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Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

The potential of boosted HCCI for achieving high loads has been investigated for intake pressures (Piⁿ) from 100 kPa (naturally aspirated) to 325 kPa absolute. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) equipped with a compression-ratio 14 piston at 1200 rpm. The intake charge was fully premixed well upstream of the intake, and the fuel was a research-grade (R+M)/2 = 87-octane gasoline with a composition typical of commercial gasolines. Beginning with Piⁿ = 100 kPa, the intake pressure was systematically increased in steps of 20 - 40 kPa, and for each Piⁿ, the fueling was incrementally increased up to the knock/stability limit, beyond which slight changes in combustion conditions can lead to strong knocking or misfire. A combination of reduced intake temperature and cooled EGR was used to compensate for the pressure-induced enhancement of autoignition and to provide sufficient combustion-phasing retard to control knock.

Advanced internal combustion engines, although generally more efficient than conventional combustion engines, often encounter limitations in multi-cylinder applications due to variations in the combustion process. This study leverages experimental data from an inline 6-cylinder heavy-duty dual fuel engine equipped with a fully-flexible variable intake valve actuation system to study cylinder-to-cylinder variations in power production. The engine is operated with late intake valve closure timings in a dual-fuel combustion mode featuring a port-injection and a direct-injection fueling system in order to improve fuel efficiency and engine performance. Experimental results show increased cylinder-to-cylinder variation in IMEP as IVC timing moves from 570°ATDC to 610°ATDC, indicating an increasingly uneven fuel distribution between cylinders.

This work explores the high-load limits of HCCI for naturally aspirated operation. This is done for three fuels with various autoignition reactivity: iso-octane, PRF80, and PRF60. The experiments were conducted in a single-cylinder HCCI research engine (0.98 liter displacement), mostly with a CR = 14 piston installed, but with some tests at CR = 18. Five load-limiting factors were identified: 1) NOx-induced combustion-phasing run-away, 2) wall-heating-induced run-away, 3) EGR-induced oxygen deprivation, 4) wandering unsteady combustion, and 5) excessive exhaust NOx. These experiments at 1200 rpm show that the actual load-limiting factor is dependent on the autoignition reactivity of the fuel, the selected CA50, and in some cases, the tolerable level of NOx emissions. For iso-octane, which has the highest resistance to autoignition of the fuels tested, the NOx emissions become unacceptable at IMEPg = 473 kPa.

This study investigates the potential of partial fuel stratification for reducing the knocking propensity of intake-boosted HCCI engines operating on conventional gasoline. Although intake boosting can substantially increase the high-load capability of HCCI, these engines would be more production-viable if the knock/stability load limit could be extended to allow higher loads at a given boost and/or to provide even higher thermal efficiencies. A technique termed partial fuel stratification (PFS) has recently been shown to greatly reduce the combustion-induced pressure-rise rate (PRR), and therefore the knocking propensity of naturally aspirated HCCI, when the engine is fueled with a φ-sensitive, two-stage-ignition fuel. The current work explores the potential of applying PFS to boosted HCCI operation using conventional gasoline, which does not typically show two-stage ignition. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) at 1200 rpm.

A tracer-based single-line PLIF imaging technique using a unique optical configuration that allows simultaneously viewing the bulk-gas and the boundary layer region has been applied to an investigation of the naturally occurring thermal stratification in a HCCI engine. Thermal stratification is critical for HCCI engines, because it determines the maximum pressure rise rate which is a limiting factor for high-load operation. The investigation is based on the analysis of temperature maps that were derived from PLIF images, using the temperature sensitivity of fluorescence from toluene introduced as tracer in the fuel. Measurements were made in a single-cylinder optically accessible HCCI engine operating under motored conditions with a vertical laser-sheet orientation that allows observation of the development of thermal stratification from the cold boundary layers into the central region of the charge.

Laser-induced incandescence (LII) has been explored as a diagnostic for qualitative two-dimensional imaging of the in-cylinder soot distribution in a diesel engine. Advantages of LII over elastic-scatter soot imaging techniques include no interfering signals from liquid fuel droplets, easy rejection of laser light scattered by in-cylinder surfaces, and the signal intensity being proportional to the soot volume fraction. LII images were obtained in a 2.3-liter, single cylinder, direct-injection diesel engine, modified for optical access. To minimize laser sheet and signal attenuation (which can affect almost any planar imaging technique applied to diesel engine combustion), a low-sooting fuel was used whose vaporization and combustion characteristics are typical of standard diesel fuels. Temporal and spatial sequences of LII images were made which show the extent of the soot distribution within the optically accessible portion the combusting spray plume.

