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Journal Article

A Preliminary Investigation into the Mitigation of Plug-in Hybrid Electric Vehicle Tailpipe Emissions Through Supervisory Control Methods

2010-04-12
2010-01-1266
Plug-in hybrid electric vehicle (PHEV) technologies have the potential for considerable petroleum consumption reductions, possibly at the expense of increased tailpipe emissions due to multiple “cold” start events and improper use of the engine for PHEV specific operation. PHEVs operate predominantly as electric vehicles (EVs) with intermittent assist from the engine during high power demands. As a consequence, the engine can be subjected to multiple cold start events. These cold start events may have a significant impact on the tailpipe emissions due to degraded catalyst performance and starting the engine under less than ideal conditions. On current hybrid electric vehicles (HEVs), the first cold start of the engine dictates whether or not the vehicle will pass federal emissions tests. PHEV operation compounds this problem due to infrequent, multiple engine cold starts.
Journal Article

Lignin-Derived Carbon Fiber as a Co-Product of Refining Cellulosic Biomass

2014-01-15
2013-01-9092
Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.
Journal Article

Considerations in Estimating Battery Energy for Hybrid and Electric Vehicles

2012-04-16
2012-01-0660
As batteries become a major component of numerous advanced vehicles, significant efforts have been allocated towards characterizing and estimating battery energy capability over the lifetime of a vehicle. Currently, battery State of Charge (SOC) is one of the primary values used for this characterization; however SOC usage has several issues when implemented in Electric Vehicle (EV), Hybrid Electric Vehicle (HEV), and Plug-In Hybrid Electric Vehicle (PHEV) systems. One of the main issues with reporting battery SOC as a characterization of battery energy capability is that it only gives a percentage of the energy available to the operator. SOC does not accurately represent the true capability or capacity of the battery, and thus fails to account for the impact to capability with respect to battery size, age, and recent operational history.
Journal Article

Effects of Fuel Laminar Flame Speed Compared to Engine Tumble Ratio, Ignition Energy, and Injection Strategy on Lean and EGR Dilute Spark Ignition Combustion

2017-03-28
2017-01-0671
Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.
Journal Article

Gaseous and Particulate Emissions Using Isobutanol-Extended Fuel in Recreational Marine Two-Stroke and Four-Stroke Engines

2014-11-11
2014-32-0087
Biologically derived isobutanol, a four carbon alcohol, has an energy density closer to that of gasoline and has potential to increase biofuel quantities beyond the current ethanol blend wall. When blended at 16 vol% (iB16), it has identical energy and oxygen content of 10 vol% ethanol (E10). Engine dynamometer emissions tests were conducted on two open-loop electronic fuel-injected marine outboard engines of both two-stroke and four-stroke designs using indolene certification fuel (non-oxygenated), iB16 and E10 fuels. Total particulate emissions were quantified using Sohxlet extraction to determine the amount of elemental and organic carbon. Data indicates a reduction in overall total particulate matter relative to indolene certification fuel with similar trends between iB16 and E10. Gaseous and PM emissions suggest that iB16, relative to E10, could be promising for increasing the use of renewable fuels in recreational marine engines and fuel systems.
Technical Paper

Morphological Examination of Nano-Particles Derived from Combustion of Cerium Fuel-Borne Catalyst Doped with Diesel Fuel

2007-07-23
2007-01-1943
This experimental work focuses on defining the detailed morphology of secondary emission products derived from the combustion of cerium (Ce) fuel-borne catalyst (FBC) doped with diesel fuel. Cerium is often used to promote the oxidation of diesel particulates collected in diesel aftertreatment systems, such as diesel particulate filters (DPFs). However, it is suspected that the secondary products could be emitted from the vehicle tailpipe without being effectively filtered by the aftertreatment systems. In this work, these secondary emissions were identified by means of a high-resolution transmission electron microscope (TEM), and their properties were examined in terms of morphology and chemistry. In preparation for fuel doping, a cerium-based aliphatic organic compound solution was mixed with a low-sulfur (110 ppm) diesel fuel at 50 ppm in terms of weight concentration.
Technical Paper

Analysis of Power-Split HEV Control Strategies Using Data from Several Vehicles

2007-04-16
2007-01-0291
As part of an ongoing vehicle benchmarking effort at Argonne National Laboratory, four different power-split HEVs were tested on a chassis dynamometer to analyze their operational behavior and understand the control strategy and its relationship to the individual features of the vehicles tested. The controls that select the way in which engine operation matches best engine efficiency load points appears to have evolved From the Gen 1 to the Gen 2 Toyota Prius. The Ford Escape HEV and Lexus RX400h were also analyzed by using similar methods, although the data are not as extensive as those for the Prius hybrids. Whereas the Escape HEV appeared to operate in a manner similar to that of the Gen 1 Prius, the RX400h (with its relatively large engine) loads the engine with excess battery charge to keep it operating at higher power levels - apparently to improve overall efficiency.
Technical Paper

