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Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

Conventional crank-based engines are limited by mechanical, thermal, and combustion inefficiencies. The free piston of a linear engine generator reduces frictional losses by avoiding the rotational motion and crankshaft linkages. Instead, electrical power is generated by the oscillation of a translator through a linear stator. Because the free piston is not geometrically constrained, dead center positions are not specifically known. This results in a struggle against adverse events like misfire, stall, over-fueling, or rapid load changes. It is the belief that incorporating springs will have the dual benefit of increasing frequency and providing a restoring force to aid in greater cycle to cycle stability. For dual free piston linear engines the addition of springs has not been fully explored, despite growing interest and literature.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

In 2007, US EPA implemented the rule that the crankcase emissions be added to the tailpipe emissions to determine the total emissions from a diesel engine if the crankcase were not closed, but few data exist to quantify crankcase emissions from earlier model diesel engines. This paper presents the results of a study on the measurement of the size distribution and number concentration of particulate matter (PM) emitted from the crankcase vents from four different diesel engines under different engine speeds and loads. The engines used in the study were a 1992 Detroit Diesel Series 60, a 1996 Caterpillar 3406E, a 1997 Cummins B5.9 and a 1995 Mack E7-400. The Detroit Diesel engine was tested on an engine dynamometer and crankcase and tailpipe particulates were observed at varying engine speeds and loads. The other three engines were mounted in vehicles, and crankcase PM was observed at several engine speeds with no external load.

Heavy-duty diesel engines (HDDE), because of their widespread use and reputation of expelling excessive soot, have frequently been held responsible for excessive amounts of overall environmental particulate matter (PM). PM is a considerable contributor to air pollution, and a subject of primary concern to health and regulatory agencies worldwide. The U.S. Environmental Protection Agency (EPA) has provided PM emissions regulations and standards of measurement techniques since the 1980's. PM standards set forth by the EPA for HDDEs are based only on total mass, instead of size and/or concentration. The European Union adopted a particle number emission limit, and it may influence the U.S. EPA to adopt particle number or size limits in the future. The purpose of this research was to study the effects biodiesel blended fuel and cetane improvers have on particle size and number.

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.

The key to overcoming Low Temperature Combustion (LTC) load range limitations is based on suitable control over the thermo-chemical properties of the in-cylinder charge. The proposed alternative to achieve the required control of LTC is the use of two separate fuel streams to regulate timing and heat release at specific operational points, where the secondary fuel, with different autoignition characteristics, is a reformed product of the primary fuel in the tank. It is proposed in this paper that the secondary fuel is produced using Thermo-Chemical Recuperation (TCR) with steam/fuel reforming. The steam/fuel mixture is heated by sensible heat from the engine exhaust gases in the recuperative reformer, where the original hydrocarbon reacts with water to form a hydrogen rich gas mixture. An equilibrium model developed by Gas Technology Institute (GTI) for n-heptane steam reforming was applied to estimate reformed fuel composition at different reforming temperatures.

The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. This paper summarizes the design of the project and early results from the first two sites. Data collection is planned for operations, maintenance, truck system descriptions, emissions, duty cycle, safety incidents, and capital costs and operating costs associated with the use of alternative fuels in trucking.

As emission regulations become increasingly strict, the need for more accurate sampling systems becomes essential. When calculating emissions from a dilution system, a correction is made to remove the effects of contaminants in the dilution air. The dilution air correction was explored to determine why this correction is needed, when this correction is important, and what methods are available for calculating the dilution factor (DF). An experimental and error analysis investigation into the standard and recently proposed methods for calculating the DF was conducted. Five steady state modes were run on a 1992 Detroit Diesel engine series 60 and the DF from eleven different equations were investigated. The effects of an inaccurate dilution air correction on calculated fuel flow from a carbon balance and the mass emissions was analyzed. The dilution air correction was shown to be important only for hydrocarbons, particulate matter (PM), and CO2.

Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. An overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel.

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.