Homogenous Charge Compression Ignition (HCCI) engines offer a good potential for achieving high fuel efficiency while virtually eliminating NOx and soot emissions from the exhaust. However, realizing the full fuel economy potential at the vehicle level depends on the size of the HCCI operating range. The usable HCCI range is determined by the knock limit on the upper end and the misfire limit at the lower end. Previously proven high sensitivity of the HCCI process to thermal conditions leads to a hypothesis that combustion chamber deposits (CCD) could directly affect HCCI combustion, and that insight about this effect can be helpful in expanding the low-load limit. A combustion chamber conditioning process was carried out in a single-cylinder gasoline-fueled engine with exhaust re-breathing to study CCD formation rates and their effect on combustion. Burn rates accelerated significantly over the forty hours of running under typical HCCI operating conditions.

Ethanol and ethanol/gasoline blends are being widely considered as alternative fuels for light-duty automotive applications. At the same time, HCCI combustion has the potential to provide high efficiency and ultra-low exhaust emissions. However, the application of HCCI is typically limited to low and moderate loads because of unacceptably high heat-release rates (HRR) at higher fueling rates. This work investigates the potential of lowering the HCCI HRR at high loads by using partial fuel stratification to increase the in-cylinder thermal stratification. This strategy is based on ethanol's high heat of vaporization combined with its true single-stage ignition characteristics. Using partial fuel stratification, the strong fuel-vaporization cooling produces thermal stratification due to variations in the amount of fuel vaporization in different parts of the combustion chamber.

Fuel stratification has been investigated as a means of improving the low-load combustion efficiency in an HCCI engine. Several stratification techniques were examined: different GDI injectors, increased swirl, and changes in injection pressure, to determine which parameters are effective for improving the combustion efficiency while maintaining NOx emissions below U.S. 2010 limits. Performance and emission measurements were obtained in an all-metal engine. Corresponding fuel distribution measurements were made with fuel PLIF imaging in a matching optically accessible engine. The fuel used was iso-octane, which is a good surrogate for gasoline. For an idle fueling rate (ϕ = 0.12), combustion efficiency was improved substantially, from 64% to 89% at the NOx limit, using delayed fuel injection with a hollow-cone injector at an injection pressure of 120 bar.

Multi-zone CFD simulations with detailed kinetics were used to model iso-octane HCCI experiments performed on a single-cylinder research engine. The modeling goals were to validate the method (multi-zone combustion modeling) and the reaction mechanism (LLNL 857 species iso-octane) by comparing model results to detailed exhaust speciation data, which was obtained with gas chromatography. The model is compared to experiments run at 1200 RPM and 1.35 bar boost pressure over an equivalence ratio range from 0.08 to 0.28. Fuel was introduced far upstream to ensure fuel and air homogeneity prior to entering the 13.8:1 compression ratio, shallow-bowl combustion chamber of this 4-stroke engine. The CFD grid incorporated a very detailed representation of the crevices, including the top-land ring crevice and head-gasket crevice. The ring crevice is resolved all the way into the ring pocket volume. The detailed grid was required to capture regions where emission species are formed and retained.

Extending the operating range of the gasoline HCCI engine is essential for achieving desired fuel economy improvements at the vehicle level, and it requires deep understanding of the thermal conditions in the cylinder. Combustion chamber deposits (CCD) have been previously shown to have direct impact on near-wall phenomena and burn rates in the HCCI engine. Hence, the objectives of this work are to characterize thermal properties of deposits in a gasoline HCCI engine and provide foundation for understanding the nature of their impact on autoignition and combustion. The investigation was performed using a single-cylinder engine with re-induction of exhaust instrumented with fast-response thermocouples on the piston top and the cylinder head surface. The measured instantaneous temperature profiles changed as the deposits grew on top of the hot-junctions.

The combustion process in diesel engines deposits soot on the in-cylinder surfaces. Previous works have suggested that these soot deposits eventually break off during cylinder blow-down and the exhaust stroke and contribute significantly to exhaust soot emissions. In order to better understand this potential pathway to soot emissions, the authors recently investigated combusting fuel-jet/wall interactions in a diesel engine. This work, published as a companion paper, showed how soot escaped from the combusting fuel jet and was brought in close proximity to the wall so that it could become a deposit. The current study extends this earlier work with laser-extinction measurements of the soot-deposition rate in the same single-cylinder, heavy-duty DI diesel engine. Measurements were made by passing the beam of a CW-diode laser through a window in the piston bowl rim that was in-line with one of the fuel jets.

