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This research focuses on co-cations modified Cu-zeolite catalyst CuCe/SSZ-13. The NOx conversion and hydrothermal stability of fresh and aged Cu/SSZ-13 and CuCe/SSZ-13 were evaluated to conclude the impact of Ce on the zeolite stability and mechanism of NH3-SCR reaction. For fresh samples, CuCe/SSZ-13 exhibited more than 80% efficiency at 225 °C to 600 °C, and showed higher NOx conversion below 225 °C and above 450 °C than Cu/SSZ-13. For aged catalysts, CuCe/SSZ-13 exhibited higher efficiency at all test temperatures than Cu/SSZ-13, and exhibited over 80% conversion at 225 °C to 350 °C, whereas, that was only 250 °C to 300 °C over fresh Cu/SSZ-13 sample. Furthermore, the effect of co-cation Ce on the phase structure changes, acid sites, redox capacity, transformation of various Cu species, and framework stability of the samples were evaluated by several techniques, such as TPD, TPO, TPR, BET, and XRD.

Exhaust gas recirculation (EGR) is effective in reducing engine-out NOx emissions; however, the EGR system is subject to fouling and corrosion. Fouling is mainly due to particulate buildup on the EGR component (e.g., EGR valve and cooler) surfaces. Corrosion is primarily related to oxides of sulfur and nitrogen in the gas stream, especially problematic when condensation occurs [1]. Because cooled EGR is most effective in controlling NOx emissions, EGR cooler design and operation are important considerations in engine design in order to meet durability requirements. An approach has been developed to greatly reduce EGR system fouling. Four EGR coolers were tested simultaneously with various PM control devices installed upstream of the cooler. System configuration and on-engine test results are presented herein.

Model validation is a process to assess the validity and predictive capabilities of a computer model by comparing simulation results with test data for its intended use of the model. One of the key difficulties for model validation is to evaluate the quality of a computer model at different test configurations in design space, and interpolate or extrapolate the evaluation results to untested new design configurations. In this paper, an integrated model interpolation and extrapolation framework based on Bayesian inference and Response Surface Models (RSM) is proposed to validate the designs both within and outside of the original design space. Bayesian inference is first applied to quantify the distributions' hyper-parameters of the bias between test and CAE data in the validation domain. Then, the hyper-parameters are extrapolated from the design configurations to untested new design. They are then followed by the prediction interval of responses at the new design points.

Sampling-based methods are general but time consuming for solving a Reliability-Based Design Optimization (RBDO) problem. In order to alleviate the computation burden, score function together with the Monte Carlo method was used to compute the stochastic sensitivities of reliability functions. In literature, re-weighting schemes were shown to converge faster than the regular Monte Carlo method. In this paper, a reweighting scheme together with score function is employed to perform sampling-based stochastic sensitivity analysis to improve the computational efficiency and accuracy. An analytical example is used to show the advantages of the proposed method. Comparisons to the conventional methods are made and discussed. Two RBDO problems are solved to demonstrate the use of the proposed method.

The diesel particulate filter (DPF) is a critical aftertreatment device for control of particulate matter (PM) emissions from a diesel engine. DPF survivability is challenged by several key factors such as: excessive thermal stress due to DPF runaway regenerations (or uncontrolled regeneration) may cause DPF substrate and washcoat failure. Catalyst poisoning elements from the diesel fuel and engine oil may cause performance degradation of the catalyzed DPF. Harsh vibration from the powertrain, as well as from the road surface, may lead to mechanical failure of the substrate and/or the matting material. Evaluations of these important validation parameters were performed.

A high-efficiency NOx aftertreatment system has been proposed for use in Diesel engines. This system includes a Lean NOx Trap (LNT) in series with a Selective Catalyst Reduction (SCR) catalyst [6], [7], [8], and is hereinafter referred to as the LNT-SCR system. The combined LNT-SCR system can potentially overcome many of the drawbacks of LNT-only and SCR-only operation and achieve very high NOx conversion efficiency without external addition of ammonia (or urea). A laboratory test procedure was developed to validate the LNT-SCR system concept, and a series of tests was conducted to test the NOx conversion of this system under various conditions. A Synthetic Gas Reactor (SGR) system was modified to accommodate LNT and SCR catalyst cores and synthetic gas mixtures were used to simulate rich-lean regeneration cycles from a diesel engine. A Fourier Transform Infrared (FTIR) system was used to measure gas compositions within the LNT-SCR system.

