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Isopentanol is an advanced biofuel that can be produced by micro-organisms through genetically engineered metabolic pathways. Compared to the more frequently studied ethanol, isopentanol's molecular structure has a longer carbon chain and includes a methyl branch. Its volumetric energy density is over 30% higher than ethanol, and it is less hygroscopic. Some fundamental combustion properties of isopentanol in an HCCI engine have been characterized in a recent study by Yang and Dec (SAE 2010-01-2164). They found that for typical HCCI operating conditions, isopentanol lacks two-stage ignition properties, yet it has a higher HCCI reactivity than gasoline. The amount of intermediate temperature heat release (ITHR) is an important fuel property, and having sufficient ITHR is critical for HCCI operation without knock at high loads using intake-pressure boosting. Isopentanol shows considerable ITHR, and the amount of ITHR increases with boost, similar to gasoline.

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.

A two-stroke engine has various advantages. It is simple in structure, light in weight, high in mechanical efficiency, superior in accelerating ability, etc. However, its fuel consumption is bad, its combustibility under partial load is poor and it is usually accepted that its exhaust gas is problematic. With increasing traffic flow volume, it has become recently necessary to operate transiently each vehicle with frequent stops and starts, as well as decelerations and accelerations. From this standpoint, the authors have formed a simple dynamic model of two-stroke engine, and by means of simulation investigated how its performance can be improved while it is transiently operated, in combination with experiment. The results confirm that the calculations from the model coincide approximately with experiment. The influences of various factors on the performance have been revealed.

In this study, accordingly, methanol fuel was supplied in suction pipe with carburetor and with electronically-controlled fuel injector (EFI), which located in front of the suction valve, to clear experimentally the influence of various factors, such as the methanol-gasoline ratio (M/F), the difference in fuel feed system, the number of times of injection [ni], the injection timing (θinj), the engine speed (N), the volumetric efficiency (η v), the suction pipe wall temperature (tw), the water content in fuel (yw) etc., on the engine performance (the output and the thermal efficiency), the exhaust characteristics (NOx, CO, UBF and HCHO concentrations) and combustion variation as well as obtaining a guideline to establish the optimum condition. The authors will be report about the results of above-mentioned.

Under the accelerating or decelerating operation, it is demanded to improve the performance and reduce the exhaust smoke of diesel engines. Regarding the exhaust smoke regulation for a vehicle engine under transitional operation, the so-called free or controlled accelerating operation, are adopted as the simple measuring method. And the engine applied for the construction or agriculture is always operating under the load conditions of stepwise or periodical changes. For two-stroke engines, in particular, the effects of operating conditions on the engine performance and the smoke character are unclear. In order to meet such demand, it is necessary to make clear the transitional character of each transfer element, i.e., the fuel injection system, the combustion process and the frictional loss.

Reduction of soot and NOx emissions from a prechamber-type diesel engine is studied by employing both chemical and physical aspects of the fuel and induction method. Fuel modification was performed to produce several forms of composite fuel: solution of alcohol and gas oil (JIS No. 1); emulsification and mixture of methyl alcohol-gas oil prepared by off- and in-line fuel systems; and separate injection of fuels into the pre- and main-chamber.

To examine the effects of exhaust gas recirculation (EGR) on the exhaust emissions and on the cycle-by-cycle variation of combustion process in a methanol engine, the authors have tried to measure the emissions of total hydrocarbon, carbon monoxides, nitric oxides and formaldehyde and to record the cylinder pressure development histories of 1000 cycles duration. Moreover, the standard deviation of peak pressure Pmax, the heat release rate and the averaged pressure history are analyzed. The results are compared with those of gasoline fueled operation.

The engine performance, combustion characteristics and exhaust emission of pre-chamber type compression ignition engine operated by various biomass fuels were investigated experimentally. The biomass fuel investigated in this report are an emulsified fuel made with gas oil and hydrous ethanol or hydrous methanol, an emulsified fuel made with hydrous methanol and rape-seed oil, and neat rape-seed oil, and gas oil. There are small deviations of the experimental results between the biomass fuels, however, the general tendencies of the engine performances and exhaust gas characteristics operated by biomass fuels are as follows: The brake thermal efficiency during biomass fuel operation becomes maximum at a certain injection timing as well as those of the gas oil operation. And this injection timing is advanced with increasing the biomass content in the fuel.