Fuel Property Impacts on Diesel Particulate Morphology, Nanostructures, and NOx Emissions

2007-04-16
2007-01-0129
Detailed diesel particulates morphology, nanostructures, fractal geometry, and nitrogen oxides (NOx) emissions were analyzed for five different test fuels in a 1.7-L, common-rail direct-injection diesel engine. The accurately formulated fuels permit the effects of sulfur, paraffins, aromatics, and naphthene concentrations to be determined. A novel thermophoretic sampling technique was used to collect particulates immediately after the exhaust valves. The morphology and nanostructures of particulate samples were examined, imaged with a high-resolution transmission electron microscope (HRTEM), and quantitatively analyzed with customized digital image processing/data acquisition systems. The results show that the particle sizes and the total mass of particulate matter (PM) emissions correlate most strongly with the fuels' aromatics and sulfur content.
Technical Paper

Closed Loop Transaxle Synchronization Control Design

2010-04-12
2010-01-0817
This paper covers the development of a closed loop transaxle synchronization algorithm which was a key deliverable in the control system design for the L3 Enigma, a Battery Dominant Hybrid Electric Vehicle. Background information is provided to help the reader understand the history that lead to this unique solution of the input and output shaft synchronizing that typically takes place in a manual vehicle transmission or transaxle when shifting into a gear from another or into a gear from neutral when at speed. The algorithm stability is discussed as it applies to system stability and how stability impacts the speed at which a shift can take place. Results are simulated in The MathWorks Simulink programming environment and show how traction motor technology can be used to efficiently solve what is often a machine design issue. The vehicle test bed to which this research is applied is a parallel biodiesel hybrid electric vehicle called the Enigma.
Technical Paper

Model-Based Systems Engineering and Control System Development via Virtual Hardware-in-the-Loop Simulation

2010-10-19
2010-01-2325
Model-based control system design improves quality, shortens development time, lowers engineering cost, and reduces rework. Evaluating a control system's performance, functionality, and robustness in a simulation environment avoids the time and expense of developing hardware and software for each design iteration. Simulating the performance of a design can be straightforward (though sometimes tedious, depending on the complexity of the system being developed) with mathematical models for the hardware components of the system (plant models) and control algorithms for embedded controllers. This paper describes a software tool and a methodology that not only allows a complete system simulation to be performed early in the product design cycle, but also greatly facilitates the construction of the model by automatically connecting the components and subsystems that comprise it.
Technical Paper

Model Architecture, Methods, and Interfaces for Efficient Math-Based Design and Simulation of Automotive Control Systems

2010-04-12
2010-01-0241
Many of today's automotive control system simulation tools are suitable for simulation, but they provide rather limited support for model building and management. Setting up a simulation model requires more than writing down state equations and running them on a computer. The role of a model library is to manage the models of physical components of the system and allow users to share and easily reuse them. In this paper, we describe how modern software techniques can be used to support modeling and design activities; the objective is to provide better system models in less time by assembling these system models in a “plug-and-play” architecture. With the introduction of hybrid electric vehicles, the number of components that can populate a model has increased considerably, and more components translate into more possible drivetrain configurations. To address these needs, we explain how users can simulate a large number of drivetrain configurations.
Technical Paper

Effects of Ethanol Additives on Diesel Particulate and NOx Emissions

2001-05-07
2001-01-1937
Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.
Technical Paper

Evolution in Size and Morphology of Diesel Particulates Along the Exhaust System

2004-06-08
2004-01-1981
The physical and morphological properties of the particulate matter emitted from a 1.7-liter light-duty diesel engine were characterized by observing its evolution in size and fractal geometry along the exhaust system. A common-rail direct-injection diesel engine, the exhaust system of which was equipped with a turbocharger, EGR, and two oxidation catalysts, was powered with a California low-sulfur diesel fuel at various engine-operating conditions. A unique thermophoretic sampling system, a high-resolution transmission electron microscope (TEM), and customized image processing/data acquisition systems were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively. The measurements were carried out at four different positions along the exhaust pipe.
Technical Paper

Engine Start Characteristics of Two Hybrid Electric Vehicles (HEVs) - Honda Insight and Toyota Prius

