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Direct injection of natural gas under high pressure conditions has emerged as a promising option for improving engine fuel economy and emissions. However, since the gaseous injection technology is new, limited experience exists as to the optimum configuration of the injection system and associated combustion chamber design. The present study uses KIVA-3 based, multidimensional modeling to improve the understanding and assist the optimization of the gaseous injection process. Compared to standard k-ε models, a Renormalization Group Theory (RNG) based k-ε model [1] has been found to be in better agreement with experiments in predicting gaseous penetration histories for both free and confined jet configurations. Hence, this validated RNG model is adopted here to perform computations in realistic engine geometries.

A detailed chemical kinetic mechanism, consisting of 22 species and 104 elementary reactions, has been used in conjunction with the multi-dimensional reactive flow code KIVA-3 to study autoignition of natural gas injected under compression ignition conditions. Calculations for three different blends of natural gas are performed on a three-dimensional computational grid by modeling both the injection and ignition processes. Ignition delay predictions at pressures and temperatures typical of top-dead-center conditions in compression ignition engines compare well with the measurements of Naber et al. [1] in a combustion bomb. Two different criteria, based on pressure rise and mass of fuel burned, are used to detect the onset of ignition. Parametric studies are conducted to show the effect of additives like ethane and hydrogen peroxide in increasing the fuel consumption rate.

The combustion, knock characteristics and exhaust emissions in an engine were investigated under homogeneous charge compression ignition operation fueled with liquefied petroleum gas with regard to variable valve timing and the addition of di-methyl ether. Liquefied petroleum gas was injected at an intake port as the main fuel in a liquid phase using a liquefied injection system, while a small amount of di-methyl ether was also injected directly into the cylinder during the intake stroke as an ignition promoter. Different intake valve timings and fuel injection amount were tested in order to identify their effects on exhaust emissions, combustion and knock characteristics. The optimal intake valve open timing for the maximum indicated mean effective pressure was retarded as the λTOTAL was decreased. The start of combustion was affected by the intake valve open timing and the mixture strength (λTOTAL) due to the volumetric efficiency and latent heat of vaporization.

Dimethyl ether (DME) as a high cetane number fuel and liquefied petroleum gas (LPG) as a high octane number fuel were supplied together to evaluate the controllability of combustion phase and improvement of power and exhaust emission in homogeneous charge compression ignition (HCCI) engine. Each fuel was injected at the intake port and in the cylinder separately during the same cycle, i.e., DME in the cylinder and LPG at the intake port, or vice versa. Direct injection timing was varied from 200 to 340 crank angle degree (CAD) while port injection timing was fixed at 20 CAD. In general, the experimental results showed that DME direct injection with LPG port injection was the better way to increase the IMEP and reduce emissions. The direct injection timing of high cetane number fuel was important to control the auto-ignition timing because the auto-ignition was occurred at proper area, where the air and high cetane number fuel were well mixed.

The effect of the composition of propane (C₃H₈) and butane (C₄H₁₀) in liquefied petroleum gas (LPG) was investigated in a dual-fuel HCCI engine fueled with di-methyl ether (DME) and LPG. The composition of LPG affects DME-LPG dual fuel HCCI combustion due to the difference in the physical properties of propane that and butane such as octane number, auto-ignition temperature and heat of vaporization. DME was injected directly into the cylinder at various injection timing from 160 to 350 crank angle degrees (CAD). LPG was injected at the intake port with a fixed injection timing at 20 CAD. It was found that power output was increased with propane ratio. This gain in power output resulted from increased expansion work due to the better anti-knock properties of propane. However, higher propane ratio made combustion efficiency decrease because of the suppression in low temperature reaction of DME which determines heat release amount of high temperature reaction.

Combustion and flame propagation characteristics of the liquid phase LPG injection (LPLI) engine were investigated in a single cylinder optical engine. Lean burn operation is needed to reduce thermal stress of exhaust manifold and engine knock in a heavy duty LPG engine. An LPLI system has advantages on lean operation. Optimized engine design parameters such as swirl, injection timing and piston geometry can improve lean burn performance with LPLI system. In this study, the effects of piston geometry along with injection timing and swirl ratio on flame propagation characteristics were investigated. A series of bottom-view flame images were taken from direct visualization using a UV intensified high-speed CCD camera. Concepts of flame area speed, in addition to flame propagation patterns and thermodynamic heat release analysis, was introduced to analyze the flame propagation characteristics.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

This work reports the development and application of multi-dimensional ignition, combustion and emissions models that account for detailed chemistry and mixing effects in a direct injection engine simulation. A detailed chemical reaction mechanism, consisting of 24 species and 104 reactions, is used for increased accuracy of emissions predictions. Turbulent combustion is represented using a modified Eddy Dissipation Concept (EDC) model to account for mixing effects. The soot model includes all aspects of soot formation and destruction. Particle transport equations are used to realistically track transport of the soot particles formed. All computational sub-models developed in this work have been implemented in a modified version of the KIVA-3V code. In order to illustrate the behavior of the new models, soot and NO emissions have been predicted at different operating conditions by varying injection timing, exhaust gas recirculation (EGR) and injection pressure.

