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2,5-dimethylfuran (DMF) is currently regarded as a potential alternative fuel to gasoline due to the development of new production technology. In this paper, the spray characteristics of DMF and its blends with gasoline were studied from a high pressure direct injection gasoline injector using the shadowgraph and Phase Doppler Particle Analyzer (PDPA) techniques, This includes the spray penetration, droplet velocity and size distribution of the various mixtures. In parallel commercial gasoline and ethanol were measured in order to compare the characteristics of DMF. A total of 52 points were measured along the spray so that the experimental results could be used for subsequent numerical modeling. In summary, the experimental results showed that DMF and its blends have similar spray properties to gasoline, compared to ethanol. The droplet size of DMF is generally smaller than ethanol and decreases faster with the increase of injection pressure.

In this study, the particle emission characteristics of 10% alternative diesel fuel blends (Rapeseed Methyl Ester and Gas-to-Liquid) were investigated through the tests carried out on a light duty common-rail Euro 4 diesel engine. Under steady engine conditions, the study focused on particle number concentration and size distribution, to comply with the particle metrics of the European Emission Regulations (Regulation NO 715/2007, amended by 692/2008 and 595/2009). The non-volatile particle characteristics during the engine warming up were also investigated. They indicated that without any modification to the engine, adding selected alternative fuels, even at a low percentage, can result in a noticeable reduction of the total particle numbers; however, the number of nucleation mode particles can increase in certain cases.

Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

Injection pressure oscillations are proven to determine considerable deviations from the expected mass flow rate, leading to the jet velocities non-uniformity, which in turn implies the uneven spatial distribution of A/F ratio. Furthermore, once the injector is triggered, these oscillations might lead the rail pressure to experience a decreasing stage, to the detriment of spray penetration length, radial propagation and jet break-up timing. This has urged the research community to develop models predicting injection-induced pressure fluctuations within the rail. Additionally, several devices have been designed to minimize and eliminate such fluctuations. However, despite the wide literature dealing with the injection-induced pressure oscillations, many aspects remain still unclear. Moreover, the compulsory compliance with environmental regulations has shifted focus onto alternative fuels, which represent a promising pathway for sustainable vehicle mobility.

Ethanol fuel blends with gasoline for spark ignition (SI) internal combustion engines are widely used on account of their advantages in terms of fuel economy and emissions reduction potential. The focus of this paper is to study the effects of these blends on combustion characteristics such as in-cylinder pressure profiles, gas-phase emissions (e.g., unburned hydrocarbons, NOx) and particulates (e.g., particulate matter and particle number) using both measurement campaigns and digital engineering workflows. Nineteen load-speed operating points in a 1L 3-cylinder GDI SI engine were measured and modelled. The measurements for in-cylinder pressure and emissions were repeated at each operating point for three types of fuel: gasoline (E0, 0% by volume of ethanol blend), E10 (10 % by volume of ethanol blend) and E20 (20% by volume of ethanol blend).

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution.

Unregulated emissions have become an important factor restricting the development of methanol and ethanol alternative alcohols fuels. Using two light-duty vehicles fuelled with pure gasoline, gasoline blend of 10% and 20% volume fraction of ethanol fuels, gasoline blend of 15% and 30% volume fraction of methanol fuels, New European Driving Cycle (NEDC) emission tests were carried on a chassis dynamometer according to ECE R83-05. High performance liquid chromatography (HPLC), Gas chromatography - Mass spectrometry (GC-MS), Fourier transform infrared spectrometer (FTIR) were used to measure methanol, formaldehyde, acetaldehyde, acetone, benzene, toluene, xylene, ethylene, propylene, 1,3-butadiene and isobutene emissions in the exhaust during the NEDC.

This study compared the combustion and emission characteristics of Homogeneous Charge Compression Ignition (HCCI) and Direct Injection Compression Ignition (DICI) modes in a boosted and high compression ratio (17) engine fueled with gasoline and gasoline/diesel blend (80% gasoline by volume, denoted as G80). The injection strategy was adjusted to achieve the highest thermal efficiency at different intake pressures. The results showed that Low Temperature Heat Release (LTHR) was not observed in gasoline HCCI. However, 20% additional diesel could lower down the octane number and improve the autoignition reactivity of G80, which contributed to a weak LTHR, accounting for approximately 5% of total released heat. The combustion efficiency in gasoline DICI was higher than those in gasoline HCCI and G80 HCCI, while the exhaust loss and heat transfer loss in DICI mode were higher than those in HCCI mode.

For spark ignition (SI) engines, the optimum spark timing is crucial for maximum efficiency. However, as the spark timing is advanced, so the propensity to knock increases, thus compromising efficiency. One method to suppress knock is to use high octane fuel additives. However, the blend ratio of these additives cannot be varied on demand. Therefore, with the advent of aggressive downsizing, new knock mitigation techniques are required. Fortuitously, there are two well-known lower alcohols which exhibit attractive knock mitigation properties: ethanol and methanol. Both not only have high octane ratings, but also result in greater charge-cooling than with gasoline. In the current work, the authors have exploited these attractive properties with the dual-injection, or the dual-fuel concept (gasoline in PFI and fuel additive in DI) using pure ethanol and methanol.

