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EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

Compact heat exchangers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases, resulting in decreased NOx emissions. These exhaust gas recirculation (EGR) coolers experience fouling through deposition of particulate matter (PM) and hydrocarbons (HCs) that reduces the effectiveness of the cooler. Surrogate tubes have been used to investigate the impacts of gas flow rate and coolant temperature on the deposition of PM and HCs. The results indicate that mass deposition is lowest at high flow rates and high coolant temperatures. An oxidation catalyst was investigated and proved to effectively reduce deposition of HCs, but did not reduce overall mass deposition to near-zero levels. Speciation of the deposit HCs showed that a range of HCs from C15 - C25 were deposited and retained in the surrogate tubes.

The buildup of deposits in EGR coolers causes significant degradation in heat transfer performance, often on the order of 20-30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operating conditions. It is unlikely that EGR cooler deposits can be prevented from forming when soot and HC are present. The presence of cooled surfaces will cause thermophoretic soot deposition and condensation of HC and acids. While this can be affected by engine calibration, it probably cannot be eliminated as long as cooled EGR is required for emission control. It is generally felt that “dry fluffy” soot is less likely to cause major fouling than “heavy wet” soot. An oxidation catalyst in the EGR line can remove HC and has been shown to reduce fouling in some applications. The combination of an oxidation catalyst and a wall-flow filter largely eliminates fouling. Various EGR cooler designs affect details of deposit formation.

The first stage of ignition in saturated hydrocarbon fuels is characterized as low temperature heat release (LTHR) or cool flame combustion. LTHR takes place as a series of isomerization reactions at temperatures from 600K to 900K, and is often detectable in HCCI, rapid compression machines, and early injection low temperature combustion (LTC). The experimental investigation presented attempts to determine the behavior of LTHR in late injection low temperature combustion in a medium duty diesel as fuel varies and the influence of such behavior on LTC torque and emissions.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

Biodiesel remains an alternative fuel of interest for use in diesel engines. A common characteristic of biodiesel, relative to petroleum diesel, is a lowered heating value (or energy content of the fuel). A lower heating value of the fuel would, presuming all other parameters are equal, result in decreased engine torque. Since engine torque is often user-demanded, the lower heating value of the fuel generally translates into increased brake specific fuel consumption. Several literature report this characteristic of biodiesel. In spite of the wealth of fuel consumption characteristic data available for biodiesel, it is not clear how other engine performance parameters may change with the use of biodiesel. Characterizing these parameters becomes complicated when considering the interactions of the various engine systems, such as a variable geometry turbocharger with exhaust gas recirculation.

Premixed diesel combustion is intended to supplant conventional combustion in the light to mid load range. This paper demonstrates the operating load limits, limiting criteria, and load-based emissions behavior of a direct-injection, diesel-fueled, premixed combustion mode across a range of test fuels. Testing was conducted on a modern single-cylinder engine fueled with a range of ultra-low sulfur fuels with cetane number ranging from 42 to 53. Operating limits were defined on the basis of emissions, noise, and combustion stability. The emissions behavior and operating limits of the tested premixed combustion mode are independent of fuel cetane number. Combustion stability, along with CO and HC emissions levels, dictate the light load limit. The high load limit is solely dictated by equivalence ratio: high PM, CO, and HC emissions result as overall equivalence ratio approaches stoichiometric.

When automobile hydrocarbons are exhausted into the atmosphere in the presence of NOx and sunlight, ground-level ozone is formed. While researchers have used Maximum Incremental Reactivity (MIR) factors to estimate ozone production, this procedure often overestimates Local Ozone Production (LOP) because it does not consider local atmospheric conditions. In this paper, an enhanced MIR methodology for estimating actual LOP attributable to a vehicle in a particular ozone problem area is presented. In addition to using tabulated MIR factors, the procedure also uses local hydrocarbon reaction terms and a relative mechanistic reactivity term that account for local atmospheric conditions. Through this approach, the effects of hydrocarbon reaction rates, hydrocarbon residence times, and prevailing HC/NOx ratio are accounted for. The procedure is intended to enable automotive engineers to more realistically estimate actual local ozone production resulting from hydrocarbon emissions.

This report describes work recently performed by AVL and DaimlerChrysler, including both simulations and single-cylinder research engine development, to quantify the effects of fuel humidity on the performance of an internal combustion engine fueled by hydrogen. The combustion process was simulated from both a thermodynamic and a chemical kinetics standpoint. Both simulations suggested that substantial NOx reductions could be achieved. An engine was then operated on a laboratory fuel system designed to provide hydrogen at various levels of humidity, and the sensitivity of its performance (emissions and efficiency) to humidity and excess air ratio was determined. These tests verified that NOx emissions were reduced by fuel humidity. Finally, the engine and simulation results were compared. Although correlation was not perfect, the trends proved to be correct.

Advanced engine combustion strategies, such as HCCI and SACI, allow engines to achieve high levels of thermal efficiency with low levels of engine-out NOx emissions. To maximize gains in fuel efficiency, HCCI combustion is often run at lean operating conditions. However, lean engine operation prevents the conventional TWC after-treatment system from reaching legislated tailpipe emissions due to oxygen saturation. One potential solution for handling this challenge without the addition of costly NOx traps or on-board systems for urea injection is the passive TWC-SCR concept. This concept includes the integration of an SCR catalyst downstream of a TWC and the use of periods of rich or stoichiometric operation to generate NH3 over the TWC to be stored on the SCR catalyst until it is needed for NOx reduction during subsequent lean operation.

