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Three-way catalyst equipped stoichiometric natural gas vehicles have proven to be an effective alternative fuel strategy that has shown superior low NOx benefits in comparison to diesels equipped with SCR. However, recent studies have shown the TWC activity to contribute to high levels of tailpipe ammonia emissions. Although a non-regulated pollutant, ammonia is a potent pre-cursor to ambient secondary PM formation. Ammonia (NH3) is an inevitable catalytic byproduct of TWCduring that results also corresponds to lowest NOx emissions. The main objective of the study is to develop a passive SCR based NH3 reduction strategy that results in an overall reduction of NH3 as well as NOx emissions from a stoichiometric spark ignited natural gas engine. The study investigated the characteristics of Fe-based and Cu-based zeolite SCR catalysts in storage, and desorption of ammonia at high exhaust temperature conditions, that are typical of stoichiometric natural gas engines.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Selective Catalytic Reduction (SCR), using urea injection, is being examined as a method for substantial reduction of oxides of nitrogen (NOx) for diesel engines, but the urea injection rates must be controlled to match the NOx production which may need to be predicted during open loop control. Unfortunately NOx is usually measured in the laboratory using a full-scale dilution tunnel and chemiluminescent analyzer, which cause delay and diffusion (in time) of the true manifold NOx concentration. Similarly, delay and diffusion of measurements of all emissions cause the task of creating instantaneous emissions models for vehicle simulations more difficult. Data were obtained to relate injections of carbon dioxide (CO2) into a tunnel with analyzer measurements. The analyzer response was found to match a gamma distribution of the input pulse, so that the analyzer output could be modeled from the tunnel CO2 input.

West Virginia University redesigned a 2002 Ford Explorer and created a diesel electric hybrid vehicle to satisfy the goals of the 2002 FutureTruck competition. These goals were to demonstrate a 25% improvement in fuel economy, to reduce greenhouse gas emissions, to achieve California ULEV emissions, to demonstrate 1/8-mile acceleration of 11.5 seconds or less, and to maintain vehicular comforts and performance. West Virginia University's 2002 hybrid sport utility vehicle (SUV), the Exclaim!, meets or exceeds these goals. Using a post-transmission parallel configuration, WVU integrated a 2.5L Detroit Diesel Corporation engine along with a Unique Mobility 75kW electric motor to replace the stock drivetrain. With an emphasis on maintaining performance, WVU strived to improve areas where SUVs have traditionally performed poorly: fuel economy and emissions. Using regenerative braking, fuel economy has been significantly improved.

In order to comply with stringent 2010 US-Environmental Protection Agency (EPA) on-road, Heavy-Duty Diesel (HDD) emissions regulations, the Selective Catalytic Reduction (SCR) aftertreatment system has been judged by a multitude of engine manufacturers as the primary technology for mitigating emissions of oxides of nitrogen (NOx). As virtually stand-alone aftertreatment systems, SCR technology further represents a very flexible and efficient solution for retrofitting legacy diesel engines as the most straightforward means of cost-effective compliance attainment. However, the addition of a reducing agent injection system as well as the inherent operation limitations of the SCR system due to required catalyst bed temperatures introduce new, unique problems, most notably that of ammonia (NH₃) slip.

The study was aimed at assessing in-use emissions of a USEPA 2010 emissions-compliant heavy-duty diesel vehicle powered by a model year (MY) 2011 engine using West Virginia University's Transportable Emissions Measurement System (TEMS). The TEMS houses full-scale CVS dilution tunnel and laboratory-grade emissions measurement systems, which are compliant with the Code of Federal Regulation (CFR), Title 40, Part 1065 [1] emissions measurement specifications. One of the specific objectives of the study, and the key topic of this paper, is the quantification of greenhouse gas (GHG) emissions (CO2, N2O and CH4) along with ammonia (NH3) and regulated emissions during real-world operation of a long-haul heavy-duty vehicle, equipped with a diesel particulate filter (DPF) and urea based selective catalytic reduction (SCR) aftertreatment system for PM and NOx reduction, respectively.

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

West Virginia University characterized the emissions and fuel economy performance of a 30-foot 2010 transit bus equipped with urea selective catalytic reduction (u-SCR) exhaust aftertreatment. The bus was exercised over speed-time driving schedules representative of both urban and on-highway activity using a chassis dynamometer while the exhaust was routed to a full-scale dilution tunnel with research grade emissions analyzers. The Paris speed-time driving schedule was used to represent slow urban transit bus activity while the Cruise driving schedule was used to represent on-highway activity. Vehicle weights representative of both one-half and empty passenger loading were evaluated. Fuel economy observed during testing with the urban driving schedule was significantly lower (55%) than testing performed with the on-highway driving schedule.