Over the past decade, laser diagnostics have improved our understanding of many aspects of diesel combustion. However, interactions between the combusting fuel jet and the piston-bowl wall are not well understood. In heavy-duty diesel engines, with typical fuels, these interactions occur with the combusting vapor-phase region of the jet, which consists of a central region containing soot and other products of rich-premixed combustion, surrounded by a diffusion flame. Since previous work has shown that the OH radical is a good marker of the diffusion flame, planar laser-induced fluorescence (PLIF) imaging of OH was applied to an investigation of the diffusion flame during wall interaction. In addition, simultaneous OH PLIF and planar laser-induced incandescence (PLII) soot imaging was applied to investigate the likelihood for soot deposition on the bowl wall.

Two fundamental aspects of HCCI engine combustion have been investigated using a single-zone model with time-varying compression and the full chemical-kinetic mechanisms for iso-octane, a representative liquid-phase fuel. This approach allows effects of the kinetics and thermodynamics to be isolated and evaluated in a well-characterized manner, providing an understanding of the selected fundamental processes. The computations were made using the CHEMKIN-III kinetic-rate code for an 1800 rpm operating condition. The study consists of two parts. First, low-load HCCI operation was investigated to determine the role of bulk-gas reactions as a source for HC and CO emissions. The computations show that as fueling is reduced to equivalence ratios of 0.15 and lower (very light load and idle), the bulk-gas reactions do not go to completion, leading to inefficient combustion and high emissions of HC and CO.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

To better understand the factors affecting soot formation in diesel engines, in-cylinder soot and diffusion flame lift-off were measured in a heavy-duty, direct-injection diesel engine. Measurements were obtained at two operating conditions using two commercial diesel fuels and a range of oxygenated paraffinic fuel blends. A line-of-sight laser extinction diagnostic was improved and employed to measure the relative soot concentration within the jet (“jet-soot”) and the rates of soot-wall deposition on the piston bowl-rim. An OH chemiluminescence imaging technique was developed to determine the location of the diffusion flame and to measure the lift-off lengths of the diffusion flame to estimate the amount of oxygen entrainment in the diesel jets. Both the jet-soot and the rate of soot-wall deposition were found to decrease with increasing fuel oxygen-to-carbon ratio (O/C) over a wide range of O/C.

This study examines the dynamics and control of an engine operated with late intake valve closure (LIVC) timings in a dual-fuel combustion mode. The engine features a fuel delivery system in which diesel is direct-injected and natural gas is port-injected. Despite the benefits of LIVC and dual-fuel strategy, combining these two techniques resulted in efficiency losses due to the variability of the combustion process across cylinders. The difference in power production across cylinders ranges from 9% at an IVC of 570°ATDC* to 38% at an IVC of 620 °ATDC and indicates an increasingly uneven fuel distribution as the intake valve remains open longer in the compression stroke. This paper describes an approach for controlling the amount of fuel injected into each cylinders’ port of an inline six- cylinder heavy-duty dual-fuel engine to minimize the variations in fuel distribution across cylinder.

Chemiluminescence imaging has been applied to investigate the naturally occurring charge stratification in an HCCI engine. This stratification slows the pressure-rise rate (PRR) during combustion, making it critical to the high-load operating limit of these engines. Experiments were conducted in a single-cylinder HCCI engine modified with windows in the combustion chamber for optical access. Using this engine, chemiluminescence images were obtained from three different view angles. These included both single-shot images with intensified CCD cameras and high-speed (20kHz) sequences with an intensified CMOS video camera. The engine was fueled with iso-octane, which has been shown to be a reasonable surrogate for gasoline and exhibits only single-stage ignition at these naturally aspirated conditions. The chemiluminescence images show that the HCCI combustion is not homogeneous but has a strong turbulent structure even when the fuel and air are fully premixed prior to intake.

A flamelet model is used to calculate combustion in a diesel engine, and the results are compared to experimental data available from an optically accessible, direct-injection diesel research engine. The 3∼D time-dependent Kiva-II code is used for the calculations, the standard Arrhenius combustion model being replaced by an ignition model and the coherent flame model for turbulent combustion. The ignition model is a four-step mechanism developed for heavy hydrocarbons which has been previously used for diesel combustion. The turbulent combustion model is a flamelet model developed from the basic ideas of Marble and Broadwell. This model considers local regions of the turbulent flame front as interfaces called flamelets which separate fuel and oxidizer in the case of a diffusion flame. These flamelets are accounted for by solving a transport equation for the flame surface density, i.e., the flame area per unit volume.