To investigate the mixture distributions in an LPG engine with Liquid phase port injection for heavy duty vehicles, an optical single cylinder engine, which is optically accessible both in side and bottom view, and laser diagnostic system were incorporated to apply PLIF (planar laser induced fluorescence) technique. Acetone was used as a dopant in LPG fuel, which was excited by KrF excimer laser (248nm), and its fluorescence images were acquired with ICCD camera. The effects of fuel injection timing, swirl intensity and excess air ratio were investigated. For the case of open valve injection, favorable stratification of fuel, both in axial and radial direction, was clearly observed compared to the closed valve injection, where reverse stratification in axial direction was observed. At the Ricardo swirl ratio of 3.4, it was apparent that excessive axial stratification of fuel got dominant, which would lead to poor engine performances.

Submodels are developed for injection, evaporation and wall impingement of a liquid LPG spray. The injection model determines the quality of fuel as two-phase choke flow at the nozzle exit. Wind tunnel experiments show the spray penetration more sensitive to ambient flow velocity than to injection pressure. Most evaporation occurs during choking, while heat transfer from surrounding air has a negligible effect on downstream droplet sizes. Three dimensional simulation shows that the bathtub cavity is better than the dog-dish cavity for stable flame propagation in lean-burn conditions. The injection timing during the IVC period has a negligible effect, while injection during an intake stroke enhances fuel/air mixing to result in more homogeneous cylinder charge.

A prototype of a small, spark-ignition free-piston engine combined with a linear alternator was designed to produce electric power for portable usage. It has a bore size of 25 mm and maximum stroke of 22 mm. The engine was fueled with liquefied petroleum gas consisting of 98% propane. The electric power generated by the linear alternator is a function of the piston dynamics and the electric conductance. Therefore, the purpose of current research is to investigate the effects of the basic engine controlling parameters such as the equivalence ratio of the mixture and the spark timing on the piston dynamics and study the relationship with the electric power generation performance. The equivalence ratio of the mixture was varied from 1.0 to 1.72, while the spark timing was varied at 3, 4, and 5 mm away from the maximum top dead center. Operating characteristics, namely, indicated mean effective pressure, electric power output, operating frequency and piston stroke were analyzed.

The effect of natural gas composition on ignition delay has been investigated numerically by using detailed and reduced chemical kinetic mechanisms. Three different blends of natural gas have been analyzed at pressures and temperatures that are typical of top dead center conditions in compression ignition engines. The predicted ignition delay shows a decrease with temperature in an Arrhenius manner and has a first order dependence on pressure. Similar trends have been observed by Naber et al. [1] in their experimental study of natural gas autoignition in a bomb. It is shown that two kinetic mechanisms (GRI-Mech 1.2 and reduced set DRM22) are best capable of predicting the ignition delay of natural gas under compression ignition conditions. The DRM22 mechanism has been chosen for further studies as t involves lower computational costs compared to the full GRI-Mech 1.2 mechanism.

To meet the target of the CO2 regulations, it is mandatory to replace high-carbon fossil fuels with low-carbon fuels. Diesel/Natural Gas (NG) reactivity-controlled compression ignition (RCCI) can reduce CO2 emission, which stratifies two types of fuels with different reactivity. And also, RCCI produces less NOx and particulate matter emissions by reducing the in-cylinder temperature. However, RCCI must still be enhanced in terms of the thermal and combustion efficiencies at low and medium loads. In this work, a modified piston geometry was applied to improve the RCCI combustion. The piston geometry was designed to minimize heat loss and reduce flame quenching in an RCCI engine. Experiments were conducted using a single-cylinder engine with a displacement volume of 1,000 cc. Diesel was directly injected into the cylinder, and NG was fed through the intake port.

