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Reactivity Controlled Compression Ignition (RCCI) has been shown to be an attractive concept to achieve clean and high efficiency combustion. RCCI can be realized by applying two fuels with different reactivities, e.g., diesel and gasoline. This motivates the idea of using a single low reactivity fuel and direct injection (DI) of the same fuel blended with a small amount of cetane improver to achieve RCCI combustion. In the current study, numerical investigation was conducted to simulate RCCI and HCCI combustion and emissions with various fuels, including gasoline/diesel, iso-butanol/diesel and iso-butanol/iso-butanol+di-tert-butyl peroxide (DTBP) cetane improver. A reduced Primary Reference Fuel (PRF)-iso-butanol-DTBP mechanism was formulated and coupled with the KIVA computational fluid dynamic (CFD) code to predict the combustion and emissions of these fuels under different operating conditions in a heavy duty diesel engine.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

The dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion could achieve high efficiency and low emissions over a wide range of operating conditions. However, further high load extension is limited by the excessive pressure rise rate and soot emission. Polyoxymethylene dimethyl ethers (PODE), a novel diesel alternative fuel, has the capability to achieve stoichiometric smoke-free RCCI combustion due to its high oxygen content and unique molecule structure. In this study, experimental investigations on high load extension of gasoline/PODE RCCI operation were conducted using late intake valve closing (LIVC) strategy and intake boosting in a single-cylinder, heavy-duty diesel engine. The experimental results show that the upper load can be effectively extended through boosting and LIVC with gasoline/PODE stoichiometric operation.

Diesel spray mixture formation is investigated at target conditions using multiple diagnostics and laboratories. High-speed Particle Image Velocimetry (PIV) is used to measure the velocity field inside and outside the jet simultaneously with a new frame straddling synchronization scheme. The PIV measurements are carried out in the Engine Combustion Network Spray A target conditions, enabling direct comparisons with mixture fraction measurements previously performed in the same conditions, and forming a unique database at diesel conditions. A 1D spray model, based upon mass and momentum exchange between axial control volumes and near-Gaussian velocity and mixture fraction profiles is evaluated against the data.

This work numerically investigates the detailed combustion kinetics of partially premixed combustion (PPC) in a diesel engine under three different premixed ratio fuel conditions. A reduced Primary Reference Fuel (PRF) chemical kinetics mechanism was coupled with CONVERGE-SAGE CFD model to predict PPC combustion under various operating conditions. The experimental results showed that the increase of premixed ratio (PR) fuel resulted in advanced combustion phasing. To provide insight into the effects of PR on ignition delay time and key reaction pathways, a post-process tool was used. The ignition delay time is related to the formation of hydroxyl (OH). Thus, the validated Converge CFD code with the PRF chemistry and the post-process tool was applied to investigate how PR change the formation of OH during the low-to high-temperature reaction transition. The reaction pathway analyses of the formations of OH before ignition time were investigated.

Butanol is an attractive alternative fuel by virtue of its renewable source and low sooting tendency. In this paper, three butanol isomers (n-butanol, isobutanol, and tert-butanol) were induced via port injection respectively and n-heptane was directly injected into the cylinder to investigate reactivity controlled compression ignition in a heavy-duty diesel engine. This work evaluates the potential of applying butanol as low reactivity fuel and the effects of reactivity gradient on combustion and emission characteristics. The experiments were performed from low load to medium-high load. Due to the different reactivities among the butanol isomers, the exhaust gas recirculation rate and the direct injection strategy were varied for a specific butanol isomer and testing load. Particularly, isobutanol/n-heptane can be operated with single direct injection and no exhaust gas recirculation up to medium load due to the high octane rating.

Multiple-injection strategies are characterized by a complex and transient interplay between high- and low-temperature reactions. Tracking low-temperature reaction products such as formaldehyde (CH2O) is particularly important to understand ignition phenomena and the so-called “combustion recession” that is observed in experiments. Experimentally, it is often difficult to discriminate between formaldehyde and other species such as poly-aromatic hydrocarbons, which is why a selective excitation approach is used in this work. Simultaneous high-speed imaging of the chemically-excited hydroxyl radical (OH*) is used to improve indication of flame location and second stage ignition. During experiments in a constant-volume vessel, two 0.5-ms injections of n-dodecane, separated by 0.5-ms dwell time, are injected into a 900-K ambient.