Dow Automotive has developed an ACM DPF substrate, characterized with light-weight, low pressure-drop, rapid regeneration, and excellent chemical resistance at high temperature. An uncatalyzed DPF was tested on a 2.0L common-rail diesel engine for over 100 soot loading and regeneration cycles, which included a combination of controlled regenerations, uncontrolled regenerations and incomplete regenerations. The DPF demonstrated high filtration efficiency and physical integrity throughout the entire test. The ACM DPF has also demonstrated excellent catalyst coating capability and performance. An ACM DPF with a total volume of three-liter and coated with the same catalyst formulation as the original catalyzed DPF, was used to replace the OEM four-liter catalyzed SiC DPF on a 2005 model-year 1.9L European diesel passenger car. It was demonstrated that the ACM DPF has lower pressure drop and faster regeneration than that of the OEM DPF.

In Brazil the market for small motorcycles had steadily increased during the last decade. Nowadays more than a 1.5 million units are produced every year. Market forecasts show that this trend will remain for many years. The amount of pollutant gases emitted by the small motorcycles fleet, begin to be significant. For this reason, the government established emissions laws for motorcycles to be effective since 2003. This law will become stricter over the years up to the point that the use of electronic fuel injection systems for small motorcycles will be a convenient way to adhere to the law. The cost of ethanol fuel is almost half of the gasoline and therefore is the fuel of choice of the majority of drivers. Moreover the use of ethanol is far better than gasoline in terms of emission of green house effect gases. The current motorcycle's fuel delivery systems are not suited to use ethanol.

A novel urea evaporation and mixing device has been developed to improve the overall performance of a urea-SCR system. The device was tested with a MY2007 Cummins ISB 6.7L diesel engine equipped with an SCR aftertreatment system. Test results show that the device effectively improved the overall NO conversion efficiency of the SCR catalyst over both steady-state and transient engine operating conditions, while NH₃ slip from the catalyst decreased.

Particulate Matter (PM) emissions from gasoline direct injection (GDI) engines are becoming a concern and will be limited by future emissions regulations, such as the upcoming Euro 6 legislation. Therefore, PM control from a GDI engine will be required in addition to effective reduction of HC, CO and NOx emissions. Three different integrated aftertreatment systems were developed to simultaneously reduce PM, HC, CO and NOx emissions from a preproduction Ford 3.5L EcoBoost GTDI engine, with PM reduction as the major focus. PM reduction efficiencies were calculated based on the measurements of PM mass and solid particle number. Test results show that tradeoffs exist in the design of aftertreatment systems to significantly reduce PM emissions from a GDI engine.

Low-cost automotive catalysts have been developed that contain 20-30% of the precious metals (7-15 g/ft3) commonly used in conventional catalysts, while providing a high efficiency of emissions control and durability for vehicles operating in emerging market countries. These catalysts were reformulated by replacing the Pd, Pt and Rh mixtures with optimized mixtures of rare-earth oxides (REOs). Laboratory studies demonstrated that these aged REO catalysts (80,000 km) with unleaded Chinese fuels reduce vehicle emissions by an average of 99%, 80% and 92% for CO, HC and NOx, respectively, when operating as a three-way catalyst in a closed-loop control mode at a stoichiometric air-to-fuel ratio. REO catalysts with 7.6g/ft3 of precious metals were tested on in-use Chinese Volkswagen Santanas with carbureted engine. Several strategies for air injection were tested on these vehicles.

Multidisciplinary Design Optimization (MDO) has been widely used in the automotive industry to balance overall weight and stringent vehicle attributes, such as safety, NVH, durability, etc. To improve product quality and shorten product development cycle, a comprehensive MDO-based platform for vehicle attribute integration is developed in this paper. Some key issues in the platform development are addressed: Parameter model synchronization, Metamodel predictive capabilities, and Pre/post processing, etc. In addition, a strategy for body design is proposed to achieve weight targets while meeting other vehicle attributes. Lastly, the proposed methodology is demonstrated by a real world example for vehicle body design.

Three-phase sequential turbocharging system with two unequal-size turbochargers is developed to improve fuel economy performance and reduce emission of the automotive diesel engine, which satisfies wide range of intake flow demand. However, it results in complicated transient control strategies under frequently changing operating conditions. The present work aims to optimize the control scheme of boost system and fuel injection and evaluate their contributions to the improvement of transient performance. A mean value model for diesel engine was built up in SIMULINK environment and verified by experiment for transient study. Then a mathematical model of optimization issue was established. Strategies of control valves and fuel injection for typical acceleration and loading processes are obtained by coupled calculating of the simulation model and optimization algorithm.