The heat release and pollutant formation processes in a direct injection natural gas engine are studied by coupling detailed chemistry with a multi-dimensional reactive flow code. A detailed kinetic mechanism consisting of 22 species and 104 elementary reactions is chosen by comparing ignition delay predictions with measurements in a combustion bomb. The ignition model is then coupled with a turbulent combustion model and extended Zeldovich kinetics to simulate heat release and nitric oxide production in a direct injection engine. Parametric studies are conducted to investigate the effect of engine operating conditions which include speed, load, injection timing and level of boost. It is shown that use of detailed chemistry is extremely important to predict the correct ignition delay period as engine operating conditions change. Use of both time and crank angle as the independent variable reveals interesting details of the heat release process as a function of engine speed.

A computer simulation of the Homogenous Charge Compression Ignition (HCCI) four-stroke engine has been developed for combustion and performance studies. The simulation couples models for mass, species, and energy within a zero-dimensional framework. The combustion process is described via a user-defined chemical kinetic mechanism. The CHEMKIN libraries have been used to formulate a stiff chemical kinetic solver suitable for integration within a complete engine cycle simulation, featuring models of gas exchange, turbulence and wall heat transfer. For illustration, two chemical kinetics schemes describing hydrogen and natural gas chemistry have been implemented in the code. The hydrogen scheme is a reduced one, consisting of 11 species and 23 reactions. The natural gas chemistry is described via the GRI-mechanism 3.0 that considers 53 species and 325 reactions, including NOx chemistry.

The concentrations of individual exhaust hydrocarbon species were measured as a function of air-fuel ratio and EGR in a 2-liter four-cylinder engine using a gas chromatography, for natural gas and LPG. NMHC in addition to the species of HC, other emissions such as CO2, CO and NOx were at 1800rpm for two compression ratios (8.6 and 10.6) and various EGR ratios up to 7%. Fuel conversion efficiencies were also investigated together with emissions to study the effect of engine parameters on the combustion performances in gas engines especially under the lean burn conditions. It was found that CO2 emission decreased leaner mixture strength, the higher compression ratio and certainly with smaller C value of fuel. HC emissions from LPG engine consisted primarily of propane (larger 60%), ethylene and propylene, while main emissions from natural gas were methane (larger than 60%), ethane, ethylene and propane on the average.

Most internal combustion engine makers have adopted after-treatment systems, such as selective catalytic reduction (SCR), diesel particulate filter (DPF), and diesel oxidation catalyst (DOC), to meet emission regulations. However, as the emission regulations become stricter, the size of the after-treatment systems become larger. This aggravates the price competitiveness of engine systems and causes fuel efficiency to deteriorate due to the increased exhaust pressure. Dual-fuel premixed charge compression ignition (DF-PCCI) combustion, which is one of the advanced combustion technologies, makes it possible to reduce nitrogen oxides (NOx) and particulate matter (PM) during the combustion process, while keeping the combustion phase controllability as a conventional diesel combustion (CDC). However, DF-PCCI combustion produces high amounts of hydrocarbon (HC) and carbon monoxide (CO) emissions due to the bulk quenching phenomenon under low load conditions as a huddle of commercialization.

Lean stratified combustion shows high potential to reduce fuel consumption because it operates without the intervention of a throttle valve. Despite its high fuel economy potential, it emits large amounts of particulate matter (PM) because the locally rich mixture is formed at the periphery of a spark plug. Furthermore, the combustion phasing angle is not realized at MBT ignition timing, which can bring high work conversion efficiency. Since PM emission and work conversion efficiency are in a trade-off relation, this research focused on reducing PM emission through achieving high work conversion efficiency. Two intake air control strategies were examined in this research; throttle operation and late intake valve closing (LIVC). The experiment was conducted in a single cylinder spray-guided direct injection spark ignition (SG-DISI) engine with liquefied petroleum gas (LPG). The injected fuel amount was fixed so as to investigate the effect of each strategy.

The application of dual-fuel combustion in the freight transportation sectors has received considerable attention due to the capability of achieving higher fuel efficiency and less pollutant emissions than the conventional diesel engines. In this study, high-speed flame visualization was used to investigate the phenomena of natural gas/diesel dual-fuel combustion in a single-cylinder heavy-duty engine with optical access. To implement diverse fuel blending conditions, diesel injection timing and natural gas substitution ratio were varied under constant fuel energy input. A novel flame regime separation method was implemented based on color segmentation in HSV color space to characterize the spatial distributions of premixed and non-premixed flame regimes. Flame images for larger natural gas substitution showed a significant reduction in the non-premixed flame regime accompanied by flame propagation along the vaporized diesel sprays.