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Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Fuel wall impingement commonly occurs in small-bore diesel engines. Particularly during engine starting, when wall temperatures are low, the evaporation rate of fuel film remaining from previous cycles plays a significant role in the autoignition process that is not fully understood. Pre-injection chemiluminescence (PIC), resulting from low-temperature oxidation of evaporating fuel film and residual gases, was measured over 3200 μsec intervals at the end of the compression strokes, but prior to fuel injection during a series of starting sequences in an optical diesel engine. These experiments were conducted to determine the effect of this parameter on combustion phasing and were conducted at initial engine temperatures of 30, 40, 50 and 60°C, at swirl ratios of 2.0 and 4.5 at 1000 RPM. PIC was determined to increase and be highly correlated with combustion phasing during initial cycles of the starting sequence.

Operation of flex fuel vehicles requires operation with a range of fuel properties. The significant differences in the heat of vaporization and energy density of E0-E100 fuels and the effect on spray development need to be fully comprehended when developing engine control strategies. Limited enthalpy for fuel vaporization needs to be accounted for when developing injection strategies for cold start, homogeneous and stratified operation. Spray imaging of multi-hole gasoline injectors with fuels ranging from E0 to E100 and environmental conditions that represent engine operating points from ambient cold start to hot conditions was performed in a spray chamber. Schlieren visualization technique was used to characterize the sprays and the results were compared with Laser Mie scattering and Back-lighting technique. Open chamber experiments were utilized to provide input and validation of a CFD model.

In present GDI engines, multiple injection strategies are often employed for engine cold start mixture formation. In the future, these strategies may also be used to control the combustion process, and to prevent misfiring or high emission levels. While the processes occurring during individual injections of GDI injectors have been investigated by a number of researchers, this paper concentrates on the interactions of multiple injection events. Even though multiple injection strategies are already applied in most GDI engines, the impact of the first injection event on the second injection event has not been analyzed in detail yet. Different optical measurement techniques are used in order to investigate the interaction of the two closely timed injection events, as well as the effect of dwell time and the in-cylinder conditions. The injector investigated is a GDI piezo injector with an outwardly opening needle.

Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

Ion current sensors have been considered for the feedback electronic control of gasoline and diesel engines and for onboard vehicles powered by both engines, while operating on their conventional cycles or on the HCCI mode. The characteristics of the ion current signal depend on the progression of the combustion process and the properties of the combustion products in each engine. There are large differences in the properties of the combustible mixture, ignition process and combustion in both engines, when they operate on their conventional cycles. In SI engines, the charge is homogeneous with an equivalence ratio close to unity, ignition is initiated by an electric spark and combustion is through a flame propagating from the spark plug into the rest of the charge.

In this study the authority of the available engine controls are characterized as the high load limit of homogeneous charge compression ignition (HCCI) combustion is approached. A boosted single-cylinder research engine is used and is equipped with direct injection (DI) fueling, a laboratory air handling system, and a hydraulic valve actuation (HVA) valve train to enable negative valve overlap (NVO) breathing. Results presented include engine loads from 350 to 650 kPa IMEPnet and manifold pressure from 98 to 190 kPaa. It is found that in order to increase engine load to 650 kPa IMEPnet, it is necessary to increase manifold pressure and external EGR while reducing the NVO duration. While both are effective at controlling combustion phasing, NVO duration is found to be a "coarse" control while fuel injection timing is a "fine" control.

In previous work, Gasoline Direct Injection Compression Ignition (GDCI) has demonstrated good potential for high fuel efficiency, low NOx, and low PM over the speed-load range using RON91 gasoline. In the current work, a four-cylinder, 1.8L engine was designed and built based on extensive simulations and single-cylinder engine tests. The engine features a pent roof combustion chamber, central-mounted injector, 15:1 compression ratio, and zero swirl and squish. A new piston was developed and matched with the injection system. The fuel injection, valvetrain, and boost systems were key technology enablers. Engine dynamometer tests were conducted at idle, part-load, and full-load operating conditions. For all operating conditions, the engine was operated with partially premixed compression ignition without mode switching or diffusion controlled combustion.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

A pilot-main injection strategy is investigated for a part-load operating point in a single cylinder optical Diesel engine. As the energizing dwell between the pilot and main injections decreases below 200 μs, combustion noise reaches a minimum and a reduction of 3 dB is possible. This decrease in combustion noise is achieved without increased pollutant emissions. Injection schedules employed in the engine are analyzed with an injection analyzer to provide injection rates for each dwell tested. Two distinct injection events are observed even at the shortest dwell tested; rate shaping of the main injection occurs as the dwell is adjusted. High-speed elastic scattering imaging of liquid fuel is performed in the engine to examine initial liquid penetration rates.

A 1.8L Gasoline Direct Injection Compression Ignition (GDCI) engine was tested over a wide range of engine speeds and loads using RON91 gasoline. The engine was operated with a new partially premixed combustion process without combustion mode switching. Injection parameters were used to control mixture stratification and combustion phasing using a multiple-late injection strategy with GDi-like injection pressures. At idle and low loads, rebreathing of hot exhaust gases provided stable compression ignition with very low engine-out NOx and PM emissions. Rebreathing enabled reduced boost pressure, while increasing exhaust temperatures greatly. Hydrocarbon and carbon monoxide emissions after the oxidation catalyst were very low. Brake specific fuel consumption (BSFC) of 267 g/kWh was measured at the 2000 rpm-2bar BMEP global test point.