With the rapid expansion of the automotive market in China, air quality in the major cities has become a severe concern. Great efforts have been made in introducing new emission regulations; however, fuel and lubricant qualities, emissions aftertreatment system durability and in-use compliance to the emissions regulations still require significant improvement. China follows the European Union (EU) emission regulations in general, but different levels of standards exist. This paper gives a comprehensive overview of the current and near-future heavy-duty diesel emission regulations, as well as fuel and lubricant specifications.

Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH₃ storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH₃ storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH₃ slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.

Diesel particulate filters (DPF) have been shown to effectively reduce particulate emissions from diesel engines. However, uncontrolled DPF regeneration can easily damage the DPF. In this paper, three different types of uncontrolled DPF regeneration are defined. They are: Type A: Uncontrolled high initial exotherm at the start of DPF regeneration, Type B: “Runaway” or uncontrolled regeneration, which takes place when the engine goes to idle during normal DPF regeneration, and Type C: Uneven soot distribution causing excess thermal stress during normal DPF regeneration. In this paper, different control strategies are developed for each of the three types of uncontrolled DPF regenerations. These control strategies include SOF control, exhaust flow pattern improvement, as well as EGR control through intake throttling and A/F ratio control.

In recent years, Diesel Particulate Filter (DPF) systems have become the state-of-the-art technology to realize low particulate emission for light, medium or heavy-duty diesel vehicles. In addition to good filtration efficiency and thermo-mechanical robustness, the engine backpressure resulted from the DPF installation is an important parameter which directly impacts the fuel economy of the engine. The goal of this experimental test series was to determine the dependence of fuel consumption on engine backpressure resulted from a DPF installed on a heavy-duty application. The testing was executed on a MY2003 Volvo D12 heavy-duty diesel engine in an engine test cell at Southwest Research Institute (SwRI). Empty DPF cans were used with an exhaust valve to mimic the post turbo pressure levels for two different types of DPF materials at nine selected engine operating points of the European Stationary Cycle (ESC).

The diesel premixed low-temperature combustion mode avoids the generation of thick mixture and the high temperature region in which a great amount of NOx and PM generates. It makes a significant reduction in the emissions of both NOx and PM available at the same time. However, with the quantity of pre-injection increases and the injection time advances, the emission of HC increases significantly, which causes a decrease in the combustion efficiency. Studies have shown that the flame quench caused by too thick or too lean mixture and the oil film on the chamber is the main source for the emission of HC. As a result, understanding the mechanism of atomization and evaporation of the fuel and the formation of the mixture makes significant sense. This paper focuses on the mixture formation process. And the methods of testing the distribution of the mixture, the influential factors and control methods are studied.

In the internal combustion engine, about 25%-40% of the energy released by burned fuel is taken away by the exhaust gas. The part of the usable energy in the exhaust can be used in the turbocharged engine. So, at present, turbocharged diesel engine hasn't made full use of exhaust gas energy. The authors propose a model of the 4-stroke turbocharged diesel engine of split exhausting system. Adding a rapidly on-and-off exhaust control valve between exhaust passage and manifold in the 4-stroke turbocharged diesel engine can improve the utilization rate of the usable energy in the exhaust. By utilizing the mean effective pressure (MEP), this paper is to calculate the maximum usable energy, the energy provided by exhaust and the energy required by intake. The results gets that the new type of exhausting system can help engine to increase usage rate of the exhaust gas energy to around 20% at the rated condition compared to the existing vehicle diesel engines with VNT.

Aiming at the high altitude operation problems for piston-type aero-engines and to improve the practical ceiling and high altitude dynamic performance, this thesis analyzes a controllable three-stage composite supercharging system, using a two-stage turbocharger coupled supercharger method. The GT-Power simulation model of a four-cylinder boxer engine was established, and the control strategy of variable flight height was obtained. The simulation research of engine performance from 0 to 20,000 meters above sea level has been carried out, which shows that the engine power is at the same level as the plain condition, and it could still maintain 85.28 percent of power even at the height of 20,000 meters, which meets the flight requirements of the aircraft.