Ethanol has long been regarded as the optimal gasoline-alternative biofuel for spark-ignition (SI) engines. It is used widely in Latin and North America and is increasingly accepted as an attractive option across Europe. Nevertheless, its low energy density requires a high rate of manufacture; in areas which are deficient of arable land, such rates might prove problematic. Therefore, fuels with higher calorific values, such as butanol or 2,5-dimethylfuran (DMF) deserve consideration; a similar yield to ethanol, in theory, would require much less land. This report addresses the suitability of DMF, to meet the needs as a biofuel substitute for gasoline in SI engines, using ethanol as the biofuel benchmark. Specific attention is given to the sensitivity of DMF to various engine control parameters: combustion phasing (ignition timing), injection timing, relative air-fuel ratio and valve timing (intake and exhaust).

The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Gasoline Compression Ignition (GCI) engines using a low octane gasoline-like fuel (LOF) have good potential to achieve lower NOx and lower particulate matter emissions with higher fuel efficiency compared to the modern diesel compression ignition (CI) engines. In this work, we conduct a well-to-wheels (WTW) analysis of the greenhouse gas (GHG) emissions and energy use of the potential LOF GCI vehicle technology. A detailed linear programming (LP) model of the US Petroleum Administration for Defense District Region (PADD) III refinery system - which produces more than 50% of the US refined products - is modified to simulate the production of the LOF in petroleum refineries and provide product-specific energy efficiencies. Results show that the introduction of the LOF production in refineries reduces the throughput of the catalytic reforming unit and thus increases the refinery profit margins.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

Dieseline combustion as a concept combines the advantages of gasoline and diesel by offline or online blending the two fuels. Dieseline has become an attractive new compression ignition combustion concept in recent years and furthermore an approach to a full-boiling-range fuel. High speed imaging with near-parallel backlit light was used to investigate the spray characteristics of dieseline and pure fuels with a common rail diesel injection system in a constant volume vessel. The results were acquired at different blend ratios, and at different temperatures and back pressures at an injection pressure of 100MPa. The penetrations and the evaporation states were compared with those of gasoline and diesel. The spray profile was analyzed in both area and shape with statistical methods. The effect of gasoline percentage on the evaporation in the fuel spray was evaluated.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

A method to design a feasible multi-component fuel for fuel concentration measurements by using PLIF was developed based on thermal gravity (TG) analysis and vapor-liquid equilibrium (VLE) calculations. Acetone, toluene, and 1,2,4-trimethylbenzene were respectively chosen as tracers for the light, medium, and heavy components of gasoline. A five-component test fuel was designed for LIF measurement, which contains n -pentane (light), isooctane, n -octane (medium), n -nonane and n -decane (heavy). The TG analysis and VLE calculation were used to ensure that the fuel had volatility similar to real gasoline and that all the tracers had a good coevaporation ratio. The fully optimized results of the six-component fuel and the disadvantages of this case are discussed. The results indicated that optimization based on the six-component fuel, which included C4 compounds such as n -butane, controlled acetone's coevaporation ratio.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Homogeneous charge combustion and emissions of ethanol ignited by pilot diesel fuel were investigated on a two-cylinder diesel engine. The results show that emissions depend on loads and ethanol volume fraction. At low loads, ethanol has little effects on smoke. With the increase of ethanol, NOx decreases, but CO emissions increase. At high loads, smoke emissions reduce greatly with increasing ethanol, but NOx and total hydrocarbon (THC) emissions increase. With the increase of ethanol, ignition delays, combustion duration shortens. The maximum rates of heat release for the fuel containing 10 vol% ethanol (E10) and 30 vol% ethanol (E30) increase. Brake specific energy consumption (BSEC) of E10 and E30 is improved slightly only at full loads. Compared to smoke emissions obtained on the same engine using ethanol blended diesel fuels, the tendency of smoke reduction is similar to that of homogeneous charge combustion of ethanol at the same operating conditions.

With the high auto ignition temperature of natural gas, various approaches such as high compression ratios and/or intake charge heating are required for auto ignition. Another approach utilizes the trapping of internal residual gas (as used before in gasoline controlled auto ignition engines), to lower the thermal requirements for the auto ignition process in natural gas. In the present work, the achievable engine load range is controlled by the degree of internal trapping of exhaust gas supplemented by intake charge heating. Special valve strategies were used to control the internal retention of exhaust gas. Significant differences in the degree of valve overlap were necessary when compared to gasoline operation at the same speeds and loads, resulting in lower amounts of residual gas observed. The dilution effect of residual gas trapping is hence reduced, resulting in higher NOx emissions for the stoichiometric air/fuel ratio operation as compared to gasoline.