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In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.

In the last years, even more attention was paid to the alternative fuels which can allow both reducing the fuel consumption and the pollutant emissions. Among gaseous fuels, methane is considered one of the most interesting in terms of engine application. It represents an immediate advantage over other hydrocarbon fuels leading to lower CO₂ emissions; if compared to gasoline, CH₄ has wider flammable limits and better anti-knock properties, but lower flame speed. The addition of H₂ to CH₄ can improve the already good qualities of methane and compensate its weak points. In this paper a comparison was carried out between CH₄ and different CH₄/H₂ mixtures. The measurements were carried out in an optically accessible small single-cylinder, Port Fuel Injection spark ignition (PFI SI), four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc motorcycle engine representative of the most popular two-wheel vehicles in Europe.

Data decomposition techniques have become a standard approach for the analysis of 2D imaging data originating from optically accessible internal combustion engines. In particular, the method of Proper Orthogonal Decomposition (POD) has proven to be a valuable tool for the evaluation of cycle-to-cycle variability based on luminous combustion imaging and particle image velocimetry (PIV) measurements. POD basically permits to characterize the dominant structures of the process under consideration. Recently, an alternative procedure based on Independent Component Analysis (ICA) has been introduced in the engine field. Unlike POD, the method of ICA identifies the patterns corresponding to physical processes that are statistically independent. In this work, a Group-ICA approach is applied to 2D cycle-resolved images of the luminosity emitted by the combustion process. The analysis is meant to characterize cyclic variability of a port fuel injection spark ignition (PFI SI) engine.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

In this paper, a Low Temperature Premixed Combustion (LTPC) was investigated employing a four cylinder D.I. common rail Diesel engine, used for passenger cars on the European market. Experiments were carried out setting the engine speed at 2500 rpm with a fuel amount of 26 mg/str to realize an operating condition close to the point of NEDC at 0.8 MPa of BMEP. The experimental approach was the management of the start of injection, injection pressure and EGR rates as a method to control NOx and soot production. The investigation was first carried out testing engine performances and emissions as set from the commercial engine map. Afterward, engine tests were carried out exploring performances, gaseous and smoke emissions at late start of combustion [10 to 17.5 cad ATDC], injection pressures from 80 to 120 MPa and EGR rates up to 50%.

A PC-programmable electronic control unit (PECU), able to manage both conventional and future electronic injection systems to make a fixed number of consecutive injections (1 to 5 or more) controlling the injection pressure and the injection pulses duration as well as the separation time or dwell in between was used to study the behaviour of a Bosch common rail injection system both on dynamic spray bench and on engine test bench. The PECU allowed a reduction in the dwell time between consecutive injection pulses from the current value of 1800 μs to 500 μs. Photographic sequences of a five holes mini-sac nozzle making five consecutive injections at 400 - 800 and 1200 bar respectively were taken at ambient pressure and temperature. They showed that both spray penetration and cone angle at all operative conditions are very uniform and stable.

Spectroscopic measurement and high speed visualization were used in single cylinder, four-stroke DI diesel engine, optically accessible. It was equipped with a four valves head and fully flexible electronic controlled ‘Common Rail’ injection system. The effect of pilot and main injection on combustion process was evaluated. Mixing formation, autoignition and soot formation process were analyzed by broadband ultraviolet-visible flame emission spectroscopy and high-speed digital imaging. The autoignition phase occurred near the tip of the jet and was characterized by strong presence of OH radicals for both investigated conditions The presence of C2 and OH radicals strongly characterized CR diesel combustion process during soot formation and evolution. In particular, high presence of OH concentration for the whole process from the autoignition to the soot formation and successive phases contributes to lower soot levels.

In-cylinder combustion phenomena, performance and emissions of a new single cylinder (225 cm3) naturally aspirated DI Diesel engine, with an advanced low cost common rail system for multiple injections, were investigated. The main objective of the present work was the study of the combustion system in terms of combustion chamber geometry, spray angle and number, injection pressure as well as injections number per engine cycle to find the best compromise between smoke and NOx emissions. CFD simulations were made to optimise the combustion chamber shape and the spray angle of a 6 holes nozzle to control the in-cylinder soot formation. The common rail (CR) system consisted of an in-house modified low cost PF Bosch injection unit for pumping the fuel up to 60MPa, a high pressure accumulator (rail) equipped with a pressure regulator valve and sensor as well as improved fast electronic drivers to drive both the pressure regulator valve and a commercial solenoid injector.