A fully coupled multi-dimensional CFD and reduced chemical kinetics model is adopted to investigate the effects of charge stratification on HCCI combustion and emissions. Seven different kinds of imposed stratification have been introduced according to the position of the maximal local fuel/air equivalence ratio in the cylinder at intake valve close. The results show that: The charge stratification results in stratification of the in-cylinder temperature. The former four kinds of stratification, whose maximal local equivalence ratios at intake valve close locate between the cylinder center and half of the cylinder radius, advance ignition timing, reduce the pressure-rise rate, and retard combustion-phasing. But the following three kinds of stratification, whose maximal local equivalence ratios at intake valve close appear between half of the cylinder radius and the cylinder wall, have little effect on the cylinder pressure.

The effects of various injection timing of methanol on thermo-atmosphere combustion of methanol by port injection of dimethyl ether (DME) and direct injection of methanol were experimentally investigated. The experiment results show that, as injection timing is at 6 degree before TDC, the combustion process comprises three stages: low temperature heat release of DME, high temperature heat release of DME and diffusion combustion of methanol. As injection timing increases, premixed combustion proportion of methanol is increased and diffusion combustion proportion is decreased. As injection timing increases to 126 degree before TDC, diffusion combustion of methanol disappears. At this time, the combustion process shows typical two stages heat release of HCCI combustion. As injection timing increases, required DME rate is increased, combustion efficiency and indicated thermal efficiency all first increase and then decrease.

HCNG is short for hydrogen enriched natural gas. Compared to traditional gasoline, diesel or even natural gas engines HCNG fuelled engines have several advantages on environment protection and energy security and in order to make full extent of the new fuel, several modifications have to be made in the corresponding engine and the control strategy. So there is a need to develop a predictive model to simulate the engine's performance without really running the engine, which could speed up the development of HCNG engines. This paper dose such a job. At first the paper presents the fundamentals of the quasi-dimensional model. The equations of the two-zone thermodynamic model and turbulent entrainment combustion model are both introduced. The methods of calculating the related parameters such as theoretical adiabatic flame temperature, laminar burning velocity of HCNG mixture under various hydrogen blending ratios are also given.

A HCCI engine has been run at different operating boundaries conditions with fuels of different RON and MON and different chemistries. The fuels include gasoline, PRF and the mixture of PRF and ethanol. Six operating boundaries conditions are considered, including different intake temperature (Tin), intake pressure (Pin) and engine speed. The experimental results show that, fuel chemistries have different effect on the combustion process at different operating conditions. It is found that CA50 (crank angle at 50% completion of heat release) shows no correlation with either RON or MON at some operating boundaries conditions, but correlates well with the Octane Index (OI) at all conditions. The higher the OI, the more the resistance to auto-ignition and the later is the heat release in the HCCI engine. The operating range is also correlation with the OI. The higher the OI, the higher IMEP can reach.

Hydrogen enriched compressed natural gas (HCNG) is thought to be a potential alternative to common hydrocarbon fuels for SI engine applications. Experimental researches focusing on how to use this kind of fuel to its full extent have been conducted for over ten years and are still on their way. From a review of these researches it is found that one of the biggest obstacles of efficiently and economically conducting such experiments is how to mix desired amount of hydrogen with natural gas. Most of the previous experiments use pre-bottled hydrogen/ NG mixtures (by mixing and storing desired amount of hydrogen and NG in high pressure steel cylinders before the tests) which are quite costly and unsafe, due to high pressure operation. More importantly, the blending ratio cannot be varied by that approach. By comparison, this paper presents an on-line hydrogen-natural gas mixing system through which the hydrogen/ NG blending ratio can be easily varied during the tests.

The influence of boost pressure (Pin) and fuel chemistry on combustion characteristics and performance of homogeneous charge compression ignition (HCCI) engine was experimentally investigated. The tests were carried out in a modified four-cylinder direct injection diesel engine. Four fuels were used during the experiments: 90-octane, 93-octane and 97-octane primary reference fuel (PRF) blend and a commercial gasoline. The boost pressure conditions were set to give 0.1, 0.15 and 0.2MPa of absolute pressure. The results indicate that, with the increase of boost pressure, the start of combustion (SOC) advances, and the cylinder pressure increases. The effects of PRF octane number on SOC are weakened as the boost pressure increased. But the difference of SOC between gasoline and PRF is enlarged with the increase of boost pressure. The successful HCCI operating range is extended to the upper and lower load as the boost pressure increased.

This paper first compares strengths and weaknesses of different options for performing optical diagnostics on HD diesel sprays. Then, practical experiences are described with the design and operation of a constant volume test cell over a period of more than five years. In this test rig, pre-combustion of a lean gas mixture is used to generate realistic gas mixture conditions prior to fuel injection. Spray growth, vaporization are studied using Schlieren and Mie scattering experiments. The Schlieren set-up is also used for registration of light emitted by the combustion process; this can also provide information on ignition delay and on soot lift-off length. The paper further describes difficulties encountered with image processing and suggests methods on how to deal with them.

