Search Results

The solution mapping method Adaptive Polynomial Tabulation (APT) for complex chemistry is presented. The method has the potential of reducing the computational time required for stochastic reactor model simulations of the HCCI combustion process. In this method the solution of the initial value chemical rate equation system is approximated in real-time with zero, first and second order polynomial expressions. These polynomials are algebraic functions of a progress variable, pressure and total enthalpy. The chemical composition space is divided a priori into block-shaped regions (hypercubes) of the same size. Each hypercube may be divided in real-time into adaptive hypercubes of different sizes. During computations, initial conditions are stored in the adaptive hypercubes. Two concentric Ellipsoids of Accuracy (EOA) are drawn around each stored initial condition.

SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

This paper reports an one–dimensional modeling procedure of the hot spot autoignition with a detailed chemistry and multi–species transport in the end gas in an SI engine. The governing equations for continuity of mass, momentum, energy and species for an one–dimensional, unsteady, compressible, laminar, reacting flow and thermal fields are discretized and solved by a fully implicit method. A chemical kinetic mechanism is used for the primary reference fuels n–heptane and iso–octane. This mechanism contains 510 chemical reactions and 75 species. The change of the cylinder pressure is calculated from both flame propagation and piston movement. The turbulent velocity of the propagating flame is modeled by the Wiebe function. Adiabatic conditions, calculated by minimizing Gibb's free energy at each time step, are assumed behind the flame front in the burned gas.

Water injection can be applied to spark ignited gasoline engines to increase the Knock Limit Spark Advance and improve the thermal efficiency. The Knock Limit Spark Advance potential of 6 °CA to 11 °CA is shown by many research groups for EN228 gasoline fuel using experimental and simulation methods. The influence of water is multi-layered since it reduces the in-cylinder temperature by vaporization and higher heat capacity of the fresh gas, it changes the chemical equilibrium in the end gas and increases the ignition delay and decreases the laminar flame speed. The aim of this work is to extend the analysis of water addition to different octane ratings. The simulation method used for the analysis consists of a detailed reaction scheme for gasoline fuels, the Quasi-Dimensional Stochastic Reactor Model and the Detonation Diagram. The detailed reaction scheme is used to create the dual fuel laminar flame speed and combustion chemistry look-up tables.