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In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.

Accurate measurements of combustion gas temperature and the coefficient of heat transfer between the gas and the combustion chamber wall of internal combustion engine in cyclic operations are difficult at present. Hence the only method available for determination of states of thermal load and heat loss to the combustion chamber wall in a cycle is to measure the instantaneous temperature on the combustion chamber wall surface accurately and precisely using proper thin-film thermocouples, then to calculate the instantanenous heat flux flowing into the wall surface by means of numerical analysis. However, it is necessary to pay adequate attention to the effects of thermophysical properties of the thermocouple materials on the measured values, since any thermocouple consists of several kinds of materials which are different from those of portions to be measured.

There have been strong demands recently for reductions in the fuel consumption and exhaust emissions of diesel engines from the standpoints of conserving energy and curbing global warming. A great deal of research is being done on new emission control technologies using direct-injection (DI) diesel engines that provide high thermal efficiency. This work includes dramatic improvements in the combustion process. The authors have developed a new combustion concept called Modulated Kinetics (MK), which reduces smoke and NOx levels simultaneously by reconciling low-temperature combustion with pre-mixed combustion [1, 2]. At present, research is under way on the second generation of MK combustion with the aim of improving emission performance further and achieving higher thermal efficiency [3]. Reducing heat rejection in the combustion chamber is effective in improving the thermal efficiency of DI diesel engines as well as that of MK combustion.