Lithium-ion polymer battery has been widely used for vehicle onboard electric energy storage ranging from 12V SLI (Starting, Lighting, and Ignition), 48V mild hybrid electric, to 300V battery electric vehicle. Formulation on cell parameters acquired from minimum numbers of experiments, the modeling and simulation could be an effective approach in predicting battery performance, thermal effectiveness, and degradation. This paper describes the modeling, simulation, and validation of Lithium-Nickel-Manganese-Cobalt-Oxide (LiNiMnCoO2) based cell with 3.6V nominal voltage and 20Ah capacity. Constant current 20A, 40A, 60A, and 80A discharge tests are conducted in the computer-controlled cycler and temperature chamber. Discharging voltage curves and cell surface temperature distributions are recorded in each discharging test. A three-dimensional cell model is constructed in the COMSOL multi-physics platform based on the cell parameters.

Flow field asymmetry can lead to an asymmetric mixture preparation in Diesel engines. To understand the evolution of this asymmetry, it is necessary to characterize the in-cylinder flow over the full compression stroke. Moreover, since bowl-in-piston cylinder geometries can substantially impact the in-cylinder flow, characterization of these flows requires the use of geometrically correct pistons. In this work, the flow has been visualized via a transparent piston top with a realistic bowl geometry, which causes severe experimental difficulties due to the spatial and temporal variation of the optical distortion. An advanced optical distortion correction method is described to allow reliable particle image velocimetry (PIV) measurements through the full compression stroke. Based on the ensemble-averaged velocity results, flow asymmetry characterized by the swirl center offset and the associated tilting of the vortex axis is quantified.

The second generation 1.8L Gasoline Direct Injection Compression Ignition (GDCI) engine was built and tested using RON91 gasoline. The engine is intended to meet stringent US Tier 3 emissions standards with diesel-like fuel efficiency. The engine utilizes a fulltime, partially premixed combustion process without combustion mode switching. The second generation engine features a pentroof combustion chamber, 400 bar central-mounted injector, 15:1 compression ratio, and low swirl and squish. Improvements were made to all engine subsystems including fuel injection, valve train, thermal management, piston and ring pack, lubrication, EGR, boost, and aftertreatment. Low firing friction was a major engine design objective. Preliminary test results indicated good improvement in brake specific fuel consumption (BSFC) over the first generation GDCI engines, while meeting targets for engine out emissions, combustion noise and stability.

EGR is a proven technology used to reduce NOx formation in both compression and spark ignition engines by reducing the combustion temperature. In order to further increase its efficiency the recirculated gases are subjected to cooling. However, this leads to a higher load on the cooling system of the engine, thus requiring a larger radiator. In the case of turbocharged engines the large variations of the pressures, especially in the exhaust manifold, produce a highly pulsating EGR flow leading to non-steady-state heat transfer in the cooler. The current research presents a method of determining the pulsating flow field and the instantaneous heat transfer in the EGR heat exchanger. The processes are simulated using the CFD code FIRE (AVL) and the results are subjected to validation by comparison with the experimental data obtained on a 2.5 liter, four cylinder, common rail and turbocharged diesel engine.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

As a result of recent focus on the control of Low Temperature Combustion (LTC) modes, dual-fuel combustion strategies such as Reactivity Controlled Compression Ignition (RCCI) have been developed. Reactivity stratification of the auto-igniting mixture is thought to be responsible for the increase in allowable engine load compared to other LTC combustion modes such as Homogenous Charge Compression Ignition (HCCI). The current study investigates the effect of ethanol intake fuel injection on in-cylinder formaldehyde formation and stratification within an optically accessible engine operated with n-heptane direct injection using optical measurements and zero-dimensional chemical kinetic models. Images obtained by Planar Laser Induced Fluorescence (PLIF) of formaldehyde using the third harmonic of a pulsed Nd:YAG laser indicate an increase in formaldehyde heterogeneity as measured by the fluorescence signal standard deviation.

While the potential emissions and efficiency benefits of HCCI combustion are well known, realizing the potentials on a production intent engine presents numerous challenges. In this study we focus on identifying challenges and opportunities associated with a production intent cam-based variable valve actuation (VVA) system on a multi-cylinder engine in comparison to a fully flexible, naturally aspirated, hydraulic valve actuation (HVA) system on a single-cylinder engine, with both platforms sharing the same GDI fueling system and engine geometry. The multi-cylinder production intent VVA system uses a 2-step cam technology with wide authority cam phasing, allowing adjustments to be made to the negative valve overlap (NVO) duration but not the valve opening durations. On the single-cylinder HVA engine, the valve opening duration and lift are variable in addition to the NVO duration. The content of this paper is limited to the low-medium operating load region at 2000 rpm.

In light-duty direct-injection (DI) diesel engines, combustion chamber geometry influences the complex interactions between swirl and squish flows, spray-wall interactions, as well as late-cycle mixing. Because of these interactions, piston bowl geometry significantly affects fuel efficiency and emissions behavior. However, due to lack of reliable in-cylinder measurements, the mechanisms responsible for piston-induced changes in engine behavior are not well understood. Non-intrusive, in situ optical measurement techniques are necessary to provide a deeper understanding of the piston geometry effect on in-cylinder processes and to assist in the development of predictive engine simulation models. This study compares two substantially different piston bowls with geometries representative of existing technology: a conventional re-entrant bowl and a stepped-lip bowl. Both pistons are tested in a single-cylinder optical diesel engine under identical boundary conditions.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.