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To detect an air-fuel ratio in wide range is very important to control the automotive engines with low fuel consumption and low exhaust emissions. Although the application of zirconia electrolyte for this purpose has been proposed by the authors several years ago, there remained several problems due to the contamination of gas diffusion apertures which are exposed to the exhaust gas environment. Here the behavior of ions transported in zirconia electrolyte have been analyzed to optimize the structure and characteristics, and to guarantee the long life operation of sensor. Gas contents and their reactions in combustion process under the wide range air-fuel ratio have been analyzed, and these results were reflected to the analysis of ion transportation in zirconia electrolyte. Experimental results supported the analytical results, and they showed the possibilities of long life operation of zirconia air-fuel ratio sensor utilizing ion transportation phenomena.

This report describes the development of an air fuel ratio sensor with a linear voltage output, and its signal processing module that is able to calibrate the sensor output function on the measuring point of the 20.9% oxygen concentration in atmospheric air and the zero diffusion current at stoichiometry as the reference. This sensing system is effective when applied to air fuel ratio PID feed back engine control and it is able to realize the reduction of initial variability of sensors, interchangeability of sensors, and long term output change of the sensor.