This paper aims to correlate the in-cylinder soot formation and the exhaust particle emissions for different methods of gasoline/ethanol fueling in spark ignition engine. In particular, the engine was fueled with gasoline and ethanol separately and not, in this latter case both blended (E30) and dual fueled (EDF). For E30 the bend was direct injected and for EDF, the ethanol was injected in the combustion chamber and the gasoline into the intake duct. For both the injection configurations, the same percentage of ethanol in gasoline was supplied: 30%v/v. The measurements were carried out at 2000 and 4000 rpm, under full load, and stoichiometric condition, in small single cylinder optical engine. 2D-digital imaging was performed to follow the combustion process with a high spatial and temporal resolution through a full-bore optical piston. The two-color pyrometry was applied for the analysis of the in cylinder soot formation in the combustion chamber.

Internal combustion engines performance greatly depends on the air-fuel mixture formation and combustion processes. In gasoline direct injection (GDI) engines, in particular, the impact of the liquid spray on the piston or cylinder walls is a key factor, especially if mixture formation occurs under the so-called wall-guided mode. Impact causes droplets rebound and/or deposition of a liquid film (wallfilm). After being rebounded, droplets undergo what is called secondary atomization. The wallfilm may remain of no negligible size, so that fuel vapor rich zones form around it leading to so-called pool-flames (flames placed in the piston pit), hence to unburned hydrocarbons (HC) and particulate matter (PM) formation. A basic study of the spray-wall interaction is here performed by directing a multi-hole GDI spray against a real shape engine piston, possibly heated, under standard air conditions.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.

In this paper, the effect of the oxygen addition on engine performance and exhaust emissions was investigated. The experimental study was carried out in a small single-cylinder PFI SI four-stroke engine. The addition of the 5% vol and 10% vol of oxygen was performed in the intake duct. Typical urban driving operating conditions were investigated. The engine emissions were characterized by means of gaseous analyzers and a smokemeter. Particle size distribution function was measured in the size range from 5.6 to 560 nm by means of an Engine Exhaust Particle Sizer (EEPS). An improvement in terms of engine power output, without BSFC penalty, and HC emissions with oxygen addition was observed at all the investigated operating conditions. On the other hand, NOx and PM emissions increase.

This paper deals with the combustion behavior and exhaust emissions of a small compression ignition engine modified to operate in diesel/methane dual fuel mode. The engine is a three-cylinder, 1028 cm3 of displacement, equipped with a common rail injection system. The engine is provided with the production diesel oxidation catalyst. Intake manifold was modified in order to set up a gas injector managed by an external control unit. Experiments were carried out at different engine speeds and loads. For each engine operating condition, the majority of the total load was supplied by methane while a small percentage of the load was realized using diesel fuel; the latter was necessary to ignite the premixed charge of gaseous fuel. Thermodynamical analysis of the combustion phase was performed by in-cylinder pressure signal. Gas emissions and particulate matter were measured at the exhaust by commercial instruments.

The use of oxygenated and renewable fuels is nowadays a widespread means to reduce regulated pollutant emissions produced by internal combustion engines, as well as to reduce the greenhouse impact of transportation. Besides PM, NOx and HC emissions, also the size distribution of particles emitted at the engine exhaust represent meaningful information, considering its adverse effects on the environment and human health. In this work, the results of a comprehensive investigation on the combustion characteristics and the exhaust emissions of a GDI high performance engine, fuelled with pure bio-ethanol and European gasoline, are shown. The engine is a 4-cylinder, 4-stroke, 1750 cm₃ displacement, and turbocharged. The engine was operated at different speed/load conditions and two fuel injection strategies were investigated: homogeneous charge mode and stratified charge mode.

Fuel depletion as well as the growing concerns on environmental issues prompt to the use of more eco-friendly fuels. The compressed natural gas (CNG) is considered one of the most promising alternative fuel for engine applications because of the lower emissions. Nevertheless, recent studies highlighted the presence of ultrafine particle emissions at the exhaust of CNG engines. The present study aims to investigate the effect of CNG on particle formation and emissions when it was direct injected and when it was dual fueled with gasoline. In this latter case, the CNG was direct injected and the gasoline port fuel injected. The study was carried out on a transparent single cylinder SI engine in order to investigate the in-cylinder process by real time non-intrusive diagnostics. In-cylinder 2D chemiluminescence measurements from UV to visible were carried out.

This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.

In the urban area the internal combustion engines are the main source of CO₂, NO and particulate matter (PM) emissions. The reduction of these emissions is no more an option, but a necessity highlighted by the even stricter emission standards. In the last years, even more attention was paid to the alternative fuels. They allow both reducing the fuel consumption and the pollutant emissions. With regards to the gaseous fuels, methane is considered one of the most interesting in terms of engine application. It represents an immediate advantage over other hydrocarbon fuels because of the lower C/H ratio. In this paper the effect of the methane on the combustion process, the pollutant emissions and the engine performance was analyzed. The measurements were carried out in an optically accessible single-cylinder, Port Fuel Injection, four-stroke SI engine equipped with the cylinder head of a commercial 250 cc motorcycles engine and fuelled both with gasoline and methane.