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Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.

Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.

Biologically derived isobutanol, a four carbon alcohol, has an energy density closer to that of gasoline and has potential to increase biofuel quantities beyond the current ethanol blend wall. When blended at 16 vol% (iB16), it has identical energy and oxygen content of 10 vol% ethanol (E10). Engine dynamometer emissions tests were conducted on two open-loop electronic fuel-injected marine outboard engines of both two-stroke and four-stroke designs using indolene certification fuel (non-oxygenated), iB16 and E10 fuels. Total particulate emissions were quantified using Sohxlet extraction to determine the amount of elemental and organic carbon. Data indicates a reduction in overall total particulate matter relative to indolene certification fuel with similar trends between iB16 and E10. Gaseous and PM emissions suggest that iB16, relative to E10, could be promising for increasing the use of renewable fuels in recreational marine engines and fuel systems.

This experimental work focuses on defining the detailed morphology of secondary emission products derived from the combustion of cerium (Ce) fuel-borne catalyst (FBC) doped with diesel fuel. Cerium is often used to promote the oxidation of diesel particulates collected in diesel aftertreatment systems, such as diesel particulate filters (DPFs). However, it is suspected that the secondary products could be emitted from the vehicle tailpipe without being effectively filtered by the aftertreatment systems. In this work, these secondary emissions were identified by means of a high-resolution transmission electron microscope (TEM), and their properties were examined in terms of morphology and chemistry. In preparation for fuel doping, a cerium-based aliphatic organic compound solution was mixed with a low-sulfur (110 ppm) diesel fuel at 50 ppm in terms of weight concentration.

As part of an ongoing vehicle benchmarking effort at Argonne National Laboratory, four different power-split HEVs were tested on a chassis dynamometer to analyze their operational behavior and understand the control strategy and its relationship to the individual features of the vehicles tested. The controls that select the way in which engine operation matches best engine efficiency load points appears to have evolved From the Gen 1 to the Gen 2 Toyota Prius. The Ford Escape HEV and Lexus RX400h were also analyzed by using similar methods, although the data are not as extensive as those for the Prius hybrids. Whereas the Escape HEV appeared to operate in a manner similar to that of the Gen 1 Prius, the RX400h (with its relatively large engine) loads the engine with excess battery charge to keep it operating at higher power levels - apparently to improve overall efficiency.

Detailed diesel particulates morphology, nanostructures, fractal geometry, and nitrogen oxides (NOx) emissions were analyzed for five different test fuels in a 1.7-L, common-rail direct-injection diesel engine. The accurately formulated fuels permit the effects of sulfur, paraffins, aromatics, and naphthene concentrations to be determined. A novel thermophoretic sampling technique was used to collect particulates immediately after the exhaust valves. The morphology and nanostructures of particulate samples were examined, imaged with a high-resolution transmission electron microscope (HRTEM), and quantitatively analyzed with customized digital image processing/data acquisition systems. The results show that the particle sizes and the total mass of particulate matter (PM) emissions correlate most strongly with the fuels' aromatics and sulfur content.

Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

The physical and morphological properties of the particulate matter emitted from a 1.7-liter light-duty diesel engine were characterized by observing its evolution in size and fractal geometry along the exhaust system. A common-rail direct-injection diesel engine, the exhaust system of which was equipped with a turbocharger, EGR, and two oxidation catalysts, was powered with a California low-sulfur diesel fuel at various engine-operating conditions. A unique thermophoretic sampling system, a high-resolution transmission electron microscope (TEM), and customized image processing/data acquisition systems were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively. The measurements were carried out at four different positions along the exhaust pipe.

A thermophoretic particulate sampling device was used to investigate the detailed morphology and microstructure of diesel particulates at various engine-operating conditions. A 75 HP Caterpillar single-cylinder direct-injection diesel engine was operated to sample particulate matter from the high-temperature exhaust stream. The morphology and microstructure of the collected diesel particulates were analyzed using a high-resolution transmission electron microscope and subsequent image processing/data acquisition system. The analysis revealed that spherical primary particles were agglomerated together to form large aggregate clusters for most of engine speed and load conditions. Measured primary particle sizes ranged from 34.4 to 28.5 nm at various engine-operating conditions. The smaller primary particles observed at high engine-operating conditions were believed to be caused by particle oxidation at the high combustion temperature.