Using exhaust gas recirculation (EGR) as a diluent instead of air allows the use of a conventional three-way catalyst for effective emissions reduction. Cooled EGR can also reduce fuel consumption and NOx emissions, but too much cool EGR leads to combustion instability and misfire. Negative valve overlap (NVO) is explored in the current work as an alternative method of dilution in which early exhaust valve closing causes combustion products to be retained in the cylinder and recompressed near top dead center, before being mixed with fresh charge during the intake stroke. The potential for fuel injection during NVO to extend the dilution limit of spark ignition combustion is evaluated in this work using experiments conducted on a 4-cylinder 2.0 L gasoline direct injection engine with variable intake and exhaust valve timing. The results demonstrate fuel injection during NVO can extend the dilution limit, improve brake specific fuel consumption (BSFC), and reduce CO and NOx emissions.

Conventional spark plugs ignite a fuel-air mixture via an electric-to-plasma energy transfer; the effectiveness of which can be described by an electric-to-plasma energy efficiency. Although conventional spark plug electric-to-plasma efficiencies have historically been viewed as adequate, it might be wondered how an increase in such an efficiency might translate (if at all) to improvements in the flame initiation period and eventual engine performance of a spark-ignition engine. A modification can be made to the spark plug that places a peaking capacitor in the path of the electrical current; upon coil energizing, the stored energy in the peaking capacitor substantially increases the energy delivered by the spark. A previous study has observed an improvement in the electric-to-plasma energy efficiency to around 50%, whereas the same study observed conventional spark plug electric-to-plasma energy efficiency to remain around 1%.

In the wake of global focus shifting towards the health and conservation of the planet, greater importance is placed upon the hazardous emissions of our fossil fuels, as well as their finite supply. These two areas remain intense topics of research in order to reduce greenhouse gas emissions and increase the fuel efficiency of vehicles, a sector which is a major contributor to society's global CO₂ emissions and consumer of fossil-fuel resources. A particular solution to this problem is the diesel engine, with its inherently fuel-lean combustion, which gives rise to low CO₂ production and higher efficiencies than other potential powertrain solutions. Diesel engines, however, typically exhibit higher nitrogen oxides (NOx) and soot engine-out emissions than their gasoline counterparts. NOx is an ingredient to ground-level ozone production and smoke is a possible carcinogen, both of which are facing stricter emissions regulations.

Internal combustion engines have dealt with increasingly restricted emissions requirements. After-treatment devices are successful bringing emissions into compliance, but in-cylinder combustion control can reduce their burden by reducing engine-out emissions. For example, oxides of nitrogen (NOx) are diesel combustion exhaust species of notoriety for their difficulty in after-treatment removal. In-cylinder conditions can be controlled for low levels of NOx, but this produces high levels of soot particulate matter (PM). The simultaneous reduction of NOx and PM can be realized through a combustion process known as low temperature combustion (LTC). This paper presents an investigation into the manifestation of LTC in the calculated heat release profile. Such a study could be important since some extreme LTC conditions may exhibit a return to the soot-NOx tradeoff, rendering an emissions-based definition of LTC unhelpful.

Finding a replacement for fossil fuels is critical for the future of automotive transportation. The compression ignition (CI) engine is an important aspect of everyday life by means of transportation and shipping of materials. Biodiesel is a viable augmentation for conventional diesel fuel in compression ignition engines. Biodiesel-fuelled diesel engines produce less particulate matter (PM) relative to conventional diesel and biodiesel has the ability to be a carbon dioxide (CO₂) neutral fuel, which may come under government regulation as a greenhouse gas. Although biodiesel is a viable diesel replacement and has certain emissions benefits, it typically also has a known characteristic of higher oxides of nitrogen (NOx) emissions relative to petroleum diesel. Advanced modes of combustion such as low temperature combustion (LTC) have attained much attention due to ever-increasing emission standards, and could also help reduce NOx in biodiesel.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Present-day implementations of premixed compression ignition low temperature (PCI) combustion in diesel engines use higher levels of exhaust gas recirculation (EGR) than conventional diesel combustion. Two common devices that can be used to achieve high levels of EGR are an intake throttle and a variable geometry turbocharger (VGT). Because the two techniques affect the engine air system in different ways, local combustion conditions differ between the two in spite of, in some cases, having similar burn patterns in the form of heat release. The following study has developed from this and other observations; observations which necessitate a deeper understanding of emissions formation within the PCI combustion regime. This paper explains, through the use of fundamental phenomenological observations, differences in ignition delay and emission indices of particulate matter (EI-PM) and nitric oxides (EI-NOx) from PCI combustion attained via the two different techniques to flow EGR.

Despite remarkable progress made over the past 30 years, automobiles continue to be a major source of hydrocarbon emissions. The objective of this study is to evaluate whether variable exhaust valve opening (EVO) and exhaust valve closing (EVC) can be used to reduce hydrocarbon emissions. An automotive gasoline engine was tested with different EVO and EVC timings under steady-state and start-up conditions. The first strategy that was evaluated uses early EVO with standard EVC. Although exhaust gas temperature is increased and catalyst light-off time is reduced, the rapid drop in cylinder temperature increases cylinder-out hydrocarbons to such a degree that a net increase in hydrocarbon emissions results. The second strategy that was evaluated uses early EVO with early EVC. Early EVO reduces catalyst light-off time by increasing exhaust gas temperature and early EVC keeps the hydrocarbon-rich exhaust gas from the piston crevice from leaving the cylinder.