So far the studies on the dynamic characteristic of internal combustion engines have been mainly carried out on the governor system and have led to development of a mathematical model more efficient for simulation and control purpose. But, there are still uncertain dynamic behaviors of the engine. The experiment and analysis on the transfer characteristic of effective torque and engine speed under a changing fuel feed quantity or brake load were carried out by using the frequency response and step response methods. Consequently, it was confirmed that the transfer response of effective torque and engine speed to the changes in fuel feed quantity or brake load comprises a response time lag and its time constant is variable with the operating condition of the engine.

If the water/gas-oil-emulsion fuel is to be used in a compression ignition engine, it is necessary not only to carry out directly engine experiment but also to determine the characteristics of so-called mixture formation process, including those of fluidity, spray mode, injection rate and evaporation in high-temperature environment and on high-temperature wall as well as the influence of these characteristics on engine performance. In this report, the authors have experimentally investigated on the physical properties and injection characteristics of water/gas oil-emulsion fuel (W/O).

The performance of a medium duty DME truck was evaluated by field tests and engine bench tests. The DME vehicle was given a public license plate on October 2004, after which running tests were continued on public roads and a test course. The DME vehicle could run the whole distance, about 500 km, without refueling. The average diesel equivalent fuel consumption of the fully loaded DME truck was 5.75 km/l, running at 80 km/h on public highways. Remedying several malfunctions that occurred in the power-train subsystems enhanced the vehicle performance and operation. The DME vehicle accumulated 13,000 km as of August, 2006 with no observed durability trouble of the fuel injection pump. Disassembly and inspection of the fuel injectors after 7,700 km operation revealed a few differences in the nozzle tip and the needle compared to diesel fuel operation. However, the injectors were used again after cleanup.

In this study, diesel exhaust emission characteristics were investigated as GTL (Gas To Liquid) fuel was applied to a heavy-duty diesel truck which had been developed to match a Japanese new long-term exhaust emission regulation (NOx < 2.0 g/kWh, PM < 0.027 g/kWh). The results in this study show that although the test vehicle has advanced technologies (e.g. high pressure fuel injection, oxidation catalyst, and urea-SCR aftertreatment system, etc.) which are applied to reduce diesel emissions, the neat GTL fuel has a great advantage to reduce particulate matter emissions and poly aromatic hydrocarbons. And regarding nano-size PM emissions, nuclei mode particles emitted during idling are significantly decreased by using the GTL fuel.

Biodiesel fuel has attracted much attention as a carbon neutral fuel because it is made from vegetable oil. Especially in Southeast Asia, there are numerous biofuel resources, such as palm oil and coconut oil, and it is desirable to utilize these for CO2 reduction. In this paper, we evaluate the properties of biodiesel fuel and biodiesel blended diesel oil. The low temperature performance of palm oil methyl ester (PME) is poor and it affects low temperature performance, even if the PME blending rate is low. The oxidation stability is a very important property of biodiesel fuel because degraded biodiesel fuel produces organic acids and polymeric substances. PME contains mainly saturated fatty acids methyl esters, so the oxidation stability is better than other fats and oils. When containing antioxidants such as beta carotene, biodiesel's oxidation stability is improved.

It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

It has been clarified that diesel fuel properties have a great effect on the exhaust emissions and fuel consumption of a conventional diesel combustion regime. And as other diesel combustion regimes are applied in order to improve exhaust emissions and fuel consumption, it can be supposed that the fuel properties also have significant effects. The purpose of this study is to propose the optimum diesel fuel properties for a premixed compression ignition (PCI) combustion regime. In this paper, the effect of the auto-ignitability of diesel fuels on exhaust emissions and fuel consumption was evaluated using a heavy-duty single-cylinder test engine. In all experiments, fuels were injected using an electronically controlled, common-rail diesel fuel injector, and most experiments were conducted under high EGR conditions in order to reduce NOx emissions.

