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Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

A work-based window method has been developed to calculate in-use brake-specific oxides of nitrogen (NOx) emissions for all engine speeds and engine loads. During an in-use test, engine speed and engine torque are read from the engine's electronic control unit, and along with time, are used to determine instantaneous engine power. Instantaneous work is calculated using this power and the time differential in the data collection. Work is then summed until the target amount of work is accumulated. The emissions levels are then calculated for that window of work. It was determined that a work window equal to the theoretical Federal Test Procedure (FTP) cycle work best provides a means of comparison to the FTP certification standard. Also, a failure criterion has been established based on the average amount of power generated in the work window and the amount of time required to achieve the target work window to determine if a particular work window is valid.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

Tube Launched-Unmanned Air Vehicles (TL-UAV) are munitions that alter their trajectories during flight to enhance the capabilities by possibly extending range, increasing loiter time through gliding, and/or having guided targeting capabilities. Traditional munition systems, specifically the tube-launched mortar rounds, are not guided. Performance of these "dumb" munitions could be enhanced by updating to TL-UAV and still utilize existing launch platforms with standard propellant detonation firing methods. The ability to actively control the flight path and extend range of a TL-UAV requires multiple onboard systems which need to be identified, integrated, assembled, and tested to meet cooperative function requirements. The main systems, for a mortar-based TL-UAV being developed at West Virginia University (WVU), are considered to be a central hub to process information, aerodynamic control devices, flight sensors, a video camera system, power management, and a wireless transceiver.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.

The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.

Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.

Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.

The U.S. Department of Energy (DOE) is embarking on a program investigating the use of Fischer-Tropsch (FT) fuels as a premium quality substitute or blending agent in direct-injection compression-ignition (diesel) engines. This paper aims to direct attention to the processing of FT fuels, emissions issues, available engine technology and the opportunity offered by FT diesel fuels for emissions control when considering diesel injection techniques. In modern automotive and heavy duty direct-injected (DI) diesel engines, precise fuel injection control is critical for achievement of 1998 and 2004 NOX and PM emission levels. High injection pressures, pilot injection and injection rate shaping are all optimized to maximize efficiency and power and to minimize emissions. These parameters must be considered as variables in the trade-off scenario between NOX and PM. Another parameter that may be considered important is the fuel type.

New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

The California Air Resources Board (ARB) developed a Medium Heavy-Duty Truck (MHDT) schedule by selecting and joining microtrips from real-world MHDT. The MHDT consisted of three modes; namely, a Lower Speed Transient, a Higher Speed Transient, and a Cruise mode. The maximum speeds of these modes were 28.9, 58.2 and 66.0 mph, respectively. Each mode represented statistically selected truck behavior patterns in California. The MHDT is intended to be applied to emissions characterization of trucks (14,001 to 33,000lb gross vehicle weight) exercised on a chassis dynamometer. This paper presents the creation of the MHDT and an examination of repeatability of emissions data from MHDT driven through this schedule. Two trucks were procured to acquire data using the MHDT schedule. The first, a GMC truck with an 8.2-liter Isuzu engine and a standard transmission, was tested at laden weight (90% GVW, 17,550lb) and at unladen weight (50% GVW, 9,750lb).

Emissions tests for heavy -duty diesel-fueled engines and vehicles are normally performed using engine dynamometers and chassis dynamometers, respectively, with laboratory grade gaseous concentration measurement analyzers and supporting test equipment. However, a considerable effort has been recently expended on developing in-use, on-board tools to measure brake-specific emissions from heavy -duty vehicles with the highest degree of accuracy and precision. This alternative testing methodology would supplement the emissions data that is collected from engine and chassis dynamometer tests. The on-board emissions testing methodology entails actively recording emissions and vehicle operating parameters (engine speed and load, vehicle speed etc.) from vehicles while they are operating on the road. This paper focuses on in-use measurements of NOX with zirconium oxide sensors and other portable NOX detectors.

Exhaust emissions from off-highway diesel engines are a significant contributor of both oxides of nitrogen (NOx) and particulate matter (PM) to air inventories. Yet, emissions research activities aimed solely at the off-highway arena have been minimal - largely overshadowed by the extensive efforts directed toward the on-highway sector. However, with current trends indicating that the performance of these off-highway vehicles will become increasingly more scrutinized by federal regulatory agencies, augmentation of current research efforts will be necessary. The global objective for this study was to collect vehicle activity information for diesel-powered off-highway vehicles while they were operated in the field. Engine speed and raw exhaust CO2 concentrations were recorded and then used to create engine dynamometer test cycles. The engine was exercised according to these cycles in the laboratory so that the mass emissions rates of exhaust gas pollutants could be measured.

In characterizing the emissions from mobile sources, it is essential that the vehicle be exercised in a way that reasonably represents typical in-use behavior. A heavy-heavy duty diesel truck (HHDDT) test schedule was developed from speed-time data gathered during two Air Resources Board-sponsored truck activity programs. The data were divided into four modes, termed Idle, Creep, Transient and Cruise Modes, in order of increasing speed. For the last three modes, speed-time schedules were created that represented all the data in that mode. Statistical parameters such as average speed, stops per unit distance, kinetic energy, maximum speed and acceleration and deceleration values were considered in arriving at these schedules. The schedules were evaluated using two Class 8 over-the-road tractors on a chassis dynamometer. Emissions were measured using a full-scale dilution tunnel, filtration for particulate matter (PM), and research grade analyzers for the gases.

Further growth of diesel engines in the light-duty and heavy-duty vehicular market is closely linked to the potential health risks of diesel exhaust. The California Air Resources Board and the Office of Environmental Health Hazard Assessment have identified diesel exhaust as a toxic air contaminant. The International Agency for Research on Cancer concluded that diesel particulate is a probable human carcinogen [1]. Cleaner burning liquid fuels, such as those derived from natural gas via the Fischer-Tropsch (FT) process, offer a potentially economically viable alternative to standard diesel fuel while providing reduced particulate emissions. Further understanding of FT operation may be realized by investigating the differences in toxicity and potential health effects between particulate matter(PM) derived from FT fuel and that derived from standard Federal diesel No. 2 (DF).