Exhaust Gas Recirculation (EGR) is an important parameter for control of diesel engine combustion, especially to achieve ultra low NOx emissions. In this paper, the effects of EGR on engine emissions and engine efficiency have been investigated in a heavy-duty diesel engine while changing combustion control parameters, such as injection pressure, injection timing, boost, compression ratio, oxygenated fuel, etc. The engine was operated at 1400 rpm for a cycle fuel rate of 50mg. The results show that NOx emissions strongly depend on the EGR rate. The effects of conventional combustion parameters, such as injection pressure, injection timing, and boost, on NOx emissions become small as the EGR rate is increased. Soot emissions depend strongly on the ignition delay and EGR rate (oxygen concentration). Soot emissions can be reduced by decreasing the compression ratio, increasing the injection pressure, or burning oxygenated fuel.

A study on the modeling of fuel sprays in diesel engines will be presented. First, modeling of non-reacting diesel spray formation is studied in Fluent and Star-CD. The main objective however is to model combustion of the spray using a generic approach. This is achieved by applying a detailed chemistry tabulation method, called FGM (Flamelet Generated Manifold). Using this approach will make additional ignition modeling, which is conventional, obsolete. The FGM method is implemented in Fluent and Star-CD. Subsequently, constant volume spray combustion and full engine cycle simulations are performed. Spray formation is modeled with Lagrangian type models that are available in Fluent and Star-CD, and also with a 1D Euler-Euler spray model that is implemented and applied in 3D Fluent simulations. The results are compared with EHPC (Eindhoven High Pressure Cell) experiments, data from Sandia National Laboratories and IFP (Institut Français du Pétrole).

The main goal of this paper is to acquire more insight into the relationship between wall and piston impingement of liquid fuel and unburnt hydrocarbon emissions (UHC) emissions, under early direct injection (EDI) premixed charge compression ignition (PCCI) operating conditions. To this end, the vaporization process is modeled for various operating conditions using a commercial CFD code (StarCD). Predicted values for liquid core penetration, or liquid length LL , have been successfully checked against experimental data from literature over a wide range of operating conditions. Next, the correlation between the CFD results for wall and piston impingement and measured UHC emissions is studied. The diesel fuel used in the experiments is modeled as n-dodecane and n-heptadecane, representing the low and high end of the diesel boiling range, respectively. A distinction is made between liquid spray impingement on the piston surface and cylinder liner.

The purpose of this study was to gain a better understanding of the effects of port fuel injection strategies and thermal stratification on the HCCI combustion processes. Experiments were conducted in a single-cylinder HCCI engine modified with windows in the combustion chamber for optical access. Two-dimensional images of the chemiluminescence were captured using an intensified CCD camera in order to understand the spatial distribution of the combustion. N-heptane was used as the test fuel. The experimental data consisting of the in-cylinder pressure, heat release rate, chemiluminescence images all indicate that the different port fuel injection strategies result in different charge distributions in the combustion chamber, and thus affect the auto-ignition timing, chemiluminescence intensity, and combustion processes. Under higher intake temperature conditions, the injection strategies have less effect on the combustion processes due to improved mixing.

A yc6112ZLQ turbocharged 6 cylinder engine with intercooler was converted to operate in dual fuel mode with compressed natural gas (CNG) and pilot diesel. The influence of the CNG ratio, pilot diesel injection advance (ADC) and intake temperature after intercooler on the combustion process, emissions and engine performance was investigated. The results show that the combustion process of dual-fuel engines is faster than diesel engine. Both the ignition timing of the pilot fuel and the excess air ratio of total fuel λ dominate the combustion characteristics of duel-fuel engines. With the increase of CNG ratio, the pressure and temperature in cylinder decrease at rated mode, but increase at torque and low speed modes. With advanced the pilot injection timing or increased the intake temperature, the cylinder pressure and temperature increase.

Studies on combustion process of Dimethyl Ether (DME) were carried out on a constant volume combustion bomb (CVCB) and a visualization engine, and the photograph of combustion of DME was taken by high speed digital CCD. The results show that the ignition delay of DME is shorter than that of diesel fuel. When the fuel delivery amounts of DME and diesel in volume are the same, the combustion duration of DME is shorter than that of diesel fuel, and the flame temperature of DME is lower than that of diesel. At the end of combustion, the second injection occurred. The results of high-speed photograph in visualization engine show that, as soon as DME leaves the nozzle, it evaporates rapidly, and under the effect of air swirl, the spray“core” is blown off. Compared to diesel, the penetration of DME is shorter, and the wall combustion of DME is apparently smaller.