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The Lithium Hydroxide (LiOH) management plan to control carbon dioxide (CO2) for the Shuttle while docked to the International Space Station (ISS) reduces the mass and volume needed to be launched. For missions before Flight UF-1/STS-108, the Shuttle and ISS each removed their own CO2 during the docked time period. To control the CO2 level, the Shuttle used LiOH canisters and the ISS used the Vozdukh or the Carbon Dioxide Removal Assembly (CDRA) with the Vozdukh being the primary ISS device for CO2 removal. Analysis predicted that both the Shuttle and Station atmospheres could be controlled using the Station resources with only the Vozdukh and the CDRA. If the LiOH canisters were not needed for the CO2 control on the Shuttle during the docked periods, then the mass and volume from these LiOH canisters normally launched on the Shuttle could be replaced with other cargo.

In order to conserve mass and volume, it was proposed that the International Space Station (ISS) control the level of carbon dioxide (CO2) in the Space Shuttle Orbiter while the Orbiter is docked to the ISS. If successful, this would greatly reduce the number of lithium hydroxide (LiOH) canisters required for each ISS-related Orbiter mission. Because of the impact on the Orbiter Environmental Control and Life Support Subsystem (ECLSS), as well as on the Orbiter flight manifest, a Space Shuttle Program (SSP) analysis was necessary. STS-108 (ISS UF1) pre-flight analysis using the Personal Computer Thermal Analyzer Program (PCTAP) predicted that the ISS would be able to control the level of CO2 in the Orbiter (and throughout the stack) under nominal conditions with no supplemental LiOH required. This analysis assumed that the Carbon Dioxide Removal Assembly (CDRA) located in the U.S.

A recent endeavor has been undertaken to understand the performance of Shuttle Orbiter lithium hydroxide (LiOH) canisters used during STS-114. During this mission, the crew relied on both fresh LiOH and aged LiOH stored on the International Space Station (ISS). Due to the Space Shuttle being grounded after the Columbia accident, the canisters stored on ISS had passed the certified two-year shelf life and were considered expired. The focus of the analysis was to determine the performance of expired LiOH in relation to fresh LiOH and the accuracy of previous predictions1 regarding the performance of expired LiOH. Understanding the performance of expired LiOH is crucial in enabling the extension of the useful life of LiOH canisters. Extending the shelf life has ramifications not only in the current Shuttle program, but in regard to future exploration missions fulfilling the Vision for Space Exploration as well.

Recent efforts have been pursued to establish the usefulness of Space Shuttle Orbiter lithium hydroxide (LiOH) canisters beyond their certified two-year shelf life, at which time they are currently considered “expired.” A stockpile of Orbiter LiOH canisters are stowed on the International Space Station (ISS) as a backup system for maintaining ISS carbon dioxide Canisters with older (CO2) control. Canister with older pack dates must routinely be replaced with newly packed canisters off-loaded from the Orbiter Middeck. Since conservation of upmass is critical for every mission, the minimization of canister swap-out rate is paramount. LiOH samples from canisters with expired dates that had been returned from the ISS were tested for CO2 removal performance at the NASA Johnson Space Center (JSC) Crew and Thermal Systems Division (CTSD). Through this test series and subsequent analysis, performance degradation was established.