2001-08-20
2001-01-2492
Hybrid electric vehicles (HEVs) may have key fuel economy and emissions advantages over current conventional vehicles, but they have drawbacks such as frequent engine starts that can slow down market penetration of HEVs. First, the hydrocarbon emissions due to the numerous engine starts would make newly developed HEV powertrains even more demanding on the emission control system. Second, frequent starts may make the engine deteriorate quickly. This study is an attempt to gain a better understanding of the engine start characteristics of two limited-production HEVs (Toyota Prius and Honda Insight). Using fast-response (5 ms) hydrocarbon and NO (nitric oxide) analyzers, the transient emissions were measured in the engine exhaust ports during cold and hot engine starts. On the basis of the experimental findings, several recommendations were made to improve performance and emissions of future HEVs.
Technical Paper

Detailed Characterization of Morphology and Dimensions of Diesel Particulates via Thermophoretic Sampling

2001-09-24
2001-01-3572
A thermophoretic particulate sampling device was used to investigate the detailed morphology and microstructure of diesel particulates at various engine-operating conditions. A 75 HP Caterpillar single-cylinder direct-injection diesel engine was operated to sample particulate matter from the high-temperature exhaust stream. The morphology and microstructure of the collected diesel particulates were analyzed using a high-resolution transmission electron microscope and subsequent image processing/data acquisition system. The analysis revealed that spherical primary particles were agglomerated together to form large aggregate clusters for most of engine speed and load conditions. Measured primary particle sizes ranged from 34.4 to 28.5 nm at various engine-operating conditions. The smaller primary particles observed at high engine-operating conditions were believed to be caused by particle oxidation at the high combustion temperature.
Technical Paper

Evaluation of Ethanol Blends for Plug-In Hybrid Vehicles Using Engine in the Loop

2012-04-16
2012-01-1280
Their easy availability, lower well-to-wheel emissions, and relative ease of use with existing engine technologies have made ethanol and ethanol-gasoline blends a viable alternative to gasoline for use in spark-ignition (SI) engines. The lower energy density of ethanol and ethanol-gasoline blends, however, results in higher volumetric fuel consumption compared with gasoline. Also, the higher latent heat of vaporization can result in cold-start issues with higher-level ethanol blends. On the other hand, a higher octane number, which indicates resistance to knock and potentially enables more optimal combustion phasing, results in better engine efficiency, especially at higher loads. This paper compares the fuel consumption and emissions of two ethanol blends (E50 and E85) with those for gasoline when used in conventional (non-hybrid) and power-split-type plug-in hybrid electric vehicles (PHEVs).
Technical Paper

Characterization of Particulate Morphology, Nanostructures, and Sizes in Low-Temperature Combustion with Biofuels

2012-04-16
2012-01-0441
Detailed characteristics of morphology, nanostructures, and sizes were analyzed for particulate matter (PM) emissions from low-temperature combustion (LTC) modes of a single-cylinder, light-duty diesel engine. The LTC engines have been widely studied in an effort to achieve high combustion efficiency and low exhaust emissions. Recent reports indicate that the number of nucleation mode particles increased in a broad engine operating range, which implies a negative impact on future PM emissions regulations in terms of the nanoparticle number. However, the size measurement of solid carbon particles by commercial instruments is indeed controversial due to the contribution of volatile organics to small nanoparticles. In this work, an LTC engine was operated with various biofuel blends, such as blends (B20) of soy bean oil (soy methyl ester, SME20) and palm oil (palm methyl ester, PME20), as well as an ultra-low-sulfur diesel fuel.
Technical Paper

Detailed Morphological Properties of Nanoparticles from Gasoline Direct Injection Engine Combustion of Ethanol Blends

2013-09-08
2013-24-0185
Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.
Technical Paper

The Impact of Cellulosic Ethanol on the Performance and Emissions of a Circle Track Race Car

2013-04-08
2013-01-1149
Ethanol has received both positive and negative attention as a renewable fuel for spark ignition engines. Studies of ethanol have shown improved volumetric efficiency, knock tolerance, and favorable burn curves[1]. Nevertheless, little research has been published exploring the impact of ethanol blends on race engine performance coupled with the impact on well-to-wheels (WTW) greenhouse gases, emissions, and petroleum reduction. In this work, a circle track race vehicle powered by a GM Performance Parts 6.2L OHV CT-525 engine was tested using 100 octane race fuel and E85 over a matrix of configurations. Carburetion vs. fuel injection configurations were benchmarked with both fuels, with the addition of 100- and 300-cells-per-inch catalytic convertors. Testing involved both dynamometer testing and on-track testing utilizing a portable emissions measurement system.
Technical Paper

Blend Ratio Optimization of Fuels Containing Gasoline Blendstock, Ethanol, and Higher Alcohols (C3-C6): Part II - Blend Properties and Target Value Sensitivity

2013-04-08
2013-01-1126
Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.
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