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Emissions of nitrogen oxides (NOx) from heavy-duty diesel engines are subject to more stringent environmental legislation. Selective catalytic reduction (SCR) over metal ion-exchanged zeolites is in this connection an efficient method to reduce NOx. Understanding durability of the SCR catalyst is crucial for correct design of the aftertreatment system. In the present paper, thermal and chemical ageing of Fe-BEA as NH3-SCR catalyst is studied. Experimental results of hydrothermal ageing, and chemical ageing due to phosphorous and potassium exposure are presented. The catalyst is characterized by flow reactor experiments, nitrogen physisorption, DRIFTS, XRD, and XPS. Based on the experimental results, a multisite kinetic model is developed to describe the activity of the fresh Fe-BEA catalyst.

The emissions from a direct injection diesel engine measured according to the ECE R49 13-mode cycle and as a function of exhaust gas recirculation are compared for diesel fuel without water addition, and for water-in-diesel as emulsion and microemulsion. The effect of water addition on the soot emissions was remarkably strong for both the emulsion and microemulsion fuels. The average weighted soot emission values for the 13-mode cycle were 0.0024 and 0.0023 g/kWh for the two most interesting emulsion and microemulsion fuels tested, respectively; 5-fold lower than the US 2007 emission limit.

Optical studies of combusting diesel sprays were done on three different alternative liquid fuels and compared to Swedish environmental class 1 diesel fuel (MK1). The alternative fuels were Rapeseed Oil Methyl Ester (RME), Palm Oil Methyl Ester (PME) and Fischer-Tropsch (FT) fuel. The studies were carried out in the Chalmers High Pressure High Temperature spray rig under conditions similar to those prevailing in a direct-injected diesel engine prior to injection. High speed shadowgraphs were acquired to measure the penetration of the continuous liquid phase, droplets and ligaments, and vapor penetration. Flame temperatures and relative soot concentrations were measured by emission based, line-of-sight, optical methods. A comparison between previous engine tests and spray rig experiments was conducted in order to provide a deeper explanation of the combustion phenomena in the engine tests.

Tailpipe particulate emissions, i.e., particle number, size distribution and total mass, from a series of four cylinder engines with 2L displacement and power output of approximately 150 hp have been measured. The engines were in their respective vehicle installation, all midsize vehicles from various manufacturers, and represented different combustion concepts, i.e., port- and direct injected vehicles and E5 and E85 fuels. The results are compared to post Euro V emission standards for gasoline and biofuels using diesel as reference. The results show that the type of combustion and fuel significantly affect the particulate formation. In general, direct injected engines show high particle numbers and mass compared to port injected engines. The particulate number and total mass can be reduced by using biofuels, e.g., ethanol mixes, instead of gasoline.