In this study, a piezo disk was used to generate a cloud of n-decane fuel drops, which were mixed with air, then carried into a combustion chamber and ignited by a platinum wire. Microgravity data obtained at the Japan Microgravity Center (JAMIC) were compared to normal gravity data, all at 1Atm pressure and 20+/-1°C initial temperature. Under normal gravity the lean limit was found to be 7.6x106/mm3 (Φ = 1.0), and from this point the flame front speed steadily increased from 20cm/s up to a maximum flame front speed of 210cm/s at a fuel drop density of about 14x106/mm3 (Φ = 1.85). Microgravity data showed a much richer lean limit - about 14.5x106/mm3 (Φ = 1.9), and the flame front speed did not gradually rise to a peak value. Instead, the measurements indicated a peak value of about 250cm/s, with a steep increase followed by a gradual decrease at richer fuel air ratios. A cellular flame structure appeared, and the cell size decreased as the mixture density increased.

Dimethyl Ether (DME) is a promising new alternative fuel for compression ignition DI engines. However, some problems arise from the poor lubricity of DME. Breakdown of the film bearing between needle and sleeve of the injector can lead to mechanical wear and leakage, a problem that is not mitigated easily. For example, the application of returning the leakage to fuel tank could raise a back pressure on the injection needle. This pressure can affect injection rate and consequently engine performance. In this study, fuels based on various DME to gas oil (diesel fuel) ratios were investigated, in part. Physical and chemical properties of DME and gas oil are shown to lead to mutual solubility at any ratio. Blended fuels have a higher lubricity compared with pure’ DME and a better injection spray compared with pure gas oil.

A novel way of using low-cetane-number petroleum gases in a compression ignition (CI) engine is introduced, by directly injecting blends of such fuels with dimethyl ether (DME), a high-cetane-number alternative fuel for low soot emissions. This method both extends advantages of DME and complements its deficiency. Although DME mixes with most hydrocarbon fuels in any ratio, in order to demonstrate the feasibility of the new method and facilitate the analysis, DME-propane blends were investigated in a direct injection CI engine. Some findings of the study are listed. In the engine operated by DME and propane blends, there was no need for significantly increasing the complexity of the fuel system than that employed in the use of neat DME. For the same reason, this method eliminates or minimizes cumbersome hardware necessary when the said gaseous fuels are separately introduced in CI engines.

Flame propagation at elevated pressures for propane, butane and autogas (20% propane and 80% butane by mass) were investigated. Flame arrival time was measured using ionization probes installed along the wall of a cylindrical combustion chamber. Flame radius was also measured using a laser schlieren technique. Results showed that the flame front speed decreased with increasing initial pressure, and the initial pressure effect on maximum flame front speed was correlated by the relationship Sf = 175·pi-0.15 (for Φ=1.0). Characteristics of flame front speed between propane, butane and autogas were very similar, whereas at fuel-rich conditions flame front speed of butane and autogas were higher than that of propane. A thermodynamic model to predict flame radius and speed as a function of time was derived and tested using measured pressure-time curves.

The combustion mechanism of a fuel droplet cloud was studied by numerical simulation. We investigated how the flame front speed and combustion products changed depending on the equivalence ratio and initial temperature. Modeling was performed using the KIVA-III software package, a three dimensional analysis software used mainly for internal combustion engine applications. The computational domain was a horizontal 1x1x100 cell sector of a spherical combustion chamber and the fuel was n-decane. Results showed that when all the fuel droplets were assumed to have evaporated, the flame front speed increased from 28 cm/s to 152 cm/s as the equivalence ratio increased. The maximum flame front speed was reached at ϕ=1.1, beyond which it decreased (at richer overall equivalence ratios). With a constant equivalence ratio, the flame front speed decreased near the outside region, because the unburned gas was compressed by the expanding burned gas.