quickly. Further, their use in packed beds creates a large, undesirable pressure drop. Work has thus been done to assess the application and performance of aluminum foam that has been washcoated with a layer of sorbent. A to-scale sorbent bed, which is envisioned for use by a Martian PLSS, was designed, built, and tested. Performance of the assembly in regards to CO2 adsorption and pressure drop was assessed, and the results are presented here.

Under a NASA sponsored technology development activity, Hamilton Sundstrand has designed, fabricated, tested and delivered a prototype solid amine-based carbon dioxide (CO2) and water (H2O) vapor removal system sized for Extravehicular Activity (EVA) operation. The prototype system employs two alternating and thermally-linked solid amine sorbent beds to continuously remove CO2 and H2O vapor from a closed environment. While one sorbent bed is exposed to the vent loop to remove CO2 and water vapor, the other bed is exposed to a regeneration circuit, defined as either vacuum or an inert sweep gas stream. A linear spool valve, coupled directly to the amine canister assembly, is utilized to simultaneously divert the vent loop flow and regeneration circuit flow between the two sorbent beds.