Their easy availability, lower well-to-wheel emissions, and relative ease of use with existing engine technologies have made ethanol and ethanol-gasoline blends a viable alternative to gasoline for use in spark-ignition (SI) engines. The lower energy density of ethanol and ethanol-gasoline blends, however, results in higher volumetric fuel consumption compared with gasoline. Also, the higher latent heat of vaporization can result in cold-start issues with higher-level ethanol blends. On the other hand, a higher octane number, which indicates resistance to knock and potentially enables more optimal combustion phasing, results in better engine efficiency, especially at higher loads. This paper compares the fuel consumption and emissions of two ethanol blends (E50 and E85) with those for gasoline when used in conventional (non-hybrid) and power-split-type plug-in hybrid electric vehicles (PHEVs).

Detailed characteristics of morphology, nanostructures, and sizes were analyzed for particulate matter (PM) emissions from low-temperature combustion (LTC) modes of a single-cylinder, light-duty diesel engine. The LTC engines have been widely studied in an effort to achieve high combustion efficiency and low exhaust emissions. Recent reports indicate that the number of nucleation mode particles increased in a broad engine operating range, which implies a negative impact on future PM emissions regulations in terms of the nanoparticle number. However, the size measurement of solid carbon particles by commercial instruments is indeed controversial due to the contribution of volatile organics to small nanoparticles. In this work, an LTC engine was operated with various biofuel blends, such as blends (B20) of soy bean oil (soy methyl ester, SME20) and palm oil (palm methyl ester, PME20), as well as an ultra-low-sulfur diesel fuel.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

Ethanol has received both positive and negative attention as a renewable fuel for spark ignition engines. Studies of ethanol have shown improved volumetric efficiency, knock tolerance, and favorable burn curves[1]. Nevertheless, little research has been published exploring the impact of ethanol blends on race engine performance coupled with the impact on well-to-wheels (WTW) greenhouse gases, emissions, and petroleum reduction. In this work, a circle track race vehicle powered by a GM Performance Parts 6.2L OHV CT-525 engine was tested using 100 octane race fuel and E85 over a matrix of configurations. Carburetion vs. fuel injection configurations were benchmarked with both fuels, with the addition of 100- and 300-cells-per-inch catalytic convertors. Testing involved both dynamometer testing and on-track testing utilizing a portable emissions measurement system.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

The detailed morphological properties of diesel particulate matter were analyzed along the exhaust system at various engine operating conditions (in a range of 1000 - 2500 rpm and 10 - 75 % loads of maximum torques). A 1.7-L turbocharged light-duty diesel engine was powered with California low-sulfur diesel fuel injected by a common-rail injection system, of which particulate emissions were controlled by an exhaust gas recirculation (EGR) system and two oxidation catalysts. A unique thermophoretic sampling system first developed for internal combustion engine research, a high-resolution transmission electron microscope (TEM), and a customized image processing/data acquisition system were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively.

Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.

This paper introduces a new systematic workflow for the rapid evaluation of energy-efficient automated driving controls in real vehicles in controlled laboratory conditions. This vehicle-in-the-loop (VIL) workflow, largely standardized and automated, is reusable and customizable, saves time and minimizes costly dynamometer time. In the first case study run with the VIL workflow, an automated car driven by an energy-efficient driving control previously developed at Argonne used up to 22 % less energy than a conventional control. In a VIL experiment, the real vehicle, positioned on a chassis dynamometer, has a digital twin that drives in a virtual world that replicates real-life situations, such as approaching a traffic signal or following other vehicles.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

Currently there is a significant research effort being made in gasoline spark/ignition (SI) engines to understand and reduce cycle-to-cycle variations. One of the phenomena that presents this cycle-to-cycle variation is combustion knock, which also happens to have a very stochastic behavior in modern SI engines. Conversely, the CFR octane rating engine presents much more repeatable combustion knock activity. The aim of this study is to assess the impact of fuel composition on the cycle to cycle variation of the pressure and timing of end gas autoignition. The variation of cylinder conditions at the timing of end-gas autoignition (knock point) for a wide selection of cycle ensembles have been analyzed for several constant RON 98 fuels on the CFR engine, as well as in a modern single-cylinder gasoline direct injection (GDI) SI engine operated at RON-like intake conditions.